Year 2025,
Volume: 9 Issue: 2, 196 - 206, 20.06.2025
Hülya Temizer
,
Özlem Çavdar
Project Number
GÜBAP 2907-23.E3101.07.01
References
- Adak, D., Sarkar, M., & Mandal, S. (2014). Effect of nano-silica on strength and durability of fly ash based geopolymer mortar. Construction and Building Materials, 70, 453–459. https://doi.org/10.1016/j.conbuildmat.2014.07.093
- Çavdar, A., & Yetgin, Ş. (2009). The effect of particle fineness on properties of Portland pozzolan cement mortars. Turkish Journal of Science & Technology, 4(1).
- Çavdar, Ö., & Temizer, H. (2025). The regression analysis and determination of mechanical and physical properties on geopolymer composites under thermal and water curing. Thermal Science. https://doi.org/10.2298/TSCI250216091C
- Naskar, S., & Chakraborty, A. K. (2016). Effect of nano materials in geopolymer concrete. Perspectives in Science, 8, 273–275. https://doi.org/10.1016/j.pisc.2016.04.049
- Nergis, D. D. B., Vizureanu, P., Sandu, A. V., Nergis, D. P. B., & Bejinariu, C. (2022). XRD and TG-DTA study of new phosphate-based geopolymers with coal ash or metakaolin as aluminosilicate source and mine tailings addition. Materials, 15, 202. https://doi.org/10.3390/ma15010202
- Chithambaram, S. J., Kumar, S., & Prasad, M. M. (2019). Thermo-mechanical characteristics of geopolymer mortar. Construction and Building Materials, 213, 100–108. https://doi.org/10.1016/j.conbuildmat.2019.04.051
- Huseien, G. F., Sam, A. R. M. S., & Alyousef, R. (2021). Texture, morphology and strength performance of self-compacting alkali-activated concrete: Role of fly ash as GBFS replacement. Construction and Building Materials, 270, 121368. https://doi.org/10.1016/j.conbuildmat.2020.121368
- Shang, J., Dai, J. G., Zhao, T. J., Guo, S. Y., Zhang, P., & Mu, B. (2018). Alternation of traditional cement mortars using fly ash-based geopolymer mortars modified by slag. Journal of Cleaner Production, 203, 746–756. https://doi.org/10.1016/j.jclepro.2018.08.255
- Hager, I., Sitarz, M., & Mróz, K. (2021). Fly-ash based geopolymer mortar for high-temperature application: Effect of slag addition. Journal of Cleaner Production, 316, 128168. https://doi.org/10.1016/j.jclepro.2021.128168
- Başpınar, S., & Kurtuluş, C. (2018). Effect of composition on geopolymer foam concrete basic properties. AKÜ IJETAS, 1, 5–10.
- Raj, P. K. A., Sarath, D., Nagarajan, P., & Thomas, B. S. (2024). A simplified mix design for GGBS–dolomite geopolymer concrete using the Taguchi method. Iranian Journal of Science and Technology, Transactions of Civil Engineering, 48, 3189–3212. https://doi.org/10.1007/s40996-024-01354-4
- Yıldız, S. (2023). Investigation of mechanical and durability properties of geopolymer concretes produced with industrial by-products [PhD thesis, Kocaeli University].
- Chokkalingam, P., El-Hassan, H., El-Dieb, A., & El-Mir, A. (2022). Development and characterization of ceramic waste powder-slag blended geopolymer concrete designed using Taguchi method. Construction and Building Materials, 349, 128744. https://doi.org/10.1016/j.conbuildmat.2022.128744
- Yüksek, S., & Kaya, S. (2017). Building material production from fly ash, lime and gypsum. APJES, 5(3), 58–70.
- Çavdar, A., & Yetgin, Ş. (2005). The effects of trass addition ratio on strength, setting time, and soundness properties of trass–cement. Science and Engineering Journal of Fırat University, 17(4), 687–692.
