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SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES

Yıl 2020, , 257 - 265, 31.08.2020
https://doi.org/10.20290/estubtdb.635259

Öz

Nanotechnology can control the
atomic, molecular, and supramolecular levels of matter. As the size of a
particle goes down to nano-size, materials exhibits good characteristics in
terms of electronics, optic, thermal, magnetic and fotocatalysis properties.
The nano composite fibers comprise of finely dispersed flakes of the second
phase inorganic material with nylon or polyester type fiber forming polymers.
Nano-fiber based materials obtained by the method of electrospining in the
interest of the outstanding features has increased due to the common
application areas of filtration, composites, medicine. In this research, we
produced nano composites at 0.50 1, 2, and 4 % ratio using polycaprolactone
(PCL) and titanium dioxide (TiO2). Energy Dispersive X-Ray Spectroscopy (EDS)
and Scanning Electron Microscopy (SEM) were used to analyze titanium dioxide
nano fibers.

Kaynakça

  • [1] Dural Erdem A, Özcan G. Polymeric Nanocomposites and Their Textile Applications.Tekstil ve Mühendis 2013; 20: 36-47.
  • [2] Celep Ş, Koç E. Nanoteknoloji ve Tekstilde Uygulama Alanları.Msc, Çukurova University,Adana, Turkey, 2008.
  • [3] Woodruff MA, Hutmacher DW.The return of a forgotten polymer—Polycaprolactone in the 21st century. Progress in Polymer Science 2010; 35:1217–1256.
  • [4] Ceylan M, Yang SY, Asmatulu R. Effects of gentamicin-loaded PCL nanofibers on growth of Gram positive and Gram negative bacteria. IJAMBR 2017; 5: 40-51.
  • [5] Croisier F, Duwez AS, Jérôme C, Léonard AF, Van der WerfK.O,Dijkstra PJ, Bennink ML.Mechanical testing of electrospun PCL fibers. Acta Biomaterialia 2012; 8; 218-224.
  • [6] Bordes C, Fréville V, Ruffin E, Marote P, Gauvrit JY, Briançon S, Lantéri P. Determination of poly(e-caprolactone) solubility parameters: Application to solvent substitution in a microencapsulation process. International Journal of Pharmaceutics 2010; 383:236-243.
  • [7] Vert M. Degradable and bioresorbable polymers in surgery and in pharmacology: beliefs and facts. J Mater Sci Mater Med 2009; 20:437-446.
  • [8] Theivasanthi T, Alagar M. Titanium dioxide (TiO2) Nanoparticles - XRD Analyses – An Insight. Cornell University Library 2013.
  • [9] Macwan DP, Pragnesh ND, Chaturvedi SA. Review on nano-TiO2 sol–gel type syntheses and its applications. J Mater Sci. 2011; 46:3669–3686.
  • [10] Gázquez MJ, Bolívar JP, Garcia-Tenorio R,Vaca F. A Review of the Production Cycle of Titanium Dioxide Pigment. Materials Sciences and Applications 2014; 5:441-458.
  • [11] Ceylan M. Superhydrophobıc Behavior of Electrospun Nanofibers with Variables Addtives.Wichita State University,Wichita,USA, 2009.
  • [12] Ramakrishna S, FujiharaK, Teo WE, Lim TC, Ma Z. Electrospinning Process,” An Introduction to Electrospinning and Nanofibers. 1st Edn,,Singapore: World Scientific Publishing Co. Pte. Ltd, 2005.
  • [13] Huang ZM, Zhang YZ, Kotaki M,Ramakrishna SA. Review on polymer nanofibers by electrospinning and their applications in nanocomposites. Composites Science and Technology 2003; 63: 2223-2253.
  • [14] Mit-uppatham C, Nithitanakul M, Supaphol P. Ultrafine Electrospun Polyamide-6 Fibers: Effect of Solution Conditions on Morphology and Average Fiber Diameter. Macromolecular Chemistry and Physics 2004; 205: 2327-2338.
  • [15] Doshi J, Reneker DH. Electrospinning process and applications of electrospun fibers. Journal of Electrostatics 1995;35:151-160.
  • [16] Kim YK, Lewis AF, Patra PK, Warner SB, Mhetre SK, Shah MA, Nam D.Nanocomposite Fibers.College of Engineering University of Massachusetts Dartmouth, 2002.
  • [17] Çallıoğlu F. The Production of Nanofiber by Roller Electrospinning Method. Tekstil ve Mühendis 2013;20:35-49.
  • [18] Dhakate SR, Singla B, Uppal M, Mathu RB.Effect of processing parameters on morphology and thermal properties of electrospun polycarbonate nanofibers.ADVANCED MATERIALS Letters 2010; 1:200-204.
  • [19] Khalifehzadeh F, Shahabi-Ghahfarrokhi I. Investigation of the characteristics of polycaprolactone-TiO2 nanofibers as nano- oxygen scavenger in the food active packaging exposed to UV-C radiation. Journal of Food Research 2019; 29: 65-79.
  • [20] Kiran ASK, Kumar TSS, Sanghavi R, Doble M, Ramakrishna S. Antibacterial and Bioactive Surface Modifications of Titanium Implants by PCL/TiO2 Nanocomposite Coatings. Nanomaterials 2018; 8:860.

