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Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel

Year 2024, Volume: 7 Issue: 1, 20 - 25, 30.06.2024
https://doi.org/10.46239/ejbcs.1425801

Abstract

In this research, the potential of Elaeagnus angustifolia tree leaf extract as a green corrosion inhibitor for mild steel in hydrochloric acid solution was examined. The stock concentration of the aqueous extract was determined to be 0.38% (w/v). Other experimental solutions were created by diluting four different extract concentrations in aggressive solution. Experimental measurements, including linear polarization (LPR), electrochemical impedance spectroscopy (EIS), and semi-logarithmic current potential curves by Tafel extrapolation method, were employed to validate the corrosion inhibition effects of the plant leaf extract at varying concentrations. Notably, oleaster leaf extract demonstrated a corrosion protection of over 90% for 0.018% w/v concentration on the mild steel, attributed to its abundance in secondary metabolites such as polyphenols and flavonoids. The atomic force microscopy (AFM) surface maps provide robust evidence for the electrochemical measurement data.

References

  • Akkoç S, Özkır D, Başaran E, Kaya S, Berisha A. 2023. A combined experimental and theoretical approach effect of a benzimidazolium salt as a new corrosion inhibitor on mild steel in HCl solution. Ionics, 29:3813–3827
  • Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M. 2018. Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: experimental, molecular dynamics, Monte Carlo and quantum mechanics study. J Mol Liq. 255:185–198
  • El-Hajjaji F, Messali M, Aljuhani A, Aouad M, Hammouti B, Belghiti M, Chauhan D, Quraishi M. 2018. Pyridazinium-based ionic liquids as novel and green corrosion inhibitors of carbon steel in acid medium: electrochemical and molecular dynamics simulation studies. J Mol Liq. 249:997–1008
  • Haque J, Srivastava V, Verma C, Quraishi M. 2017. Experimental and quantum chemical analysis of 2-amino-3-((4-((S)-2-amino-2-carboxyethyl)-1H-imidazol-2-yl)thio) propionic acid as new and green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution. J Mol Liq. 225:848–855
  • Karazehir T, Mert ME, Doğru Mert B. 2022. Corrosion prevention of mild steel in acidic medium by 2-Pyrrolidin-1-yl-1,3-thiazole-5-carboxylic acid: Theoretical and experimental approach. J Indian Chem Soc, 99:100642
  • Mert ME & Doğru Mert B. 2023. Karbon Ayak İzinin Azaltılması için Korozyon İnhibitörü Olarak Son Kullanma Tarihi Geçmiş Depakin Tabletin İncelenmesi. Kadirli Uygulamalı Bilimler Fakültesi Dergisi, 3(1):56–66
  • Mert ME. 2022. 2-etil-4-metil-1,3-tiyazol-5-karboksilik Asitin Korozyona Karşı İnhibisyon Etkisinin İncelenmesi. BŞEÜ Fen Bilimleri Dergisi, 9(2):1110-1121
  • Mohammadinejad R, Karimi S, Iravani S, Varma RS. 2016. Plant-derived nanostructures: types and applications. Green Chem. 18:20–52
  • Nazlıgül H, Güllü E, Mert ME, Doğru Mert B. 2022. Investigation of Inhibition Performance of Epdantoin for Mild Steel Protection in HCl Solution: Electrochemical and Quantum Theoretical Approaches. Tr J Nature Sci. 11(4):70-78
  • Özkır D. 2019. A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques. J Electrochem Sci Technol. 10(1):37–54
  • Ramezanzadeh B, Vakili H, Amini R, 2015. The effects of addition of poly(vinyl)alcohol (PVA) as a green corrosion inhibitor to the phosphate conversion coating on the anticorrosion and adhesion properties of the epoxy coating on the steel substrate, Appl Surf Sci. 327:174–181
  • Singh P, Srivastava V, Quraishi M. 2016a. Novel quinoline derivatives as green corrosion inhibitors for mild steel in acidic medium: electrochemical, SEM, AFM, and XPS studies. J Mol Liq. 216:164–173
  • Singh P, Makowska-Janusik M, Slovensky P, Quraishi M. 2016b. Nicotinonitriles as green corrosion inhibitors for mild steel in hydrochloric acid: electrochemical, computational and surface morphological studies. J Mol Liq. 220:71–81
  • Tan B, He J, Zhang S, Xu C, Chen S, Liu H, Li W. 2021. Insight into anti-corrosion nature of Betel leaves water extracts as the novel and eco-friendly inhibitors. J Colloid Interface Sci. 585:287–301
  • Verma C, Ebenso EE, Bahadur I, Quraishi MA. 2018. An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media. J Mol Liq. 266:577–590
  • Zhang J-N, Ma M-H, Ma X-L, Ma F-L, Du Q-Y, Liu J-N, Wang X-C, Zhao Q-P, Yu Y-J, She Y. 2023. A comprehensive study of the effect of drying methods on compounds in Elaeagnus angustifolia L. flower by GC-MS and UHPLC-HRMS based untargeted metabolomics combined with chemometrics. Ind Crop Prod. 195:116452
Year 2024, Volume: 7 Issue: 1, 20 - 25, 30.06.2024
https://doi.org/10.46239/ejbcs.1425801

