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Comparison of Graphene Oxide-Titanium Oxide (GO-TiO2) Composite Film Coating Methods on Glass Substrates and Surface Characterization Study

Year 2024, Volume: 14 Issue: 2, 174 - 181

Abstract

In this work, graphene oxide-titanium oxide (GO-TiO2) nanocomposite was successfully produced via ultrasonication process. For coating process, spin coating (SC), dip coating (DC) and spray coating methods were used. The synthesized nanocomposite and surfaces were characterized by optical microscope, SEM, EDX, FTIR, XRD, four-probe conductivity, water contact angle.
As result of experiments, while spin coating provides thinner coating, a thicker and higher water contact angle surface was formed under the optimum condition of dip coating. XRD, four-probe conductivity results revealed partial formation of reduced graphene oxide within the composite structure. Water contact angle results showed that the best result regarding stability of droplet shape was on the spin coated surface. On the other hand, it was observed that deionized water test liquid droplet on the dip coated surfaces stabilized relatively slower but provided a much higher water contact angle.

Project Number

120M992BSEU

Thanks

This study was compiled from the results of the study carried out within the scope of project number 120M992BSEU supported by The Scientific and Technological Research Council of Turkey (TÜBİTAK). The researchers thank TÜBİTAK.

References

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  • [2] Aydin, H. (2019). The effect of graphene oxide on the structural and electrical properties of yttrium ferrite based nanopowders. European Journal of Technique (EJT), 9(1), 84-98.
  • [3] Aydin, C. (2018). The Characterization of Morphology, Chemical and Optical Properties of Perylene Based Organic Nanocomposites Modified with Graphene Oxide. European Journal of Technique (Ejt), 8(1), 99-109.
  • [4] Chen, X., & Mao, S. S. (2007). Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications. Chemical Reviews, 107(7), 2891-2959.
  • [5] Liu, X., Chen, C., Chen, X. A., Qian, G., Wang, J., Wang, C., ... & Liu, Q. (2018). WO3 QDs enhanced photocatalytic and electrochemical perfomance of GO/TiO2 composite. Catalysis Today, 315, 155-161.
  • [6] Acir, A., Emin Canlı, M., Ata, I., & Erdi Tanürün, H. (2019). Effects of a circular-shaped turbulator having varying hole numbers on energy and exergy efficiencies of a solar air heater. International Journal of Ambient Energy, 40(7), 739-748.
  • [7] Acir, A., Canli, M. E., Ata, I., Uzun, S., & Tanürün, H. E. (2021). Experimental Investigation of Thermal Energy Storage Efficiency Using Fin Application with Phase Change Material (PCM) under solar radiation. Heat Transfer Research, 52(6).
  • [8] Kamat, P. V. (2010). Graphene-based nanoarchitectures. Anchoring semiconductor and metal nanoparticles on a two-dimensional carbon support. The Journal of Physical Chemistry Letters, 1(2), 520-527.
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  • [12] Wu, X. (2021). Applications of titanium dioxide materials. Titanium Dioxide-Advances and Applications.
  • [13] Vinodhkumar, G., Wilson, J., Inbanathan, S. S. R., Potheher, I. V., Ashokkumar, M., & Peter, A. C. (2020). Solvothermal synthesis of magnetically separable reduced graphene oxide/Fe3O4 hybrid nanocomposites with enhanced photocatalytic properties. Physica B: Condensed Matter, 580, 411752.
  • [14] Magesan, P., Ganesan, P., & Umapathy, M. J. (2016). Ultrasonic-assisted synthesis of doped TiO2 nanocomposites: characterization and evaluation of photocatalytic and antimicrobial activity. Optik, 127(13), 5171-5180.
  • [15] Fattahi, A., Liang, R., Kaur, A., Schneider, O., Arlos, M. J., Peng, P., ... & Zhou, N. (2019). Photocatalytic degradation using TiO2-graphene nanocomposite under UV-LED illumination: Optimization using response surface methodology. Journal of Environmental Chemical Engineering, 7(5), 103366.
