Research Article
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PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances

Year 2022, Volume: 5 Issue: 1, 15 - 21, 08.06.2022
https://doi.org/10.46239/ejbcs.1078752

Abstract

Zinc–nickel alloy coating (ZnNi) was successfully deposited on carbon steel (CS) applying current density of 47 mAcm-2 with galvanostatic technique. The ZnNi alloy coating image showed that CS metal surface was plated with a blue-grey homogeneous layer. Polyaniline film (PANI) film was synthesized with cyclic voltammetry technique from 0.10 M aniline containing 0.20 M sodium oxalate solution on ZnNi coated carbon steel (CS/ZnNi) electrode surface. And then the synthesis of top PPy film was achieved in pyrrole monomer containing acetonitrile + tetrabutyl ammonium perchlorate medium successfully. After the top PPy synthesis, it was observed that both the PANi homopolymer film and the ZnNi coating continued to exist on the CS surface. The corrosion behaviors of uncoated and coated electrodes were investigated in 3.5% NaCl solution. For this aim, the anodic polarization plots and electrochemical impedance spectroscopy technique were used. The results showed that the top PPy homopolymer film provided an effective barrier property on CS/ZnNi/PANi electrode and a remarkable anodic protection to substrate for longer exposure time.

References

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  • Chouia F, Chala A, Lakel A, Sahraoui T. 2021. Morphology and Corrosion Behavior of Zn-Ni Layers Electrodeposited on Low Alloy Carbon Steel Substrate. Ann Chim Sci Mat. 45(3):225–230. doi.org/10.18280/acsm.450305
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  • Kilinççeker G, Galip H. 2008. The effects of acetate ions (CH3COO−) on electrochemical behavior of copper in chloride solutions. Mater Chem Phys. 110(2-3):380-386. doi.org/10.1016/j.matchemphys.2008.02.026
  • Kilinççeker G, Demir H. 2013. The Inhibition Effects of Methionine on Corrosion Behavior of Copper in 3.5% NaCl Solution at pH = 8.5. Prot Met Phys Chem. 49(6):788-797. doi.org/10.1134/s2070205113060221
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  • Ozyilmaz AT, Ozyilmaz G, Colak N. 2006. Novel synthesis medium for poly(aniline-co-o-anisidine). Surf Coat Technol. 201:2484-2490. doi:10.1016/j.surfcoat.2006.04.008
  • Ozyilmaz AT, Sangun MK, Filazi I, Surmelioglu C, Ozyilmaz G. 2020. A Novel Approach to the Synthesis of Alloy: PEG400 Containing ZnNi and ZnNiCr Alloy Coatings and Their Anticorrosion Performance. Metall Mater Trans A. 51(7):3638–3647. doi.org/10.1007/s11661-020-05766-5
  • Özyılmaz AT. 2005. The corrosion behavior of polyaniline top coat on nickel plated copper from neutral aqueous medium. Prog Org Coat. 54(2):127–133. doi.org/10.1016/j.porgcoat.2005.05.003
  • Sokolova MP, Smirnov MA, Kasatkin IA, Dmitriev IY, Saprykina NN, Toikka AM, Lahderanta E, Elyashevich GK. 2017. Interaction of Polyaniline with Surface of Carbon Steel. Int J Polym Sci. 2017:1–9. doi.org/10.1155/2017/6904862
  • Tozar A, Karahan IH. 2014. Structural and corrosion protection properties of electrochemically deposited nano-sized Zn–Ni alloy coatings. Appl Surf Sci. 318:15–23. doi.org/10.1016/j.apsusc.2013.12.020
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  • Winiarski J, Laszczyńska A, Szczygieł B. 2015. An electrochemical study on the influence of sodium molybdate on electrodeposition process and phase composition of ternary Zn–Ni–Mo alloy coatings. Trans IMF. 93(5):267–274. doi.org/10.1080/00202967.2015.1114728
  • World Steel Association. 2021. Global crude steel output decreases by 0.9% in 2020. World Steel Association Press Releases. https://www.worldsteel.org
Year 2022, Volume: 5 Issue: 1, 15 - 21, 08.06.2022
https://doi.org/10.46239/ejbcs.1078752

