SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES

Year 2023, Volume: 24 Issue: 4 - Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering, 216 - 229, 27.12.2023

Elvan Sayın , Güneş Süheyla Kürkçüoğlu

https://doi.org/10.18038/estubtda.1229463

Abstract

In this investigation, we present synthesis and characterized of three new heteropolynuclear cyanide complexes with 2-(Hydroxymethyl)pyridine (hmpH) of [M(H2O)(hmpH)Ni(CN)4]2·nH2O, (M(II) = Fe, Co and Ni); n = 12 for Fe, 2 for Co and Ni). The obtained complexes have been studied by elemental, thermal analysis, FT-IR, and Raman spectroscopic measurement techniques. Considering the alterations in characteristic peaks of cyanide, aqua, and hmpH ligands, general knowledge about the structural features of the complexes was detected from the vibrational spectra. The Ni(II) ion is coordinated by four cyanide-carbon atoms forming a square planar geometry. In addition, thermal analyses and electrical features of the complexes were investigated.

Keywords

Cyanide complex, Tetracyanonickelate(II) complex, 2-(Hydroxymethyl)pyridine complex, FT-IR and Raman spectra, Thermal analyses

Supporting Institution

The Research Fund of Eskişehir Osmangazi University.

Project Number

201319D14

Thanks

This paper is dedicated to Prof. Dr. Ziya KANTARCI, who died on January, 2012.

SYNTHESIS, CHARACTERIZATION OF CYANIDE COMPLEXES WITH 2-(HYDROXYMETHYL)PYRIDINE BY VIBRATIONAL SPECTROSCOPIC, THERMAL STUDIES AND ELECTRICAL PROPERTIES

Abstract

Keywords

Cyanide complex; Tetracyanonickelate(II) complex; 2-(Hydroxymethyl)pyridine complex; FT-IR and Raman spectra; Thermal analyses., Cyanide complex, Tetracyanonickelate(II) complex, 2-(Hydroxymethyl)pyridine complex, FT-IR and Raman spectra, Thermal analyses

Project Number

201319D14

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