  • [16] Deshmukh, S. P., Kale, D. P., Kar, S., Shirsath, S. R., Bhanvase, B. A., Saharan, V. K., & Sonawane, S. H. (2020). Ultrasound assisted preparation of rGO/TiO2 nanocomposite for effective photocatalytic degradation of methylene blue under sunlight. Nano-Structures & Nano-Objects, 21, 100407.
  • [17] Eda, G., & Chhowalla, M. (2009). Graphene-based composite thin films for electronics. Nano Letters, 9(2), 814-818.
  • [18] Nine, M. J., Cole, M. A., Johnson, L., Tran, D. N., & Losic, D. (2015). Robust superhydrophobic graphene-based composite coatings with self-cleaning and corrosion barrier properties. ACS applied materials & interfaces, 7(51), 28482-28493
  • [19] Kumaran, V., Sudhagar, P., Konga, A. K., & Ponniah, G. (2020). Photocatalytic degradation of synthetic organic reactive dye wastewater using GO-TiO2 nanocomposite. Polish Journal of Environmental Studies, 29(2), 1683-1690.
  • [20] Liang, J., Zhao, Y., Guo, L., & Li, L. (2012). Flexible free-standing graphene/SnO2 nanocomposites paper for Li-ion battery. ACS applied materials & interfaces, 4(11), 5742-5748.
  • [21] Liang, Y., Wang, H., Sanchez Casalongue, H., Chen, Z., & Dai, H. (2010). TiO2 nanocrystals grown on graphene as advanced photocatalytic hybrid materials. Nano Research, 3, 701-705.
  • [22] Atalay Gengeç, N. (2021). The Effect of Graphene Oxide Exfoliation Degree on Graphene Film Properties. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 8(1), 345-355.
  • [23] Ribao, P., Rivero, M. J., & Ortiz, I. (2017). TiO2 structures doped with noble metals and/or graphene oxide to improve the photocatalytic degradation of dichloroacetic acid. Environmental Science and Pollution Research, 24, 12628-12637.
  • [24] Raja, R., Govindaraj, M., Antony, M. D., Krishnan, K., Velusamy, E., Sambandam, A., ... & Rayar, V. W. (2017). Effect of TiO2/reduced graphene oxide composite thin film as a blocking layer on the efficiency of dye-sensitized solar cells. Journal of Solid State Electrochemistry, 21, 891-903.
  • [25] Joshi, N. C., Congthak, R., & Gururani, P. (2020). Synthesis, adsorptive performances and photo-catalytic activity of graphene oxide/TiO2 (GO/TiO2) nanocomposite-based adsorbent. Nanotechnology for Environmental Engineering, 5, 1-13.
  • [26] He, R., & He, W. (2016). Ultrasonic assisted synthesis of TiO2–reduced graphene oxide nanocomposites with superior photovoltaic and photocatalytic activities. Ceramics International, 42(5), 5766-5771.
  • [27] Timoumi, A., Alamri, S. N., & Alamri, H. (2018). The development of TiO2-graphene oxide nano composite thin films for solar cells. Results in physics, 11, 46-51.
  • [28] Akhair, S. M., Harun, Z., Jamalludin, M. R., Shuhor, M. F., Kamarudin, N. H., Yunos, M. Z., ... & Azhar, M. F. H. (2017). Effect of graphene oxide with controlled stirring time. Chemical Engineering Transactions, 56, 709-714.
  • [29] Rommozzi, E., Zannotti, M., Giovannetti, R., D’Amato, C. A., Ferraro, S., Minicucci, M., ... & Di Cicco, A. (2018). Reduced graphene oxide/TiO2 nanocomposite: from synthesis to characterization for efficient visible light photocatalytic applications. Catalysts, 8(12), 598.
  • [30] Bera, M., Gupta, P., & Maji, P. K. (2018). Facile one-pot synthesis of graphene oxide by sonication assisted mechanochemical approach and its surface chemistry. Journal of nanoscience and nanotechnology, 18(2), 902-912.
  • [31] Dai, J. F., Wang, G. J., Ma, L., & Wu, C. K. (2015). Surface properties of graphene: relationship to graphene-polymer composites. Rev. Adv. Mater. Sci, 40(1), 60-71. Scidà, A., Haque, S., Treossi, E., Robinson, A., Smerzi, S., Ravesi, S., ... & Palermo, V. (2018). Application of graphene-based flexible antennas in consumer electronic devices. Materials Today, 21(3), 223-
Year 2024, Volume: 14 Issue: 2, 174 - 181

