Use of Nano-Porous Calcium Silicate for Heavy Metal Removal from Aqueous Solutions
Abstract
Water is indispensable
for our life and fresh water resources are becoming rich by heavy metals
particularly by industrial wastes. Heavy metals are very harmful to the living
organisms and accumulated in the food chain. Removal of heavy metals are therefore
very important for protection of ecological systems. In this study, nano-porous
calcium silicate produced from Rice Hull Ash in the laboratory, was used for
the adsorption of copper, lead and zinc ions from an aqueous solution. The
three elements – copper, lead and zinc – were adsorbed on the calcium silicate
surface in ratios of 90-96 % in the first 15 minutes. Before and after the adsorption
experiments, FTIR analyses of calcium silicate samples were done to investigate
the adsorption type which can be chemical or physical.
Keywords
References
- Anupam, K., Dutta, S., Bhattacharjee, C. and Datta, S., 2011. Adsorptive removal of chromium (VI) from aqueous solution over powdered activated carbon: Optimization through response surface methodology. Chem. Eng. J. 173, 135-143.
- Borrmann, T., Edgar, K., McFarlane, A.J., Spencer, J.N. and Johnston, J.H., 2004. Calcium silicate-carbon nanotube composites. Current Applied Physics, 4, 359-361.
- Dai, Y., Zhang, K., Li, J., Jiang, Y. and Tanaka, S., 2017. Adsorption of copper and zinc onto carbon material in an aqueous solution oxidized by ammonium peroxydisulphate. Separation and Purification Technology, 186, 255-263.
- Ito, Y., Kusakawe, T., Ishida, M., Shibata, N. and Takada, K., 2005. Oral solid gentamicin preparation using emulsifier and adsorbent. J. of Controlled Release, 105, 23-31.
- Johnston, J.H., McFarlane, A.J., Borrmann, T. and Moraes, J., 2004. Nano structured silicas and silicates-new materials and their applications in Paper. Current Applied Physics, 4, 411-414. Johnston, J.H., McFarlane, A.J. and Borrmann, T., 2008. Nano-structured silicate, functionalized from thereof, preparation and uses. United States Patent and Trademark Office, No: 20080305027 dated 12.11.2008.
- Li, S.M., Jia, N., Zhu, J.F., Maa, M.G. and Sun, R.C., 2010. Synthesis of cellulose nanocomposites in ethanol/water mixed solvents and their characterization. Carbohydrate Polymers, 80, 270-275.
- Oglakci, A. and Baglar, B., 2010. Heavy Metal Desorption from the Surfaces of Calcium Silicate and Several Adsorbents. Graduation Project, Istanbul Technical University, Chemical Engineering Dept., Istanbul, Turkey.
- Pourshakiba, M., 2012. Production of Nano-Porous Calcium Silicate from Rice Hull Ash, Characterization and Use of heavy metal Adsorption. Msc. Thesis, İstanbul technical University, Chemical Engineering Dept., Istanbul, Turkey.
Details
Primary Language
English
Subjects
-
Journal Section
Research Article
Authors
Onur Yılmaz Özcan
*
This is me
Türkiye
Publication Date
December 1, 2018
Submission Date
June 12, 2018
Acceptance Date
July 9, 2018
Published in Issue
Year 2018 Volume: 2 Number: 2