Abstract

References

  • Akdağ A, Özyılmaz AT. 2017. Poly(N-methylpyrrole) Film on ZnNi Plated Carbon Steel Electrode. Acta Chim. Slov. 64(2):312–318. doi.org/10.17344/acsi.2016.3119
  • Ates M. 2016. A review on conducting polymer coatings for corrosion protection. J Adhes Sci Technol. 30(14):1510–1536. doi.org/10.1080/01694243.2016.1150662
  • Bhat RS, Shetty SM, Kumar, NA. 2021. Electroplating of Zn-Ni Alloy Coating on Mild Steel and Its Electrochemical Studies. J Mater Eng Perform. 30:8188–8195. doi.org/10.1007/s11665-021-06051-1
  • Chouia F, Chala A, Lakel A, Sahraoui T. 2021. Morphology and Corrosion Behavior of Zn-Ni Layers Electrodeposited on Low Alloy Carbon Steel Substrate. Ann Chim Sci Mat. 45(3):225–230. doi.org/10.18280/acsm.450305
  • El-Lateef HM, El-Sayed A, Mohran H. 2015. Role of Ni content in improvement of corrosion resistance of Zn–Ni alloy in 3.5% NaCl solution. Part I: Polarization and impedance studies. T Nonferr Metal Soc. 25(8):2807–2816. doi.org/10.1016/S1003-6326(15)63906-1
  • Hou B, Li X, Ma X, Du C, Zhang D, Zheng M, Xu W, Lu D, Ma F. 2017. The cost of corrosion in China. NPJ Mater Degrad. 1(1):4. doi.org/10.1038/s41529-017-0005-2
  • International Iron and Steel Institute. 1978. A handbook of world steel statistics 1978. https://worldsteel.org/steel-by-topic/statistics/steel-statistical-yearbook/
  • Kaliyannan GV, Velusamy MKK, Palaniappan SK, Anandraj MK, Rathanasamy R. 2020. Polymer Coatings for Corrosive Protection. Polymer Coatings: Technology and Applications, Wiley, pp 371–395. doi.org/10.1002/9781119655145.ch17
  • Kilinççeker G, Galip H. 2008. The effects of acetate ions (CH3COO−) on electrochemical behavior of copper in chloride solutions. Mater Chem Phys. 110(2-3):380-386. doi.org/10.1016/j.matchemphys.2008.02.026
  • Kilinççeker G, Demir H. 2013. The Inhibition Effects of Methionine on Corrosion Behavior of Copper in 3.5% NaCl Solution at pH = 8.5. Prot Met Phys Chem. 49(6):788-797. doi.org/10.1134/s2070205113060221
  • Koch GH, Brongers MPH, Thompson NG, Virmani YP, Payer JH. 2002. Cost of Corrosion Supplement. Corrosion Costs and Preventive Strategies in the United States. https://doi.org/FHWA-RD-01-156
  • Oxford Economics. 2019. The Role of Steel Manufacturing in the Global Economy: A Report for the World Steel Association. https://www.worldsteel.org
  • Ozyilmaz AT, Ozyilmaz G, Colak N. 2006. Novel synthesis medium for poly(aniline-co-o-anisidine). Surf Coat Technol. 201:2484-2490. doi:10.1016/j.surfcoat.2006.04.008
  • Ozyilmaz AT, Sangun MK, Filazi I, Surmelioglu C, Ozyilmaz G. 2020. A Novel Approach to the Synthesis of Alloy: PEG400 Containing ZnNi and ZnNiCr Alloy Coatings and Their Anticorrosion Performance. Metall Mater Trans A. 51(7):3638–3647. doi.org/10.1007/s11661-020-05766-5
  • Özyılmaz AT. 2005. The corrosion behavior of polyaniline top coat on nickel plated copper from neutral aqueous medium. Prog Org Coat. 54(2):127–133. doi.org/10.1016/j.porgcoat.2005.05.003
  • Sokolova MP, Smirnov MA, Kasatkin IA, Dmitriev IY, Saprykina NN, Toikka AM, Lahderanta E, Elyashevich GK. 2017. Interaction of Polyaniline with Surface of Carbon Steel. Int J Polym Sci. 2017:1–9. doi.org/10.1155/2017/6904862
  • Tozar A, Karahan IH. 2014. Structural and corrosion protection properties of electrochemically deposited nano-sized Zn–Ni alloy coatings. Appl Surf Sci. 318:15–23. doi.org/10.1016/j.apsusc.2013.12.020
  • Üneri S. 2011. Korozyon ve Önlenmesi (3rd ed.). Corrosion Association, Ankara
  • Winiarski J, Laszczyńska A, Szczygieł B. 2015. An electrochemical study on the influence of sodium molybdate on electrodeposition process and phase composition of ternary Zn–Ni–Mo alloy coatings. Trans IMF. 93(5):267–274. doi.org/10.1080/00202967.2015.1114728
  • World Steel Association. 2021. Global crude steel output decreases by 0.9% in 2020. World Steel Association Press Releases. https://www.worldsteel.org
There are 20 citations in total.

Details

Primary Language English
Subjects Electrochemistry
Journal Section Research Articles
Authors

Ibrahim Filazi 0000-0002-8194-1421

Ali Tuncay Ozyilmaz

Publication Date June 8, 2022
Acceptance Date April 21, 2022
Published in Issue Year 2022 Volume: 5 Issue: 1

Cite

APA Filazi, I., & Ozyilmaz, A. T. (2022). PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances. Eurasian Journal of Biological and Chemical Sciences, 5(1), 15-21. https://doi.org/10.46239/ejbcs.1078752
AMA Filazi I, Ozyilmaz AT. PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances. Eurasian J. Bio. Chem. Sci. June 2022;5(1):15-21. doi:10.46239/ejbcs.1078752
Chicago Filazi, Ibrahim, and Ali Tuncay Ozyilmaz. “PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances”. Eurasian Journal of Biological and Chemical Sciences 5, no. 1 (June 2022): 15-21. https://doi.org/10.46239/ejbcs.1078752.
EndNote Filazi I, Ozyilmaz AT (June 1, 2022) PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances. Eurasian Journal of Biological and Chemical Sciences 5 1 15–21.
IEEE I. Filazi and A. T. Ozyilmaz, “PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances”, Eurasian J. Bio. Chem. Sci., vol. 5, no. 1, pp. 15–21, 2022, doi: 10.46239/ejbcs.1078752.
ISNAD Filazi, Ibrahim - Ozyilmaz, Ali Tuncay. “PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances”. Eurasian Journal of Biological and Chemical Sciences 5/1 (June 2022), 15-21. https://doi.org/10.46239/ejbcs.1078752.
JAMA Filazi I, Ozyilmaz AT. PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances. Eurasian J. Bio. Chem. Sci. 2022;5:15–21.
MLA Filazi, Ibrahim and Ali Tuncay Ozyilmaz. “PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances”. Eurasian Journal of Biological and Chemical Sciences, vol. 5, no. 1, 2022, pp. 15-21, doi:10.46239/ejbcs.1078752.
Vancouver Filazi I, Ozyilmaz AT. PANi/PPy and PANi Films on ZnNi Alloy Coated Carbon Steel; Electrochemical Syntheses and Corrosion Performances. Eurasian J. Bio. Chem. Sci. 2022;5(1):15-21.

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