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Review of Processes Concerning Zeolite Activation And Modification

Year 2017, Volume: 1 Issue: 7, 15 - 24, 01.06.2017

Abstract

Zeolite is mainly used in several processes such removal of metals from wastewater, adsorption of desired material from aqueous solutions. Before apply it to any solution, it is better to activate zeolite and then, if needed, to modify with any chemical material. In this manuscript, acid and thermal activation of zeolite were explained according to their usage in literature. And also, in some cases, the reason for modification of zeolite and how it is used in literature were mentioned

References

  • Ates A, Hardacre C. 2012. The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments. Journal of Colloid and Interface Science. 372: 130–140.
  • Breck DW. 1974. Zeolite Molecular Sieves: Structure, Chemistry, and Use. New York: Wiley & Sons.
  • Burris LE, Juenger MCG. 2016. Milling as a pretreatment method for increasing the reactivity of natural zeolites for use as supplementary cementitious materials. Cement and Concrete Composites. 65: 163-170.
  • Chakarova K, Andonova S, Dimitrov L, Hadjiivanov K. 2016. FTIR study of CO and N2 adsorption on [Ge]FAU zeolites in their Na- and H-forms. Microporous and Mesoporous Materials. 220: 188-197.
  • Chen S, Shao Z, Fang Z, Chen Q, Tang T, Fu W, Zhang L, Tang T. 2016. Design and synthesis of the basic Cu-doped zeolite X catalyst with high activity in oxidative coupling reactions. Journal of Catalysis. 338: 38–46.
  • Çanlı M. 2013. Modification of zeolites and examination of its surface properties. PhD thesis. Manisa Celal Bayar University, Manisa.
  • de Barros MASD, Machado NRCF, Alves FV, Sousa-Aguiar EF. Ion exchange mechanism of Cr+3 on naturally occurring clinoptilolite. Brazilian Journal of Chemical Engineering. DOI:10.1590/S0104-66321997000300006.
  • Dyballa, M., Becker, P., Trefz, D., Klemm, E., Fischer, A., Jakob, H., and Hunger, M. 2016. Parameters influencing the selectivity to propene in the MTO conversion on 10-ring zeolites: directly synthesized zeolites ZSM-5, ZSM-11, and ZSM-22. Applied Catalysis A: General 510: 233–243.
  • Emdadi, L., Oh, S.C., Wu, Y., Oliaee, S.N., Diao, Y., Zhu, G., and Liu, D. 2016. The role of external acidity of meso-/microporous zeolites in determining selectivity for acid- catalyzed reactions of benzyl alcohol. Journal of Catalysis 335: 165–174.
  • Giroux M, Sahadeo E, Libera R, Maurizi A, Giles I, Marteel-Parrish A. 2016. An undergraduate research experience: Synthesis, modification, and comparison of hydrophobicity of zeolites A and X. Polyhedron. 114: 42-52.
  • Gora-Marek K, Brylewska K, Tarach KA, Rutkowska M, Jablonska M, Choi M, Chmielarz L. 2015. IR studies of Fe modified ZSM-5 zeolites of diverse mesopore topologies in the terms of their catalytic performance in NH3-SCR and NH3-SCO processes. Applied Catalysis B: Environmental. 179: 589–598.
  • Guesh K, Mayoral A, Marquez-Alvarez C, Chebude Y, Diaz I. 2016. Enhanced photocatalytic activity of TiO2 supported on zeolites tested in real wastewaters from the textile industry of Ethiopia. Microporous and Mesoporous Materials. 225: 88-97.
  • Guzman A, Zuazo I, Feller A, Olindo R, Sievers C, Lercher JA. 2006. Influence of the activation temperature on the physicochemical properties and catalytic activity of La-X zeolites for isobutane/cis-2-butene alkylation. Microporous and Mesoporous Materials. 97: 49– 57.
  • Jablonska M, Krol A, Kukulska-Zajac E, Taracha K, Girman V, Chmielarz L, Gora-Marek K. 2015. Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration. Applied Catalysis B: Environmental. 166–167: 353–365.
  • Jiang S, Huang S, Qin L, Tu W, Zhu J, Tian H, Wang P. 2010. Density functional theory study of relevant properties of lanthanum species and 1-butene activation over lanthanum modified zeolite. Journal of Molecular Structure: THEOCHEM. 962: 1–6.
