Research Article
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Development of Natural Castile Soaps from Vegetable Oils

Year 2024, Volume: 14 Issue: 3, 194 - 202, 19.12.2024
https://doi.org/10.26650/experimed.1509904

Abstract

Objective: Castile soaps are believed to be natural, 100% biodegradable, non-toxic surfactants and in some cases, they have antimicrobial properties. As raw materials, they are used extensively in the cosmetic industry for personal and home care products. Natural castile soap bases are generally produced in super fat stoichiometry to protect skin from caustic damage. The super fat method optimizes the total amount of caustic required for the saponification of natural vegetable oils and keeps these oils at the maximum level in the final product. The aim of this study was to develop natural soap based raw materials and castile soaps from various vegetable oils such as olive oil, coconut oil, castor oil, almond oil and jojoba oil.

Materials and Methods: Castile soaps were produced using the super fat method by measuring the saponification values of the vegetable oils. Viscosity, pH, appearance, and microbiological tests were performed to determine their shelf life.

Results: The castile formulations did not contain any preservatives, no microbiological risk was observed during their shelf life. All soap based raw materials and castil formulations have a two-year shelf life. These castile soaps are 100% soluble in water.

Conclusion: This article documents the laboratory-scale production of six soap based raw materials and the development of five castile formulations for personal and household cleaning. Super fat method optimized the total amount of caustic required for the saponification of natural vegetable oils such as olive oil, coconut oil, castor oil and maintains the oils in the product at the maximum level without allowing the presence of free caustic in the final product. Super fat castile soaps are the safest personal and household cleaning products because they don’t contain caustic residue, have their long shelf life and feature high solubility in water minimizing the risk of residue on skin and surface.

References

  • 1. Takagi Y, Kaneda K, Miyaki M, Matsuo K, Kawada H, Hosokawa H. The long-term use of soap does not affect the pH-maintenance mechanism of human skin. Skin Res Technol 2015; 21(2): 144-8. google scholar
  • 2. Mehling A, Kleber M, Hensen H. Comparative studies on the ocular and dermal irritation potential of surfactants. Food Chem Toxicol 2007; 45(5): 747-58. google scholar
  • 3. Löffler H, Happle R. Profile of irritant patch testing with detergents: sodium lauryl sulfate, sodium laureth sulfate and alkyl polyglucoside. Contact Dermatitis 2003; 48(1): 26-32. google scholar
  • 4. Failor C. Making natural liquid soaps: herbal shower gels, conditioning shampoos, moisturizing hand soaps, luxurious bubble baths, and more. USA: Storey Books; 2000. google scholar
  • 5. Panda H. Herbal soaps & detergent hand book. India: National Institute of Industrial Research Delhi; 2011. google scholar
  • 6. Girgis AY. Production of high quality castile soap from high rancid olive oil. Grasas y Aceites 2003; 54(3): 226-33. google scholar
  • 7. Thompson J. Liquid soapmaking: tips, techniques and recipes for creating all manner of liquid and soft soap naturally. USA: Jackie Thompson; 2014. google scholar
  • 8. Cavitch SM. The natural soap book. USA: Storey Books; 1995. google scholar
  • 9. Intahphuak S, Khonsung P, Panthong A. Anti-inflammatory, analgesic, and antipyretic activities of virgin coconut oil. Pharm Biol 2010; 48(2): 151-7. google scholar
  • 10. Nevin KG, Rajamohan T. Virgin coconut oil supplemented diet increases the antioxidant status in rats. Food Chem 2006; 9(2): 260-6. google scholar
  • 11. Sari M. The utilization of vco (virgin coconut oil) in manufacturing of solid soap with red betel leaf extract addition. IOP Conf Ser: Mater Sci Eng 2018; 335(1): 012038. google scholar