- Çavdar, A., & Çavdar, Ö. (2024). Availability of sedimentary and volcanic rock deposits on Northeastern Turkey as concrete aggregates. Physics and Chemistry of the Earth, 134. https://doi.org/10.1016/j.pce.2024.103567
- Erem, A. D., & Özcan, G. (2015). Polypropylene/titanium dioxide nanocomposite fiber production and characterization. Journal of Textiles and Engineer, 22(99), 1–6. https://doi.org/10.7216/130075992015229901
- Mengeloğlu, F., & Çavuş, V. (2019). Effect of titanium dioxide (nm and µm TiO₂) on some mechanical properties of wood plastic composites. In MAS International European Conference on Mathematics-Engineering-Natural & Medical Sciences-X (pp. 1–6). İzmir, Türkiye.
- Mohammed, D. T., & Yaltay, N. (2024). Strength and elevated temperature resistance properties of the geopolymer paste produced with ground granulated blast furnace slag and pumice powder. Ain Shams Engineering Journal, 15(3), 102483. https://doi.org/10.1016/j.asej.2023.102483
- Temizer, H., & Çavdar, Ö. (2024). Effects on geopolymer mortars of the blast-furnace slags obtained from different regions. In 3rd International Conference on Contemporary Academic Research, November 10–11, Konya, Turkey.
- Yousuf, M., & Khan, R. A. (2021). Mechanical and microstructural characteristics of sustainable geopolymer concrete using industrial by-products. Journal of Cleaner Production, 282, 124517. https://doi.org/10.1016/j.jclepro.2020.124517
- Ali, M. A., & Ahmed, S. F. (2022). Utilization of marble waste in geopolymer concrete for sustainable construction. Construction and Building Materials, 320, 126212. https://doi.org/10.1016/j.conbuildmat.2021.126212
Microstructural investigation of geopolymer composites obtained from recyclable waste materials
Year 2025,
Volume: 9 Issue: 2, 196 - 206, 20.06.2025
Hülya Temizer
,
Özlem Çavdar
Abstract
Today, researchers are exploring materials that could replace cement and provide solutions for utilizing waste products. In this study, a binder was formulated using 85% blast furnace slag and 15% fly ash. Three different additives—marble powder, strontium mineral waste, and titanium dioxide—were incorporated as partial replacements for blast furnace slag at ratios of 5%, 5%, and 1%, respectively, to create geopolymer mortars. The impact of these additives on the flexural and compressive strength of the mortars was evaluated. Furthermore, SEM/EDX analysis was performed to assess the microstructural effects of the additives. The findings revealed that titanium dioxide resulted in the highest compressive strength, recorded at 65.7 MPa. The SEM/EDX analysis suggested that the samples demonstrated a homogeneous internal structure, indicating a robust bond among the components of the matrix.
Ethical Statement
This study has not been published anywhere before or is not under evaluation.
Project Number
GÜBAP 2907-23.E3101.07.01
Thanks
This study was supported by Gümüşhane University GÜBAP unit with the project number 2907-23.E3101.07.01.
References
- Adak, D., Sarkar, M., & Mandal, S. (2014). Effect of nano-silica on strength and durability of fly ash based geopolymer mortar. Construction and Building Materials, 70, 453–459. https://doi.org/10.1016/j.conbuildmat.2014.07.093
- Çavdar, A., & Yetgin, Ş. (2009). The effect of particle fineness on properties of Portland pozzolan cement mortars. Turkish Journal of Science & Technology, 4(1).
