Research Article
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GREEN REDUCTION OF GRAPHENE OXIDE BY USING KOMBUCHA TEA

Year 2019, Volume: 20 , 24 - 29, 16.12.2019
https://doi.org/10.18038/estubtda.630211

Abstract

In this study, a simple and efficient
method of reduction for the preparation of reduced graphene oxide (RGO) from
graphene oxide (GO) using Kombucha Tea (KT) is reported. The graphene oxides
(GOs) were produced from natural graphite (Gr) powders based on Hummers’
method. KT was used as natural reductants to reduction of GO. Polyphenol
content of KT was determined by using Folin-Cioceltau method. KT and GO were
mixed in certain ratios to reduce graphene oxide (RGO) at room temperature. RGO
was characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy
(SEM) and Fourer Transform Infrared (FTIR). It was clearly observed that the
functional groups containing oxygen were reduced as a result of the analyzes.

Supporting Institution

Cumhuriyet University

Project Number

M702

Thanks

This study was supported by Sivas Cumhuriyet University Scientific Research Projects (CÜBAP), project number as M702.

References

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  • Joung D, Singh V, Park S, Schulte A, Seal S, Khondaker SI. Anchoring Ceria Nanoparticles on Reduced Graphene Oxide and Their Electronic Transport Properties. |J. Phys. Chem C 2011; 115: 24494–24500.
  • F.Y. Ban FY, Majid SR, Huang2 NM, Lim HN. Graphene Oxide and Its Electrochemical Performance. Int. J. Electrochem. Sci 2012; 7: 4345 – 4351.
  • Zhu L, Zhao Z, Li Y, Yu X, Li C, Zhang Q. High-quality production of graphene by liquid-phase exfoliation of expanded graphite. Materials Chemistry and Physics 2013; 137: 894-990.
  • Alazmi A, Rasul S, Patole SP, Costa PM.F.J. Comparative study of synthesis and reduction methods for graphene oxide. Polyhedron 2016; 116: 153–161.
  • Zhu L, Zhao X, Li Y, Yu X, Li C, Zhang Q. High-quality production of graphene by liquid-phase exfoliation of expanded graphite. Materials Chemistry and Physics 2013;3 137 (2013): 984- 990.
  • Thakur S, Karak N. Alternative methods and nature-based reagents for the reduction of graphene oxide: A review. Carbon 2015; 94: 224–242.
  • Hou D, Liu Q, Cheng H, Zhang H, Wang S. Green reduction of graphene oxide via Lycium barbarum extract. Journal of Solid State Chemistry 2017; 246: 351–356.
  • Suresh D, Udayabhanu, Kumar M.A.P, Nagabhushana H, Sharma SC. Cinnamon supported facile green reduction of graphene oxide, its dye elimination and antioxidant activities. Materials Letters 2015; 151: 93–95.
  • Hou D, Liu Q, Cheng H, Li K, Wang D, Zhang H. Chrysanthemum extract assisted green reduction of graphene oxide. Materials Chemistry and Physics 2016;183: 76-82.
  • Gurunathan S, Han JW, Eppakayala V, Kim JH. Green synthesis of graphene and its cytotoxic effects in human breast cancer cells. International Journal of Nanomedicine 2013; 8 :1015–1027.
  • Noreen H, Semmar N, Farman M, McCullagh JSO. Measurement of total phenolic content and antioxidant activity of aerial parts of medicinal plant Coronopus didymus. Asian Pacific Journal of Tropical Medicine 2017; 10(8): 792–801.
  • Guo J, Zhu S, Chen Z, Li Y, Yu Z, Liu Q, Li J, Feng C, Zhang D. Sonochemical synthesis of TiO2 nanoparticles on graphene for use as photocatalyst. Ultrasonics Sonochemistry 2011; 18: 1082–1090.
  • Hou D, Liu Q, Wang X, Quan Y, Qiao Z ,Yu Li , Ding S. Facile synthesis of graphene via reduction of graphene oxide by artemisinin in ethanol. Journal of Materiomics 2018; 4 :256-265.
  • Andrijanto, E., Shoelarta, S., Subiyanto, G., Rifki, S., (2015). Facile Synthesis of Graphene from Graphite Using Ascorbic Acid as Reducing Agent, The 3rd International Conference on Advanced Materials Science and Technology (ICAMST 2015)
  • Rahmanian, N., Hamishehkar, H., Dolatabadi, J., E., N., Arrsalani, N. (2014). Nano graphene oxide: A novel carrier for oral delivery of flavonoids, Colloids and Surfaces B: Biointerfaces 123, 331–338.
  • Tiyek, İ., Dönmez, U., Yıldırım, B., Alma, M., A., Ersoy, M., S., Karataş, Ş., Yazıcı, M. (2016). Kimyasal yöntem ile indirgenmiş grafen oksit sentezi ve karakterizasyonu, SAÜ Fen Bil Der 20, 349-357.
  • Romero, A., Lavin-Lopez, M., P., Sanchez-Silva, L., Valverde, J., L., Paton-Carrero, A. (2018). Comparative study of different scalable routes to synthesize graphene oxide and reduced graphene oxide, Materials Chemistry and Physics 203, 284-292.
Year 2019, Volume: 20 , 24 - 29, 16.12.2019
https://doi.org/10.18038/estubtda.630211