  • 12. Peedikayil FC, Remy V, John S, Chandru TP, Sreenivasan P, Bijapur GA. Comparison of antibacterial efficacy of coconut oil and chlorhexidine on streptococcus mutans: an in vivo study. J Int Soc Prev Community Dent 2016; 6(5): 447-52. google scholar
  • 13. Shahdan IA, Abllah Z, Jalaludin AA, Nasir NAMM. Virgin coconut oil and its antimicrobial properties against pathogenic microorganisms: a review. Adv Health Sci Res 2018; 8: 192-9. google scholar
  • 14. Varma SR, Sivaprakasam TO, Arumugam I, Dilip N, Raghuraman M, Pavan KB, et al. In vitro anti-inflammatory and skin protective properties of virgin coconut oil. J Tradit Complement Med 2018; 9(1): 5-14. google scholar
  • 15. Lin TK, Zhong L, Santiago JS. Anti-inflammatory and skin barrier repair effects of topical application of some plant oils. Int J Mol Sci 2017; 19(1): 70. google scholar
  • 16. Debicka MG, Przychodzen P, Cappello F, Jankowska AK, Gammazza AM, Knap N, et al. Potential health benefits of olive oil and plant polyphenols. Int J Mol Sci 2018; 19(3): 686. google scholar
  • 17. Cui Z, Xin M, Yin H, Zhang J, Han F. Topical use of olive oil preparation to prevent radiodermatitis: results of a prospective study in nasopharyngeal carcinoma patients. Int J Clin Exp Med 2015; 8(7): 11000-6. google scholar
  • 18. Waterman E, Lockwood B. Active components and clinical applications of olive oil. Altern Med Rev 2007; 12(4): 331-42. google scholar
  • 19. Widyasanti A, Ayuningtyas B, Rosalinda S. Characterization of liquid soap from castor oil (ricinus communis) with the addition of white tea extracts. IOP Conf Ser: Earth Environ Sci 2020; 443: 012061. google scholar
  • 20. Patel VR, Dumancas GG, Viswanath LCK, Maples R, Subong BJJ. Castor oil: properties, uses, and optimization of processing parameters in commercial production. Lipid Insights 2016; 9: 1-12. google scholar
  • 21. Abdulrasheed A, Aroke UO, Muazu MT. Characterization and utilization of castor bean seed oil extract for production of medicated soap. Am J Eng Res 2015; 4(12): 67-72. google scholar
  • 22. Kugler S, Ossowicz P, Matusiak KM, Wierzbicka E. Advances in rosin-based chemicals: the latest recipes, applications and future trends. Molecules 2019; 24(9): 1651. google scholar
  • 23. Pohle WD, Speh CF. Detergent action of rosin soaps and fatty acid - rosin soaps. Oil Soap 1940; 17: 214-6. google scholar
  • 24. Pohle WD. Solubility of calcium soaps of gum rosin, rosin acids and fatty acids. Oil Soap 1941; 18: 244-5. google scholar
  • 25. Kesler CC. Process of making rosin soap, 1928, US1663764A. Available from: https://patents.google.com/patent/US1663764A/en google scholar
  • 26. Karlberg AT, Hagvall L. Colophony: rosin in unmodified and modified form, Kanerva’s Occupational Dermatology 2020; 467-79. google scholar
  • 27. ISO 21149-2017 Cosmetics - microbiology - enumeration and detection of aerobic mesophilic bacteria. Available from: https:// www.iso.org/standard/72240.html google scholar
  • 28. ISO 16212-2017 Cosmetics - microbiology - enumeration of yeast and mould. Available from: https://www.iso.org/standard/72241. google scholar
  • 29. Cosmos Standard Technical Guide, Version 4.0, 1 January 2023. Available from: https://media.cosmos-standard.org/filer_public/ a9/35/a935e9a9-6623-4d5d-b0dd-0c56c81417c3/cosmos-standard_v40.pdf google scholar
  • 30. ISO 16128-1-2016 Guidelines on technical definitions and criteria for natural and organic cosmetic ingredients and products. Available from: https://www.iso.org/standard/62503.html google scholar
  • 31. ISO 16128-2-2017 Cosmetics - guidelines on technical definitions and criteria for natural and organic cosmetic ingredients. Available from: https://www.iso.org/standard/65197.html google scholar
Year 2024, Volume: 14 Issue: 3, 194 - 202, 19.12.2024
https://doi.org/10.26650/experimed.1509904

