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TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS)

Year 2012, Volume: 25 Issue: 4, 843 - 851, 07.05.2012

Abstract

The forensic examination and dating of documents is important in our society, because documents are used throughout our lives to record everything we do. The analysis of questioned documents therefore involves different types of analysis including comparison of the handwriting, ink, typescript or print, as well as physical and chemical characterization of the paper itself. Inductively coupled plasma mass spectrometry (ICP-MS) has already successfully been applied to applications in geology, forensics, ceramics, metals, glasses and a wide variety of environmental and industrial materials. In this study the use of elemental compositions, determined by ICP – MS to differentiate paper samples was investigated. Paper samples of commonly used office document paper from different sources were first microwave – digested in nitric acid – hydrogen peroxide solution and then trace elements concentrations were determined using ICP – MS.

References

  • [1] Tănase, I. Gh., “Techniques and methods in spectrometric analysis”, Ed. Ars Docendi Bucharest, 120-124 (2001).
  • [2] Dufosse, T., Touron, P., “Comparison of bullet alloys by chemical analysis: Use of ICP – MS method”, Forensic Sci. Int., 91: 197-206 (1998).
  • [3] Smook, G., “Handbook for Pulp & Paper Technologists”, Angus Wilde Publications, Vancouver, 2nd ed., 225-230 (1992).
  • [4] Grant, J., “The role of paper in questioned document work”, J. Forensic Sci. Soc., 13: 91-95 (1973).
  • [5] Schlesinger, H. L., Settle, D.M., “A large – scale study of paper by neutron activation analysis”, J. Forensic Sci., 16: 309-330 (1971).
  • [6] Blanchard, D.B., Harrison, S.H., “Trace elemental profiles and ratios determined by instrumental neutron activation analysis for fine paper identification”, J. Forensic Sci., 23: 679- 686 (1978).
  • [7] Simon, P.J., Glessen, B.C., Copeland, T.R., “Categorization of papers by trace metal content using atomic absorption spectrometric and pattern recognition techniques”, Anal. Chem., 49: 2285-2288 (1977).
  • [8] Polk, D.E., Allard, A.E., “Forensic characterization of papers. II: determination of batch differences by scanning electron microscopic elemental analysis of the inorganic components”, J. Forensic Sci., 22: 524-533 (1977).
  • [9] Gess, J.M., “A perspective on neutral alkaline papermaking”, J. Tech. Ass. Pulp Paper Ind. (TAPPI), 75: 79-85 (1992).
  • [10] Kuptsov, A.H., “Applications of Fourier transform Raman spectroscopy in forensic science”, J. Forensic. Sci., 39: 305-318 (1994).
  • [11] Spence, L.D., Francis, R.B., Tinggi, U.J., “Comparison of the elemental composition of office document paper: evidence in a homicide case”, Forensic. Sci., 47: 648-651 (2002).
  • [12] McGaw, E.A., Szymanski, D.W., Waddell Smith, R., “Determination of trace elemental concentrations in document papers for forensic comparison using inductively coupled plasma – mass spectrometry”, J. Forensic. Sci., 54: 1163-1170
Year 2012, Volume: 25 Issue: 4, 843 - 851, 07.05.2012

Abstract

References

  • [1] Tănase, I. Gh., “Techniques and methods in spectrometric analysis”, Ed. Ars Docendi Bucharest, 120-124 (2001).
  • [2] Dufosse, T., Touron, P., “Comparison of bullet alloys by chemical analysis: Use of ICP – MS method”, Forensic Sci. Int., 91: 197-206 (1998).
  • [3] Smook, G., “Handbook for Pulp & Paper Technologists”, Angus Wilde Publications, Vancouver, 2nd ed., 225-230 (1992).
  • [4] Grant, J., “The role of paper in questioned document work”, J. Forensic Sci. Soc., 13: 91-95 (1973).
  • [5] Schlesinger, H. L., Settle, D.M., “A large – scale study of paper by neutron activation analysis”, J. Forensic Sci., 16: 309-330 (1971).
  • [6] Blanchard, D.B., Harrison, S.H., “Trace elemental profiles and ratios determined by instrumental neutron activation analysis for fine paper identification”, J. Forensic Sci., 23: 679- 686 (1978).
  • [7] Simon, P.J., Glessen, B.C., Copeland, T.R., “Categorization of papers by trace metal content using atomic absorption spectrometric and pattern recognition techniques”, Anal. Chem., 49: 2285-2288 (1977).
  • [8] Polk, D.E., Allard, A.E., “Forensic characterization of papers. II: determination of batch differences by scanning electron microscopic elemental analysis of the inorganic components”, J. Forensic Sci., 22: 524-533 (1977).
  • [9] Gess, J.M., “A perspective on neutral alkaline papermaking”, J. Tech. Ass. Pulp Paper Ind. (TAPPI), 75: 79-85 (1992).
  • [10] Kuptsov, A.H., “Applications of Fourier transform Raman spectroscopy in forensic science”, J. Forensic. Sci., 39: 305-318 (1994).
  • [11] Spence, L.D., Francis, R.B., Tinggi, U.J., “Comparison of the elemental composition of office document paper: evidence in a homicide case”, Forensic. Sci., 47: 648-651 (2002).
  • [12] McGaw, E.A., Szymanski, D.W., Waddell Smith, R., “Determination of trace elemental concentrations in document papers for forensic comparison using inductively coupled plasma – mass spectrometry”, J. Forensic. Sci., 54: 1163-1170
There are 12 citations in total.

Details

Primary Language English
Journal Section Chemistry
Authors

Y Aboul-enein

I. Gh. Tanase This is me

Florin Mihai Udrıstıoıu This is me

Andrei A. Bunacıu This is me

Publication Date May 7, 2012
Published in Issue Year 2012 Volume: 25 Issue: 4

Cite

APA Aboul-enein, Y., Tanase, I. G., Udrıstıoıu, F. M., Bunacıu, A. A. (2012). TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS). Gazi University Journal of Science, 25(4), 843-851.
AMA Aboul-enein Y, Tanase IG, Udrıstıoıu FM, Bunacıu AA. TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS). Gazi University Journal of Science. October 2012;25(4):843-851.
Chicago Aboul-enein, Y, I. Gh. Tanase, Florin Mihai Udrıstıoıu, and Andrei A. Bunacıu. “TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS)”. Gazi University Journal of Science 25, no. 4 (October 2012): 843-51.
EndNote Aboul-enein Y, Tanase IG, Udrıstıoıu FM, Bunacıu AA (October 1, 2012) TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS). Gazi University Journal of Science 25 4 843–851.
IEEE Y. Aboul-enein, I. G. Tanase, F. M. Udrıstıoıu, and A. A. Bunacıu, “TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS)”, Gazi University Journal of Science, vol. 25, no. 4, pp. 843–851, 2012.
ISNAD Aboul-enein, Y et al. “TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS)”. Gazi University Journal of Science 25/4 (October 2012), 843-851.
JAMA Aboul-enein Y, Tanase IG, Udrıstıoıu FM, Bunacıu AA. TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS). Gazi University Journal of Science. 2012;25:843–851.
MLA Aboul-enein, Y et al. “TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS)”. Gazi University Journal of Science, vol. 25, no. 4, 2012, pp. 843-51.
Vancouver Aboul-enein Y, Tanase IG, Udrıstıoıu FM, Bunacıu AA. TRACE ELEMENTS ANALYSIS IN PAPER USING INDUCTIVELY COUPLED PLASMA - MASS SPECTROMETRY (ICP - MS). Gazi University Journal of Science. 2012;25(4):843-51.