  • Jin Y, Xiao C, Liu J, Zhang S, Asaoka S, Zhao S. 2015. Mesopore modification of beta zeolites by sequential alkali and acid treatments: Narrowing mesopore size distribution featuring unimodality and mesoporous texture properties estimated upon a mesoporous volumetric model. Microporous and Mesoporous Materials. 218: 180-191.
  • Koshy N, Singh DN. 2016. Fly ash zeolites for water treatment applications. Journal of Environmental Chemical Engineering. 4: 1460–1472.
  • Kühl G H. 1999. Modification of Zeolites. In: Catalysis and Zeolites: Fundamentals and Applications. New York: Springer.
  • Martinez A, Peris E. 2016. Non-oxidative methane dehydroaromatization on Mo/HZSM- 5catalysts: Tuning the acidic and catalytic properties through partial exchange of zeolite protons with alkali and alkaline-earth cations. Applied Catalysis A: General. 515: 32– 44.
  • Meusinger J, Corma A. 1995. Activation of hydrogen on zeolites: Kinetics and mechanism of n-heptane cracking on H-ZSM-5zeolites under high hydrogen pressure. Journal of Catalysis. 152: 189-197.
  • Mirzaei N, Hadi M, Gholami M, Fard RF, Aminabad MS. 2016. Sorption of acid dye by surfactant modificated natural zeolites. Journal of the Taiwan Institute of Chemical Engineers. 59: 186–194.
  • Nasser G, Kurniawan T, Miyake K, Galadima A, Hirota Y, Nishiyama N, Muraza O. 2016. Dimethyl ether to olefins over dealuminated mordenite (MOR) zeolites derived from natural minerals. Journal of Natural Gas Science and Engineering. 28: 566-571.
  • Rodriguesa MV, Vignatti C, Garetto T, Pulcinelli SH, Santilli CV, Martins L. 2015. Glycerol dehydration catalyzed by MWW zeolites and the changes in the catalyst deactivation caused by porosity modification Applied Catalysis A: General. 495: 84–91.
  • Srebowata A, Tarach K, Girman V, Gora-Marek K. 2016. Catalytic removal of trichloroethylene from water over palladium loaded microporous and hierarchical zeolites. Applied Catalysis B: Environmental. 181: 550–560.
  • Sun HY, Sun LP, Li F, Zhang L. 2015. Adsorption of benzothiophene from fuels on modified NaY zeolites. Fuel Processing Technology. 134: 284–289.
  • Vieira LH, Carvalho KTG, Urquieta-Gonzalez EA, Pulcinelli SH, Santilli CV, Martins L. 2016. Effects of crystal size, acidity, and synthesis procedure on the catalytic performance of gallium and aluminum MFI zeolites in glycerol dehydration. Journal of Molecular Catalysis A: Chemical. 422: 148-157.
  • Villa C, Pecina ET, Torres R, Gomez L. 2010. Geopolymer synthesis using alkaline activation of natural zeolite. Construction and Building Materials. 24: 2084–2090.
  • Visa M. 2016. Synthesis and characterization of new zeolite materials obtained from fly ash for heavy metals removal in advanced wastewater treatment. Powder Technology. 294: 338–347.
  • Wang X, Ozdemir O, Hampton MA, Nguyen AV, Do DD. 2012. The effect of zeolite treatment by acids on sodium adsorption ratio of coal seam gas water. Water Research. 46: 5247- 5254.
  • Wei Y, de Jongh PE, Bonati MLM, Law DJ, Sunley GJ, de Jong KP. 2015. Enhanced catalytic performance of zeolite ZSM-5 for conversion of methanol to dimethyl ether by combining alkaline treatment and partial activation. Applied Catalysis A: General. 504: 211–219.
  • Xu S, Sheng H, Ye T, Hu D, Liao S. 2016. Hydrophobic aluminosilicate zeolites as highly efficient catalysts for the dehydration of alcohols. Catalysis Communications. 78: 75– 79.
  • Yamasaki Y, Tsunoji N, Takamitsu Y, Sadakane M, Sano T. 2016. Synthesis of phosphorus- modified small-pore zeolites utilizing tetraalkyl phosphonium cations as both structure- directing and phosphorous modification agents. Microporous and Mesoporous Materials. 223: 129-139.
  • Yang S, Cao Z, Arvanitis A, Sun X, Xu Z, Dong J. 2016. DDR-type zeolite membrane synthesis, modification and gas permeation studies. Journal of Membrane Science. 505: 194–204.

