SYNTHESIS AND CHARACTERIZATION OF A NOVEL OXIME COMPOUND OF 2-AMINOMETHYLPYRIDINE AND ITS METAL COMPLEXES.

Year 2009, Issue: 019, 23 - 30, 15.08.2009

Cengiz Yenikaya Mustafa Demir Halil İlkimen

Abstract

(1Z,2E)-N'-hydroxy-2-(hydroxyimino)-N-(pyridin-2-yl)acetimidamide (H₂L)
is synthesized from the reaction between anti-monochloroglyoxime
and 2-aminomethylpyridine and characterized by means of ¹H-NMR, ¹³C-NMR,
FT-IR, elemental analysis methods. Co²⁺, Ni²⁺ and Cu²⁺
complexes of H₂L ligand were obtained and their structures were
elucidated with FT-IR, elemental analysis, ICP-OES, magnetic susceptibility and conductivity studies.

Keywords

Glyoxime, Metal Complexes, 2-Aminomethylpyridine, Vic-Dioxime

2-AMİNOMETİLPİRİDİN ESASLI YENİ OKSİM BİLEŞİĞİ İLE METAL KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Abstract

(1Z,2E)-N-hidroksil-(2-hidroksiimino)-N^’-(piridin-2-ilmetil)
propanimidamid (H₂L) ligandı, anti-monoklorglioksim
ile 2-aminometilpiridinin reaksiyonundan elde edilmiş olup yapısı ¹H-NMR,
¹³C-NMR, FT-IR, elementel analiz teknikleri kullanılarak
aydınlatılmıştır. H₂L ligandının Co²⁺, Ni²⁺ ve
Cu²⁺ kompleksleri hazırlanarak FT-IR, elementel analiz, ICP-OES,
manyetik duyarlılık ve iletkenlik metotları ile yapıları aydınlatılmaya
çalışılmıştır.

Keywords

Glioksim, metal kompleksleri, 2-aminometilpiridin, vic-dioksim

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