AND CHARACTERIZATION OF METAL COMPLEXES OF (1Z,2E)-N'-HYDROXY-2-(HYDROXYIMINO)-N-(p-TOLYL)ACETIMIDAMIDE LIGAND

Year 2018, Issue: 041, 13 - 22, 16.12.2018

Halil İlkimen

Abstract

In this study, (1Z,2E)-N'-hydroxy-2-(hydroxyimino)-N-(p-tolyl)acetimidamide (H₂L) ligand was synthesized, which is
reported in literature, and ligand constituted anti-chloroglyoxime (gly) and p-toluidin
(ptol) was synthesized and its metal
complexes with Fe(II) and Zn(II) were obtained. The structure of ligand has
been proposed by using elemantal analysis, ¹H-NMR, ¹³C‑NMR,
FT-IR, UV-Vis techniques. The structure of amorphous Fe(II) and Zn(II)complexes
have been proposed by using elemantal analysis, ICP-OES, FT-IR, UV-Vis,
magnetic susceptibility and molar conductivity techniques.

Keywords

Glyoxime, Metal Complexes, p-Toluidine, Vic-Dioxime

(1Z, 2E)-N’-HİDROKSİL-2-HİDROKSİİMİNO-N-p-TOLİL-ASETAMİDİN LİGANDININ Fe(II) VE Zn(II) KOMPLEKSLERININ SENTEZI VE YAPILARININ AYDINLATILMASI

Abstract

Bu çalışmada anti-kloroglioksim (gly) ile p-toluidin (ptol) reaksiyonundan (1Z, 2E)-N’-hidroksil-2-hidroksiimino-N-p-tolil-asetamidin
(H₂L) ligandı
literatürde belirtildiği şekilde sentezlenmiştir. Daha sonra bu ligandının
Fe(II) ve Zn(II) metal kompleksleri sentezlenmiştir. Ligandın yapısı elementel
analiz, ¹H-NMR, ¹³C-NMR, FT-IR, UV-Vis metotları ile aydınlatılmıştır.
Amorf halde elde edilen Fe(II)
ve Zn(II) komplekslerinin yapıları ise elementel analiz, ICP-OES, FT-IR, UV-Vis, manyetik duyarlılık ve molar iletkenlik
sonuçları dikkate alınarak önerilmiştir.

Keywords

Glioksim, Metal Kompleksleri, p-Toluidin, Vic-Dioksim

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