Abstract

Project Number

M702

References

  • Puangjan A, Chaiyasith S. An efficient ZrO2/Co3O4/reduced graphene oxide nanocomposite electrochemical sensor for simultaneous determination of gallic acid, caffeic acid and protocatechuic acid natural antioxidants. Electrochimica Acta 2016; 211: 273–288.
  • Joung D, Singh V, Park S, Schulte A, Seal S, Khondaker SI. Anchoring Ceria Nanoparticles on Reduced Graphene Oxide and Their Electronic Transport Properties. |J. Phys. Chem C 2011; 115: 24494–24500.
  • F.Y. Ban FY, Majid SR, Huang2 NM, Lim HN. Graphene Oxide and Its Electrochemical Performance. Int. J. Electrochem. Sci 2012; 7: 4345 – 4351.
  • Zhu L, Zhao Z, Li Y, Yu X, Li C, Zhang Q. High-quality production of graphene by liquid-phase exfoliation of expanded graphite. Materials Chemistry and Physics 2013; 137: 894-990.
  • Alazmi A, Rasul S, Patole SP, Costa PM.F.J. Comparative study of synthesis and reduction methods for graphene oxide. Polyhedron 2016; 116: 153–161.
  • Zhu L, Zhao X, Li Y, Yu X, Li C, Zhang Q. High-quality production of graphene by liquid-phase exfoliation of expanded graphite. Materials Chemistry and Physics 2013;3 137 (2013): 984- 990.
  • Thakur S, Karak N. Alternative methods and nature-based reagents for the reduction of graphene oxide: A review. Carbon 2015; 94: 224–242.
  • Hou D, Liu Q, Cheng H, Zhang H, Wang S. Green reduction of graphene oxide via Lycium barbarum extract. Journal of Solid State Chemistry 2017; 246: 351–356.
  • Suresh D, Udayabhanu, Kumar M.A.P, Nagabhushana H, Sharma SC. Cinnamon supported facile green reduction of graphene oxide, its dye elimination and antioxidant activities. Materials Letters 2015; 151: 93–95.
  • Hou D, Liu Q, Cheng H, Li K, Wang D, Zhang H. Chrysanthemum extract assisted green reduction of graphene oxide. Materials Chemistry and Physics 2016;183: 76-82.
  • Gurunathan S, Han JW, Eppakayala V, Kim JH. Green synthesis of graphene and its cytotoxic effects in human breast cancer cells. International Journal of Nanomedicine 2013; 8 :1015–1027.
  • Noreen H, Semmar N, Farman M, McCullagh JSO. Measurement of total phenolic content and antioxidant activity of aerial parts of medicinal plant Coronopus didymus. Asian Pacific Journal of Tropical Medicine 2017; 10(8): 792–801.
  • Guo J, Zhu S, Chen Z, Li Y, Yu Z, Liu Q, Li J, Feng C, Zhang D. Sonochemical synthesis of TiO2 nanoparticles on graphene for use as photocatalyst. Ultrasonics Sonochemistry 2011; 18: 1082–1090.
  • Hou D, Liu Q, Wang X, Quan Y, Qiao Z ,Yu Li , Ding S. Facile synthesis of graphene via reduction of graphene oxide by artemisinin in ethanol. Journal of Materiomics 2018; 4 :256-265.
  • Andrijanto, E., Shoelarta, S., Subiyanto, G., Rifki, S., (2015). Facile Synthesis of Graphene from Graphite Using Ascorbic Acid as Reducing Agent, The 3rd International Conference on Advanced Materials Science and Technology (ICAMST 2015)
  • Rahmanian, N., Hamishehkar, H., Dolatabadi, J., E., N., Arrsalani, N. (2014). Nano graphene oxide: A novel carrier for oral delivery of flavonoids, Colloids and Surfaces B: Biointerfaces 123, 331–338.
  • Tiyek, İ., Dönmez, U., Yıldırım, B., Alma, M., A., Ersoy, M., S., Karataş, Ş., Yazıcı, M. (2016). Kimyasal yöntem ile indirgenmiş grafen oksit sentezi ve karakterizasyonu, SAÜ Fen Bil Der 20, 349-357.
  • Romero, A., Lavin-Lopez, M., P., Sanchez-Silva, L., Valverde, J., L., Paton-Carrero, A. (2018). Comparative study of different scalable routes to synthesize graphene oxide and reduced graphene oxide, Materials Chemistry and Physics 203, 284-292.
There are 18 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Sevil Cetınkaya Gürer 0000-0001-5421-0474

Project Number M702
Publication Date December 16, 2019
Published in Issue Year 2019 Volume: 20

Cite

AMA Cetınkaya Gürer S. GREEN REDUCTION OF GRAPHENE OXIDE BY USING KOMBUCHA TEA. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering. December 2019;20:24-29. doi:10.18038/estubtda.630211