TİTANYUM DIOKSİT KATKI MALZEMELERİ POLİKAPROLAKTON NANOKOMPOSİT FİBERLERİNİN SENTEZİ ve KARAKTERİZASYONU

Yıl 2020, , 257 - 265, 31.08.2020
https://doi.org/10.20290/estubtdb.635259

Öz

Nanoteknoloji, maddenin atomik, moleküler ve supramoleküler seviyelerini kontrol edebilir. Bir partikülün boyutu nano boyutuna indikçe malzemeler elektronik, optik, termal, manyetik ve fotokataliz özellikleri açısından iyi özellikler gösterir. Nano kompozit elyaf, naylon ya da polyester tipi elyaf oluşturucu polimerler ile ikinci faz inorganik malzemenin ince dağılmış pullarından oluşur. Göze çarpan özelliklere göre elektrospinleme yöntemiyle elde edilen nano elyaf esaslı malzemeler, genel filtrasyon, kompozitler, ilaç uygulama alanları nedeniyle artmıştır. Bu araştırmada, polikaprolakton (PCL) ve titanyum dioksit (TiO2) kullanarak% 0.50 1,2 ve 4 oranında nano kompozitler ürettik. Titanyum dioksit nano liflerinin analizinde Enerji Dağıtıcı X-Işını Spektroskopisi (EDS) ve Taramalı Elektron Mikroskobu (SEM) kullanılmıştır.