Abstract

References

  • 1. Takagi Y, Kaneda K, Miyaki M, Matsuo K, Kawada H, Hosokawa H. The long-term use of soap does not affect the pH-maintenance mechanism of human skin. Skin Res Technol 2015; 21(2): 144-8. google scholar
  • 2. Mehling A, Kleber M, Hensen H. Comparative studies on the ocular and dermal irritation potential of surfactants. Food Chem Toxicol 2007; 45(5): 747-58. google scholar
  • 3. Löffler H, Happle R. Profile of irritant patch testing with detergents: sodium lauryl sulfate, sodium laureth sulfate and alkyl polyglucoside. Contact Dermatitis 2003; 48(1): 26-32. google scholar
  • 4. Failor C. Making natural liquid soaps: herbal shower gels, conditioning shampoos, moisturizing hand soaps, luxurious bubble baths, and more. USA: Storey Books; 2000. google scholar
  • 5. Panda H. Herbal soaps & detergent hand book. India: National Institute of Industrial Research Delhi; 2011. google scholar
  • 6. Girgis AY. Production of high quality castile soap from high rancid olive oil. Grasas y Aceites 2003; 54(3): 226-33. google scholar
  • 7. Thompson J. Liquid soapmaking: tips, techniques and recipes for creating all manner of liquid and soft soap naturally. USA: Jackie Thompson; 2014. google scholar
  • 8. Cavitch SM. The natural soap book. USA: Storey Books; 1995. google scholar
  • 9. Intahphuak S, Khonsung P, Panthong A. Anti-inflammatory, analgesic, and antipyretic activities of virgin coconut oil. Pharm Biol 2010; 48(2): 151-7. google scholar
  • 10. Nevin KG, Rajamohan T. Virgin coconut oil supplemented diet increases the antioxidant status in rats. Food Chem 2006; 9(2): 260-6. google scholar
  • 11. Sari M. The utilization of vco (virgin coconut oil) in manufacturing of solid soap with red betel leaf extract addition. IOP Conf Ser: Mater Sci Eng 2018; 335(1): 012038. google scholar
  • 12. Peedikayil FC, Remy V, John S, Chandru TP, Sreenivasan P, Bijapur GA. Comparison of antibacterial efficacy of coconut oil and chlorhexidine on streptococcus mutans: an in vivo study. J Int Soc Prev Community Dent 2016; 6(5): 447-52. google scholar
  • 13. Shahdan IA, Abllah Z, Jalaludin AA, Nasir NAMM. Virgin coconut oil and its antimicrobial properties against pathogenic microorganisms: a review. Adv Health Sci Res 2018; 8: 192-9. google scholar
  • 14. Varma SR, Sivaprakasam TO, Arumugam I, Dilip N, Raghuraman M, Pavan KB, et al. In vitro anti-inflammatory and skin protective properties of virgin coconut oil. J Tradit Complement Med 2018; 9(1): 5-14. google scholar
  • 15. Lin TK, Zhong L, Santiago JS. Anti-inflammatory and skin barrier repair effects of topical application of some plant oils. Int J Mol Sci 2017; 19(1): 70. google scholar
  • 16. Debicka MG, Przychodzen P, Cappello F, Jankowska AK, Gammazza AM, Knap N, et al. Potential health benefits of olive oil and plant polyphenols. Int J Mol Sci 2018; 19(3): 686. google scholar
  • 17. Cui Z, Xin M, Yin H, Zhang J, Han F. Topical use of olive oil preparation to prevent radiodermatitis: results of a prospective study in nasopharyngeal carcinoma patients. Int J Clin Exp Med 2015; 8(7): 11000-6. google scholar
  • 18. Waterman E, Lockwood B. Active components and clinical applications of olive oil. Altern Med Rev 2007; 12(4): 331-42. google scholar
  • 19. Widyasanti A, Ayuningtyas B, Rosalinda S. Characterization of liquid soap from castor oil (ricinus communis) with the addition of white tea extracts. IOP Conf Ser: Earth Environ Sci 2020; 443: 012061. google scholar
  • 20. Patel VR, Dumancas GG, Viswanath LCK, Maples R, Subong BJJ. Castor oil: properties, uses, and optimization of processing parameters in commercial production. Lipid Insights 2016; 9: 1-12. google scholar
  • 21. Abdulrasheed A, Aroke UO, Muazu MT. Characterization and utilization of castor bean seed oil extract for production of medicated soap. Am J Eng Res 2015; 4(12): 67-72. google scholar
  • 22. Kugler S, Ossowicz P, Matusiak KM, Wierzbicka E. Advances in rosin-based chemicals: the latest recipes, applications and future trends. Molecules 2019; 24(9): 1651. google scholar
  • 23. Pohle WD, Speh CF. Detergent action of rosin soaps and fatty acid - rosin soaps. Oil Soap 1940; 17: 214-6. google scholar
  • 24. Pohle WD. Solubility of calcium soaps of gum rosin, rosin acids and fatty acids. Oil Soap 1941; 18: 244-5. google scholar
  • 25. Kesler CC. Process of making rosin soap, 1928, US1663764A. Available from: https://patents.google.com/patent/US1663764A/en google scholar
  • 26. Karlberg AT, Hagvall L. Colophony: rosin in unmodified and modified form, Kanerva’s Occupational Dermatology 2020; 467-79. google scholar
  • 27. ISO 21149-2017 Cosmetics - microbiology - enumeration and detection of aerobic mesophilic bacteria. Available from: https:// www.iso.org/standard/72240.html google scholar
  • 28. ISO 16212-2017 Cosmetics - microbiology - enumeration of yeast and mould. Available from: https://www.iso.org/standard/72241. google scholar
  • 29. Cosmos Standard Technical Guide, Version 4.0, 1 January 2023. Available from: https://media.cosmos-standard.org/filer_public/ a9/35/a935e9a9-6623-4d5d-b0dd-0c56c81417c3/cosmos-standard_v40.pdf google scholar
  • 30. ISO 16128-1-2016 Guidelines on technical definitions and criteria for natural and organic cosmetic ingredients and products. Available from: https://www.iso.org/standard/62503.html google scholar
  • 31. ISO 16128-2-2017 Cosmetics - guidelines on technical definitions and criteria for natural and organic cosmetic ingredients. Available from: https://www.iso.org/standard/65197.html google scholar
There are 31 citations in total.

Details

Primary Language English
Subjects Analytical Biochemistry
Journal Section Research Article
Authors

Kadri Gökhan Özokan 0000-0003-1140-1996

Abdulkerim Bilginer 0000-0002-7129-2149

Publication Date December 19, 2024
Submission Date July 3, 2024
Acceptance Date November 6, 2024
Published in Issue Year 2024 Volume: 14 Issue: 3

Cite

Vancouver Özokan KG, Bilginer A. Development of Natural Castile Soaps from Vegetable Oils. Experimed. 2024;14(3):194-202.