Abstract

References

  • Akkoç S, Özkır D, Başaran E, Kaya S, Berisha A. 2023. A combined experimental and theoretical approach effect of a benzimidazolium salt as a new corrosion inhibitor on mild steel in HCl solution. Ionics, 29:3813–3827
  • Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M. 2018. Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: experimental, molecular dynamics, Monte Carlo and quantum mechanics study. J Mol Liq. 255:185–198
  • El-Hajjaji F, Messali M, Aljuhani A, Aouad M, Hammouti B, Belghiti M, Chauhan D, Quraishi M. 2018. Pyridazinium-based ionic liquids as novel and green corrosion inhibitors of carbon steel in acid medium: electrochemical and molecular dynamics simulation studies. J Mol Liq. 249:997–1008
  • Haque J, Srivastava V, Verma C, Quraishi M. 2017. Experimental and quantum chemical analysis of 2-amino-3-((4-((S)-2-amino-2-carboxyethyl)-1H-imidazol-2-yl)thio) propionic acid as new and green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution. J Mol Liq. 225:848–855
  • Karazehir T, Mert ME, Doğru Mert B. 2022. Corrosion prevention of mild steel in acidic medium by 2-Pyrrolidin-1-yl-1,3-thiazole-5-carboxylic acid: Theoretical and experimental approach. J Indian Chem Soc, 99:100642
  • Mert ME & Doğru Mert B. 2023. Karbon Ayak İzinin Azaltılması için Korozyon İnhibitörü Olarak Son Kullanma Tarihi Geçmiş Depakin Tabletin İncelenmesi. Kadirli Uygulamalı Bilimler Fakültesi Dergisi, 3(1):56–66
  • Mert ME. 2022. 2-etil-4-metil-1,3-tiyazol-5-karboksilik Asitin Korozyona Karşı İnhibisyon Etkisinin İncelenmesi. BŞEÜ Fen Bilimleri Dergisi, 9(2):1110-1121
  • Mohammadinejad R, Karimi S, Iravani S, Varma RS. 2016. Plant-derived nanostructures: types and applications. Green Chem. 18:20–52
  • Nazlıgül H, Güllü E, Mert ME, Doğru Mert B. 2022. Investigation of Inhibition Performance of Epdantoin for Mild Steel Protection in HCl Solution: Electrochemical and Quantum Theoretical Approaches. Tr J Nature Sci. 11(4):70-78
  • Özkır D. 2019. A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques. J Electrochem Sci Technol. 10(1):37–54
  • Ramezanzadeh B, Vakili H, Amini R, 2015. The effects of addition of poly(vinyl)alcohol (PVA) as a green corrosion inhibitor to the phosphate conversion coating on the anticorrosion and adhesion properties of the epoxy coating on the steel substrate, Appl Surf Sci. 327:174–181
  • Singh P, Srivastava V, Quraishi M. 2016a. Novel quinoline derivatives as green corrosion inhibitors for mild steel in acidic medium: electrochemical, SEM, AFM, and XPS studies. J Mol Liq. 216:164–173
  • Singh P, Makowska-Janusik M, Slovensky P, Quraishi M. 2016b. Nicotinonitriles as green corrosion inhibitors for mild steel in hydrochloric acid: electrochemical, computational and surface morphological studies. J Mol Liq. 220:71–81
  • Tan B, He J, Zhang S, Xu C, Chen S, Liu H, Li W. 2021. Insight into anti-corrosion nature of Betel leaves water extracts as the novel and eco-friendly inhibitors. J Colloid Interface Sci. 585:287–301
  • Verma C, Ebenso EE, Bahadur I, Quraishi MA. 2018. An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media. J Mol Liq. 266:577–590
  • Zhang J-N, Ma M-H, Ma X-L, Ma F-L, Du Q-Y, Liu J-N, Wang X-C, Zhao Q-P, Yu Y-J, She Y. 2023. A comprehensive study of the effect of drying methods on compounds in Elaeagnus angustifolia L. flower by GC-MS and UHPLC-HRMS based untargeted metabolomics combined with chemometrics. Ind Crop Prod. 195:116452
There are 16 citations in total.

Details

Primary Language English
Subjects Solution Chemistry, Electrochemistry, Physical Chemistry (Other)
Journal Section Research Articles
Authors

Demet Özkır 0000-0002-8096-5755

Publication Date June 30, 2024
Submission Date January 25, 2024
Acceptance Date March 3, 2024
Published in Issue Year 2024 Volume: 7 Issue: 1

Cite

APA Özkır, D. (2024). Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel. Eurasian Journal of Biological and Chemical Sciences, 7(1), 20-25. https://doi.org/10.46239/ejbcs.1425801
AMA Özkır D. Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel. Eurasian J. Bio. Chem. Sci. June 2024;7(1):20-25. doi:10.46239/ejbcs.1425801
Chicago Özkır, Demet. “Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel”. Eurasian Journal of Biological and Chemical Sciences 7, no. 1 (June 2024): 20-25. https://doi.org/10.46239/ejbcs.1425801.
EndNote Özkır D (June 1, 2024) Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel. Eurasian Journal of Biological and Chemical Sciences 7 1 20–25.
IEEE D. Özkır, “Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel”, Eurasian J. Bio. Chem. Sci., vol. 7, no. 1, pp. 20–25, 2024, doi: 10.46239/ejbcs.1425801.
ISNAD Özkır, Demet. “Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel”. Eurasian Journal of Biological and Chemical Sciences 7/1 (June 2024), 20-25. https://doi.org/10.46239/ejbcs.1425801.
JAMA Özkır D. Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel. Eurasian J. Bio. Chem. Sci. 2024;7:20–25.
MLA Özkır, Demet. “Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel”. Eurasian Journal of Biological and Chemical Sciences, vol. 7, no. 1, 2024, pp. 20-25, doi:10.46239/ejbcs.1425801.
Vancouver Özkır D. Oleaster Leaf Extract: A Potential Environmentally Friendly Inhibitor for Mild Steel. Eurasian J. Bio. Chem. Sci. 2024;7(1):20-5.