Kaynakça

  • [1] Dural Erdem A, Özcan G. Polymeric Nanocomposites and Their Textile Applications.Tekstil ve Mühendis 2013; 20: 36-47.
  • [2] Celep Ş, Koç E. Nanoteknoloji ve Tekstilde Uygulama Alanları.Msc, Çukurova University,Adana, Turkey, 2008.
  • [3] Woodruff MA, Hutmacher DW.The return of a forgotten polymer—Polycaprolactone in the 21st century. Progress in Polymer Science 2010; 35:1217–1256.
  • [4] Ceylan M, Yang SY, Asmatulu R. Effects of gentamicin-loaded PCL nanofibers on growth of Gram positive and Gram negative bacteria. IJAMBR 2017; 5: 40-51.
  • [5] Croisier F, Duwez AS, Jérôme C, Léonard AF, Van der WerfK.O,Dijkstra PJ, Bennink ML.Mechanical testing of electrospun PCL fibers. Acta Biomaterialia 2012; 8; 218-224.
  • [6] Bordes C, Fréville V, Ruffin E, Marote P, Gauvrit JY, Briançon S, Lantéri P. Determination of poly(e-caprolactone) solubility parameters: Application to solvent substitution in a microencapsulation process. International Journal of Pharmaceutics 2010; 383:236-243.
  • [7] Vert M. Degradable and bioresorbable polymers in surgery and in pharmacology: beliefs and facts. J Mater Sci Mater Med 2009; 20:437-446.
  • [8] Theivasanthi T, Alagar M. Titanium dioxide (TiO2) Nanoparticles - XRD Analyses – An Insight. Cornell University Library 2013.
  • [9] Macwan DP, Pragnesh ND, Chaturvedi SA. Review on nano-TiO2 sol–gel type syntheses and its applications. J Mater Sci. 2011; 46:3669–3686.
  • [10] Gázquez MJ, Bolívar JP, Garcia-Tenorio R,Vaca F. A Review of the Production Cycle of Titanium Dioxide Pigment. Materials Sciences and Applications 2014; 5:441-458.
  • [11] Ceylan M. Superhydrophobıc Behavior of Electrospun Nanofibers with Variables Addtives.Wichita State University,Wichita,USA, 2009.
  • [12] Ramakrishna S, FujiharaK, Teo WE, Lim TC, Ma Z. Electrospinning Process,” An Introduction to Electrospinning and Nanofibers. 1st Edn,,Singapore: World Scientific Publishing Co. Pte. Ltd, 2005.
  • [13] Huang ZM, Zhang YZ, Kotaki M,Ramakrishna SA. Review on polymer nanofibers by electrospinning and their applications in nanocomposites. Composites Science and Technology 2003; 63: 2223-2253.
  • [14] Mit-uppatham C, Nithitanakul M, Supaphol P. Ultrafine Electrospun Polyamide-6 Fibers: Effect of Solution Conditions on Morphology and Average Fiber Diameter. Macromolecular Chemistry and Physics 2004; 205: 2327-2338.
  • [15] Doshi J, Reneker DH. Electrospinning process and applications of electrospun fibers. Journal of Electrostatics 1995;35:151-160.
  • [16] Kim YK, Lewis AF, Patra PK, Warner SB, Mhetre SK, Shah MA, Nam D.Nanocomposite Fibers.College of Engineering University of Massachusetts Dartmouth, 2002.
  • [17] Çallıoğlu F. The Production of Nanofiber by Roller Electrospinning Method. Tekstil ve Mühendis 2013;20:35-49.
  • [18] Dhakate SR, Singla B, Uppal M, Mathu RB.Effect of processing parameters on morphology and thermal properties of electrospun polycarbonate nanofibers.ADVANCED MATERIALS Letters 2010; 1:200-204.
  • [19] Khalifehzadeh F, Shahabi-Ghahfarrokhi I. Investigation of the characteristics of polycaprolactone-TiO2 nanofibers as nano- oxygen scavenger in the food active packaging exposed to UV-C radiation. Journal of Food Research 2019; 29: 65-79.
  • [20] Kiran ASK, Kumar TSS, Sanghavi R, Doble M, Ramakrishna S. Antibacterial and Bioactive Surface Modifications of Titanium Implants by PCL/TiO2 Nanocomposite Coatings. Nanomaterials 2018; 8:860.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Elif Burcu Yılmaz Bu kişi benim 0000-0001-6926-3480

Muhammet Ceylan 0000-0001-6933-2917

Yayımlanma Tarihi 31 Ağustos 2020
Yayımlandığı Sayı Yıl 2020

Kaynak Göster

APA Yılmaz, E. B., & Ceylan, M. (2020). SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES. Eskişehir Teknik Üniversitesi Bilim Ve Teknoloji Dergisi B - Teorik Bilimler, 8(2), 257-265. https://doi.org/10.20290/estubtdb.635259
AMA Yılmaz EB, Ceylan M. SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES. Estuscience - Theory. Ağustos 2020;8(2):257-265. doi:10.20290/estubtdb.635259
Chicago Yılmaz, Elif Burcu, ve Muhammet Ceylan. “SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES”. Eskişehir Teknik Üniversitesi Bilim Ve Teknoloji Dergisi B - Teorik Bilimler 8, sy. 2 (Ağustos 2020): 257-65. https://doi.org/10.20290/estubtdb.635259.
EndNote Yılmaz EB, Ceylan M (01 Ağustos 2020) SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES. Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 8 2 257–265.
IEEE E. B. Yılmaz ve M. Ceylan, “SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES”, Estuscience - Theory, c. 8, sy. 2, ss. 257–265, 2020, doi: 10.20290/estubtdb.635259.
ISNAD Yılmaz, Elif Burcu - Ceylan, Muhammet. “SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES”. Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 8/2 (Ağustos 2020), 257-265. https://doi.org/10.20290/estubtdb.635259.
JAMA Yılmaz EB, Ceylan M. SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES. Estuscience - Theory. 2020;8:257–265.
MLA Yılmaz, Elif Burcu ve Muhammet Ceylan. “SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES”. Eskişehir Teknik Üniversitesi Bilim Ve Teknoloji Dergisi B - Teorik Bilimler, c. 8, sy. 2, 2020, ss. 257-65, doi:10.20290/estubtdb.635259.
Vancouver Yılmaz EB, Ceylan M. SYNTHESIS AND CHARACTERIZATION OF POLYCAPROLACTONE NANOCOMPOSITE FIBER WITH TITANIUM DIOXIDE ADDITIVES. Estuscience - Theory. 2020;8(2):257-65.