Zeolitin Aktive ve Modifiye Edilmesi Süreçleri Hakkinda Bir Derleme

Year 2017, Volume: 1 Issue: 7, 15 - 24, 01.06.2017

Abstract

Zeolit, metallerin atıksudan uzaklaştırılması, istenen malzemenin sulu çözeltilerden adsorpsiyonu gibi çeşitli işlemlerde kullanılır. Herhangi bir çözeltiye uygulamadan önce, zeolitin aktif hale getirilmesi ve daha sonra gerekirse herhangi bir kimyasal madde ile modifiye edilmesi daha iyidir. Bu makalede, zeolitin asit ve termal aktivasyonu, literatürdeki kullanımlarına göre açıklanmıştır. Ayrıca, bazı durumlarda, zeolitin modifikasyon nedeninden ve literatürde nasıl kullanıldığından bahsedilmiştir

References

  • Ates A, Hardacre C. 2012. The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments. Journal of Colloid and Interface Science. 372: 130–140.
  • Breck DW. 1974. Zeolite Molecular Sieves: Structure, Chemistry, and Use. New York: Wiley & Sons.
  • Burris LE, Juenger MCG. 2016. Milling as a pretreatment method for increasing the reactivity of natural zeolites for use as supplementary cementitious materials. Cement and Concrete Composites. 65: 163-170.
  • Chakarova K, Andonova S, Dimitrov L, Hadjiivanov K. 2016. FTIR study of CO and N2 adsorption on [Ge]FAU zeolites in their Na- and H-forms. Microporous and Mesoporous Materials. 220: 188-197.
  • Chen S, Shao Z, Fang Z, Chen Q, Tang T, Fu W, Zhang L, Tang T. 2016. Design and synthesis of the basic Cu-doped zeolite X catalyst with high activity in oxidative coupling reactions. Journal of Catalysis. 338: 38–46.
  • Çanlı M. 2013. Modification of zeolites and examination of its surface properties. PhD thesis. Manisa Celal Bayar University, Manisa.
  • de Barros MASD, Machado NRCF, Alves FV, Sousa-Aguiar EF. Ion exchange mechanism of Cr+3 on naturally occurring clinoptilolite. Brazilian Journal of Chemical Engineering. DOI:10.1590/S0104-66321997000300006.
  • Dyballa, M., Becker, P., Trefz, D., Klemm, E., Fischer, A., Jakob, H., and Hunger, M. 2016. Parameters influencing the selectivity to propene in the MTO conversion on 10-ring zeolites: directly synthesized zeolites ZSM-5, ZSM-11, and ZSM-22. Applied Catalysis A: General 510: 233–243.
  • Emdadi, L., Oh, S.C., Wu, Y., Oliaee, S.N., Diao, Y., Zhu, G., and Liu, D. 2016. The role of external acidity of meso-/microporous zeolites in determining selectivity for acid- catalyzed reactions of benzyl alcohol. Journal of Catalysis 335: 165–174.
  • Giroux M, Sahadeo E, Libera R, Maurizi A, Giles I, Marteel-Parrish A. 2016. An undergraduate research experience: Synthesis, modification, and comparison of hydrophobicity of zeolites A and X. Polyhedron. 114: 42-52.
  • Gora-Marek K, Brylewska K, Tarach KA, Rutkowska M, Jablonska M, Choi M, Chmielarz L. 2015. IR studies of Fe modified ZSM-5 zeolites of diverse mesopore topologies in the terms of their catalytic performance in NH3-SCR and NH3-SCO processes. Applied Catalysis B: Environmental. 179: 589–598.
  • Guesh K, Mayoral A, Marquez-Alvarez C, Chebude Y, Diaz I. 2016. Enhanced photocatalytic activity of TiO2 supported on zeolites tested in real wastewaters from the textile industry of Ethiopia. Microporous and Mesoporous Materials. 225: 88-97.
  • Guzman A, Zuazo I, Feller A, Olindo R, Sievers C, Lercher JA. 2006. Influence of the activation temperature on the physicochemical properties and catalytic activity of La-X zeolites for isobutane/cis-2-butene alkylation. Microporous and Mesoporous Materials. 97: 49– 57.
  • Jablonska M, Krol A, Kukulska-Zajac E, Taracha K, Girman V, Chmielarz L, Gora-Marek K. 2015. Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration. Applied Catalysis B: Environmental. 166–167: 353–365.
  • Jiang S, Huang S, Qin L, Tu W, Zhu J, Tian H, Wang P. 2010. Density functional theory study of relevant properties of lanthanum species and 1-butene activation over lanthanum modified zeolite. Journal of Molecular Structure: THEOCHEM. 962: 1–6.