Abstract

Project Number

120M992BSEU

References

  • [1] Hummers, W. S., & Offeman, R. E. (1958). Preparation of Graphitic Oxide. Journal of the American Chemical Society, 80(6), 1339.
  • [2] Aydin, H. (2019). The effect of graphene oxide on the structural and electrical properties of yttrium ferrite based nanopowders. European Journal of Technique (EJT), 9(1), 84-98.
  • [3] Aydin, C. (2018). The Characterization of Morphology, Chemical and Optical Properties of Perylene Based Organic Nanocomposites Modified with Graphene Oxide. European Journal of Technique (Ejt), 8(1), 99-109.
  • [4] Chen, X., & Mao, S. S. (2007). Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications. Chemical Reviews, 107(7), 2891-2959.
  • [5] Liu, X., Chen, C., Chen, X. A., Qian, G., Wang, J., Wang, C., ... & Liu, Q. (2018). WO3 QDs enhanced photocatalytic and electrochemical perfomance of GO/TiO2 composite. Catalysis Today, 315, 155-161.
  • [6] Acir, A., Emin Canlı, M., Ata, I., & Erdi Tanürün, H. (2019). Effects of a circular-shaped turbulator having varying hole numbers on energy and exergy efficiencies of a solar air heater. International Journal of Ambient Energy, 40(7), 739-748.
  • [7] Acir, A., Canli, M. E., Ata, I., Uzun, S., & Tanürün, H. E. (2021). Experimental Investigation of Thermal Energy Storage Efficiency Using Fin Application with Phase Change Material (PCM) under solar radiation. Heat Transfer Research, 52(6).
  • [8] Kamat, P. V. (2010). Graphene-based nanoarchitectures. Anchoring semiconductor and metal nanoparticles on a two-dimensional carbon support. The Journal of Physical Chemistry Letters, 1(2), 520-527.
  • [9] Zhang, L., Liu, Q., & Sun, Y. (2020). Enhanced photocatalytic activity of GO-TiO2 composites: The role of GO in the nanocomposite. Applied Catalysis B: Environmental, 260, 118195. https://doi.org/10.1016/j.apcatb.2019.118195
  • [10] Chong, M. N., Jin, B., Chow, C. W. K., & Saint, C. (2010). Recent developments in photocatalytic water treatment technology: A review. Water Research, 44(10), 2997-3027.
  • [11] Zafar, M., Imran, S. M., Iqbal, I., Azeem, M., Chaudhary, S., Ahmad, S., & Kim, W. Y. (2024). Graphene-based polymer nanocomposites for energy applications: Recent advancements and future prospects. Results in Physics, 107655.
  • [12] Wu, X. (2021). Applications of titanium dioxide materials. Titanium Dioxide-Advances and Applications.
  • [13] Vinodhkumar, G., Wilson, J., Inbanathan, S. S. R., Potheher, I. V., Ashokkumar, M., & Peter, A. C. (2020). Solvothermal synthesis of magnetically separable reduced graphene oxide/Fe3O4 hybrid nanocomposites with enhanced photocatalytic properties. Physica B: Condensed Matter, 580, 411752.
  • [14] Magesan, P., Ganesan, P., & Umapathy, M. J. (2016). Ultrasonic-assisted synthesis of doped TiO2 nanocomposites: characterization and evaluation of photocatalytic and antimicrobial activity. Optik, 127(13), 5171-5180.
  • [15] Fattahi, A., Liang, R., Kaur, A., Schneider, O., Arlos, M. J., Peng, P., ... & Zhou, N. (2019). Photocatalytic degradation using TiO2-graphene nanocomposite under UV-LED illumination: Optimization using response surface methodology. Journal of Environmental Chemical Engineering, 7(5), 103366.
  • [16] Deshmukh, S. P., Kale, D. P., Kar, S., Shirsath, S. R., Bhanvase, B. A., Saharan, V. K., & Sonawane, S. H. (2020). Ultrasound assisted preparation of rGO/TiO2 nanocomposite for effective photocatalytic degradation of methylene blue under sunlight. Nano-Structures & Nano-Objects, 21, 100407.
  • [17] Eda, G., & Chhowalla, M. (2009). Graphene-based composite thin films for electronics. Nano Letters, 9(2), 814-818.
  • [18] Nine, M. J., Cole, M. A., Johnson, L., Tran, D. N., & Losic, D. (2015). Robust superhydrophobic graphene-based composite coatings with self-cleaning and corrosion barrier properties. ACS applied materials & interfaces, 7(51), 28482-28493
