Research Article
BibTex RIS Cite

EFFECTS OF ADMIXTURES ON HYDRATION HEAT OF CEMENT PASTE

Year 2007, Issue: 014, 73 - 86, 17.12.2007

Abstract

In this study, Trisodium citrate (C6H5Na3O7 – Ret. 1), citric acid (C6H8O7 – Ret.2) and tartaric acid (C4H6O6 – Ret.3)
were used to retard the hydration process of cement paste. Admixtures were investigated with respect to their effects
on the hydration heat of ordinary Portland cement. Heat liberation graphs of mixes during hydration process were
plotted by using isothermal calorimetry. Heat liberation of mixes varies due to their different rapid dissolution
properties. Cement paste without a retarder has an early setting time between all mixes. The calorimetric graphs
indicate that the setting time increases as the ratio of retarder increases. At the ratio of 0.2 %, tartaric acid has the
strongest effect on retardation.

References

  • [1] Lea’s Chemistry of Cement and Concrete. 4th Ed. Arnold; (1998), 263- 271.
  • [2] Osipov AD, Concrete setting retarders. Power Technology and Engineering.12 (1978), no. 7, 670-678
  • [3] Uchikawa H, Sawaki D and Hanehara S., Influence of kind and added timing of organic admixture on the composition, structure and property of fresh cement paste. Cem Concr Res; 25 (1995),no. 2, 353- 364.
  • [4] Rai S, Chaturvedi S and Singh NB., Examination of Portland cement paste hydrated in the presence ofmalic acid. Cem Concr Res., 34: (2004), 455- 462.
  • [5] Bohner M, et all. Effect of several additives and their admixtures on the physico-chemical properties of acalcium phosphate cement. Journal of Material Science: Materials in Medicine, 11(2000); 111- 116.
  • [6] Young JF. A review of the mechanism of set-retardation in Portland cement pastes containing admixtures. Cem Concr Res 2 (1972), 415- 433.
  • [7] Thomas NL and Birchal JD. The retarding action of sugars on cement hydration. Cem Concr Res. 13(1983), 830-842.
  • [8] Singh NB, Singh AK and Singh SP. Retardation of Portland cement by citric acid. Proc.8th Int. Cong. Chem. Cem. Rio, Brazil, vol.2.1, (1986), 101-108.
  • [9] Heren Z and Olmez H, The influence of ethanolamines on the surface properties of Portland cement pastes. Cem Concr Res.,27 (1997), no. 6, 805-809.
  • [10] Wilding CR, Walter A and Double DD. A classification of inorganic and organic admixtures by conduction calorimetry. Cem Concr Res 14,(1984), 185-189.
  • [11] Singh NB, Singh SP and Singh AK. Effect of lactic acid on the hydration of Portland cement. Cem Concr Res 16 (1986), 545-553.

KATKILARIN ÇİMENTO HAMURU HİDRATASYON ISISINA ETKİLERİ

Year 2007, Issue: 014, 73 - 86, 17.12.2007

Abstract

Bu çalışmada, Trisodyum sitrat (C6H5Na3O7 – Ret. 1), sitrik asit (C6H8O7 – Ret.2) ve tartarik asit (C4H6O6 – Ret.3)
çimento harçlarının hidratasyon süreçlerini geciktirmek amacıyla kullanılmıştır. Katkılar Portland çimentosunun
hidratasyon ısısı üzerine etkileri ele alınarak incelenmiştir. Hidratasyon süreçleri boyunca karışımların ısı çıkışı
grafikleri izotermal kalorimetre kullanılarak çizilmiştir. Karışımların ısı çıkışları katkıların hızlı çözünme
özelliklerine bağlı olarak değişirler. Katkısız çimento hamuru bütün karışımlar arasında en erken priz süresine
sahiptir. Kalorimetre grafikleri katkı oranı arttıkça priz süresinin uzadığını işaret eder. 0.2 % oranında, tartarik asit
geciktirme üzerinden güçlü etkiye sahiptir.

References

  • [1] Lea’s Chemistry of Cement and Concrete. 4th Ed. Arnold; (1998), 263- 271.
  • [2] Osipov AD, Concrete setting retarders. Power Technology and Engineering.12 (1978), no. 7, 670-678
  • [3] Uchikawa H, Sawaki D and Hanehara S., Influence of kind and added timing of organic admixture on the composition, structure and property of fresh cement paste. Cem Concr Res; 25 (1995),no. 2, 353- 364.
  • [4] Rai S, Chaturvedi S and Singh NB., Examination of Portland cement paste hydrated in the presence ofmalic acid. Cem Concr Res., 34: (2004), 455- 462.
  • [5] Bohner M, et all. Effect of several additives and their admixtures on the physico-chemical properties of acalcium phosphate cement. Journal of Material Science: Materials in Medicine, 11(2000); 111- 116.
  • [6] Young JF. A review of the mechanism of set-retardation in Portland cement pastes containing admixtures. Cem Concr Res 2 (1972), 415- 433.
  • [7] Thomas NL and Birchal JD. The retarding action of sugars on cement hydration. Cem Concr Res. 13(1983), 830-842.
  • [8] Singh NB, Singh AK and Singh SP. Retardation of Portland cement by citric acid. Proc.8th Int. Cong. Chem. Cem. Rio, Brazil, vol.2.1, (1986), 101-108.
  • [9] Heren Z and Olmez H, The influence of ethanolamines on the surface properties of Portland cement pastes. Cem Concr Res.,27 (1997), no. 6, 805-809.
  • [10] Wilding CR, Walter A and Double DD. A classification of inorganic and organic admixtures by conduction calorimetry. Cem Concr Res 14,(1984), 185-189.
  • [11] Singh NB, Singh SP and Singh AK. Effect of lactic acid on the hydration of Portland cement. Cem Concr Res 16 (1986), 545-553.
There are 11 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

A.Uğur Öztürk This is me

Publication Date December 17, 2007
Published in Issue Year 2007 Issue: 014

Cite

APA Öztürk, A. (2007). KATKILARIN ÇİMENTO HAMURU HİDRATASYON ISISINA ETKİLERİ. Journal of Science and Technology of Dumlupınar University(014), 73-86.

HAZİRAN 2020'den itibaren Journal of Scientific Reports-A adı altında ingilizce olarak yayın hayatına devam edecektir.