- Çavdar, Ö., & Temizer, H. (2025). The regression analysis and determination of mechanical and physical properties on geopolymer composites under thermal and water curing. Thermal Science. https://doi.org/10.2298/TSCI250216091C
- Naskar, S., & Chakraborty, A. K. (2016). Effect of nano materials in geopolymer concrete. Perspectives in Science, 8, 273–275. https://doi.org/10.1016/j.pisc.2016.04.049
- Nergis, D. D. B., Vizureanu, P., Sandu, A. V., Nergis, D. P. B., & Bejinariu, C. (2022). XRD and TG-DTA study of new phosphate-based geopolymers with coal ash or metakaolin as aluminosilicate source and mine tailings addition. Materials, 15, 202. https://doi.org/10.3390/ma15010202
- Chithambaram, S. J., Kumar, S., & Prasad, M. M. (2019). Thermo-mechanical characteristics of geopolymer mortar. Construction and Building Materials, 213, 100–108. https://doi.org/10.1016/j.conbuildmat.2019.04.051
- Huseien, G. F., Sam, A. R. M. S., & Alyousef, R. (2021). Texture, morphology and strength performance of self-compacting alkali-activated concrete: Role of fly ash as GBFS replacement. Construction and Building Materials, 270, 121368. https://doi.org/10.1016/j.conbuildmat.2020.121368
- Shang, J., Dai, J. G., Zhao, T. J., Guo, S. Y., Zhang, P., & Mu, B. (2018). Alternation of traditional cement mortars using fly ash-based geopolymer mortars modified by slag. Journal of Cleaner Production, 203, 746–756. https://doi.org/10.1016/j.jclepro.2018.08.255
- Hager, I., Sitarz, M., & Mróz, K. (2021). Fly-ash based geopolymer mortar for high-temperature application: Effect of slag addition. Journal of Cleaner Production, 316, 128168. https://doi.org/10.1016/j.jclepro.2021.128168
- Başpınar, S., & Kurtuluş, C. (2018). Effect of composition on geopolymer foam concrete basic properties. AKÜ IJETAS, 1, 5–10.
- Raj, P. K. A., Sarath, D., Nagarajan, P., & Thomas, B. S. (2024). A simplified mix design for GGBS–dolomite geopolymer concrete using the Taguchi method. Iranian Journal of Science and Technology, Transactions of Civil Engineering, 48, 3189–3212. https://doi.org/10.1007/s40996-024-01354-4
- Yıldız, S. (2023). Investigation of mechanical and durability properties of geopolymer concretes produced with industrial by-products [PhD thesis, Kocaeli University].
- Chokkalingam, P., El-Hassan, H., El-Dieb, A., & El-Mir, A. (2022). Development and characterization of ceramic waste powder-slag blended geopolymer concrete designed using Taguchi method. Construction and Building Materials, 349, 128744. https://doi.org/10.1016/j.conbuildmat.2022.128744
- Yüksek, S., & Kaya, S. (2017). Building material production from fly ash, lime and gypsum. APJES, 5(3), 58–70.
- Çavdar, A., & Yetgin, Ş. (2005). The effects of trass addition ratio on strength, setting time, and soundness properties of trass–cement. Science and Engineering Journal of Fırat University, 17(4), 687–692.
- Çavdar, A., & Çavdar, Ö. (2024). Availability of sedimentary and volcanic rock deposits on Northeastern Turkey as concrete aggregates. Physics and Chemistry of the Earth, 134. https://doi.org/10.1016/j.pce.2024.103567
- Erem, A. D., & Özcan, G. (2015). Polypropylene/titanium dioxide nanocomposite fiber production and characterization. Journal of Textiles and Engineer, 22(99), 1–6. https://doi.org/10.7216/130075992015229901
- Mengeloğlu, F., & Çavuş, V. (2019). Effect of titanium dioxide (nm and µm TiO₂) on some mechanical properties of wood plastic composites. In MAS International European Conference on Mathematics-Engineering-Natural & Medical Sciences-X (pp. 1–6). İzmir, Türkiye.
- Mohammed, D. T., & Yaltay, N. (2024). Strength and elevated temperature resistance properties of the geopolymer paste produced with ground granulated blast furnace slag and pumice powder. Ain Shams Engineering Journal, 15(3), 102483. https://doi.org/10.1016/j.asej.2023.102483
- Temizer, H., & Çavdar, Ö. (2024). Effects on geopolymer mortars of the blast-furnace slags obtained from different regions. In 3rd International Conference on Contemporary Academic Research, November 10–11, Konya, Turkey.
- Yousuf, M., & Khan, R. A. (2021). Mechanical and microstructural characteristics of sustainable geopolymer concrete using industrial by-products. Journal of Cleaner Production, 282, 124517. https://doi.org/10.1016/j.jclepro.2020.124517
- Ali, M. A., & Ahmed, S. F. (2022). Utilization of marble waste in geopolymer concrete for sustainable construction. Construction and Building Materials, 320, 126212. https://doi.org/10.1016/j.conbuildmat.2021.126212