  • [19] Kumaran, V., Sudhagar, P., Konga, A. K., & Ponniah, G. (2020). Photocatalytic degradation of synthetic organic reactive dye wastewater using GO-TiO2 nanocomposite. Polish Journal of Environmental Studies, 29(2), 1683-1690.
  • [20] Liang, J., Zhao, Y., Guo, L., & Li, L. (2012). Flexible free-standing graphene/SnO2 nanocomposites paper for Li-ion battery. ACS applied materials & interfaces, 4(11), 5742-5748.
  • [21] Liang, Y., Wang, H., Sanchez Casalongue, H., Chen, Z., & Dai, H. (2010). TiO2 nanocrystals grown on graphene as advanced photocatalytic hybrid materials. Nano Research, 3, 701-705.
  • [22] Atalay Gengeç, N. (2021). The Effect of Graphene Oxide Exfoliation Degree on Graphene Film Properties. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 8(1), 345-355.
  • [23] Ribao, P., Rivero, M. J., & Ortiz, I. (2017). TiO2 structures doped with noble metals and/or graphene oxide to improve the photocatalytic degradation of dichloroacetic acid. Environmental Science and Pollution Research, 24, 12628-12637.
  • [24] Raja, R., Govindaraj, M., Antony, M. D., Krishnan, K., Velusamy, E., Sambandam, A., ... & Rayar, V. W. (2017). Effect of TiO2/reduced graphene oxide composite thin film as a blocking layer on the efficiency of dye-sensitized solar cells. Journal of Solid State Electrochemistry, 21, 891-903.
  • [25] Joshi, N. C., Congthak, R., & Gururani, P. (2020). Synthesis, adsorptive performances and photo-catalytic activity of graphene oxide/TiO2 (GO/TiO2) nanocomposite-based adsorbent. Nanotechnology for Environmental Engineering, 5, 1-13.
  • [26] He, R., & He, W. (2016). Ultrasonic assisted synthesis of TiO2–reduced graphene oxide nanocomposites with superior photovoltaic and photocatalytic activities. Ceramics International, 42(5), 5766-5771.
  • [27] Timoumi, A., Alamri, S. N., & Alamri, H. (2018). The development of TiO2-graphene oxide nano composite thin films for solar cells. Results in physics, 11, 46-51.
  • [28] Akhair, S. M., Harun, Z., Jamalludin, M. R., Shuhor, M. F., Kamarudin, N. H., Yunos, M. Z., ... & Azhar, M. F. H. (2017). Effect of graphene oxide with controlled stirring time. Chemical Engineering Transactions, 56, 709-714.
  • [29] Rommozzi, E., Zannotti, M., Giovannetti, R., D’Amato, C. A., Ferraro, S., Minicucci, M., ... & Di Cicco, A. (2018). Reduced graphene oxide/TiO2 nanocomposite: from synthesis to characterization for efficient visible light photocatalytic applications. Catalysts, 8(12), 598.
  • [30] Bera, M., Gupta, P., & Maji, P. K. (2018). Facile one-pot synthesis of graphene oxide by sonication assisted mechanochemical approach and its surface chemistry. Journal of nanoscience and nanotechnology, 18(2), 902-912.
  • [31] Dai, J. F., Wang, G. J., Ma, L., & Wu, C. K. (2015). Surface properties of graphene: relationship to graphene-polymer composites. Rev. Adv. Mater. Sci, 40(1), 60-71. Scidà, A., Haque, S., Treossi, E., Robinson, A., Smerzi, S., Ravesi, S., ... & Palermo, V. (2018). Application of graphene-based flexible antennas in consumer electronic devices. Materials Today, 21(3), 223-
There are 31 citations in total.

Details

Primary Language English
Subjects Mechanical Engineering (Other)
Journal Section Research Article
Authors

İbrahim Fırat Balkaya 0000-0002-7674-196X

Project Number 120M992BSEU
Early Pub Date January 13, 2025
Publication Date
Submission Date August 20, 2024
Acceptance Date September 9, 2024
Published in Issue Year 2024 Volume: 14 Issue: 2

Cite

APA Balkaya, İ. F. (2025). Comparison of Graphene Oxide-Titanium Oxide (GO-TiO2) Composite Film Coating Methods on Glass Substrates and Surface Characterization Study. European Journal of Technique (EJT), 14(2), 174-181. https://doi.org/10.36222/ejt.1536083

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