  • Jin Y, Xiao C, Liu J, Zhang S, Asaoka S, Zhao S. 2015. Mesopore modification of beta zeolites by sequential alkali and acid treatments: Narrowing mesopore size distribution featuring unimodality and mesoporous texture properties estimated upon a mesoporous volumetric model. Microporous and Mesoporous Materials. 218: 180-191.
  • Koshy N, Singh DN. 2016. Fly ash zeolites for water treatment applications. Journal of Environmental Chemical Engineering. 4: 1460–1472.
  • Kühl G H. 1999. Modification of Zeolites. In: Catalysis and Zeolites: Fundamentals and Applications. New York: Springer.
  • Martinez A, Peris E. 2016. Non-oxidative methane dehydroaromatization on Mo/HZSM- 5catalysts: Tuning the acidic and catalytic properties through partial exchange of zeolite protons with alkali and alkaline-earth cations. Applied Catalysis A: General. 515: 32– 44.
  • Meusinger J, Corma A. 1995. Activation of hydrogen on zeolites: Kinetics and mechanism of n-heptane cracking on H-ZSM-5zeolites under high hydrogen pressure. Journal of Catalysis. 152: 189-197.
  • Mirzaei N, Hadi M, Gholami M, Fard RF, Aminabad MS. 2016. Sorption of acid dye by surfactant modificated natural zeolites. Journal of the Taiwan Institute of Chemical Engineers. 59: 186–194.
  • Nasser G, Kurniawan T, Miyake K, Galadima A, Hirota Y, Nishiyama N, Muraza O. 2016. Dimethyl ether to olefins over dealuminated mordenite (MOR) zeolites derived from natural minerals. Journal of Natural Gas Science and Engineering. 28: 566-571.
  • Rodriguesa MV, Vignatti C, Garetto T, Pulcinelli SH, Santilli CV, Martins L. 2015. Glycerol dehydration catalyzed by MWW zeolites and the changes in the catalyst deactivation caused by porosity modification Applied Catalysis A: General. 495: 84–91.
  • Srebowata A, Tarach K, Girman V, Gora-Marek K. 2016. Catalytic removal of trichloroethylene from water over palladium loaded microporous and hierarchical zeolites. Applied Catalysis B: Environmental. 181: 550–560.
  • Sun HY, Sun LP, Li F, Zhang L. 2015. Adsorption of benzothiophene from fuels on modified NaY zeolites. Fuel Processing Technology. 134: 284–289.
  • Vieira LH, Carvalho KTG, Urquieta-Gonzalez EA, Pulcinelli SH, Santilli CV, Martins L. 2016. Effects of crystal size, acidity, and synthesis procedure on the catalytic performance of gallium and aluminum MFI zeolites in glycerol dehydration. Journal of Molecular Catalysis A: Chemical. 422: 148-157.
  • Villa C, Pecina ET, Torres R, Gomez L. 2010. Geopolymer synthesis using alkaline activation of natural zeolite. Construction and Building Materials. 24: 2084–2090.
  • Visa M. 2016. Synthesis and characterization of new zeolite materials obtained from fly ash for heavy metals removal in advanced wastewater treatment. Powder Technology. 294: 338–347.
  • Wang X, Ozdemir O, Hampton MA, Nguyen AV, Do DD. 2012. The effect of zeolite treatment by acids on sodium adsorption ratio of coal seam gas water. Water Research. 46: 5247- 5254.
  • Wei Y, de Jongh PE, Bonati MLM, Law DJ, Sunley GJ, de Jong KP. 2015. Enhanced catalytic performance of zeolite ZSM-5 for conversion of methanol to dimethyl ether by combining alkaline treatment and partial activation. Applied Catalysis A: General. 504: 211–219.
  • Xu S, Sheng H, Ye T, Hu D, Liao S. 2016. Hydrophobic aluminosilicate zeolites as highly efficient catalysts for the dehydration of alcohols. Catalysis Communications. 78: 75– 79.
  • Yamasaki Y, Tsunoji N, Takamitsu Y, Sadakane M, Sano T. 2016. Synthesis of phosphorus- modified small-pore zeolites utilizing tetraalkyl phosphonium cations as both structure- directing and phosphorous modification agents. Microporous and Mesoporous Materials. 223: 129-139.
  • Yang S, Cao Z, Arvanitis A, Sun X, Xu Z, Dong J. 2016. DDR-type zeolite membrane synthesis, modification and gas permeation studies. Journal of Membrane Science. 505: 194–204.
There are 33 citations in total.

Details

Primary Language English
Journal Section Review
Authors

Murat Çanlı This is me

Publication Date June 1, 2017
Published in Issue Year 2017 Volume: 1 Issue: 7

Cite

APA Çanlı, M. (2017). Review of Processes Concerning Zeolite Activation And Modification. Science and Technique in the 21st Century, 1(7), 15-24.