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Investigation of Microstructure and Mechanical Properties (Ni-Cr-Mo) Dental Prosthesis

Year 2024, Volume: 1 Issue: 2, 62 - 66, 27.10.2024
https://doi.org/10.5281/zenodo.13996483

Abstract

Ni63.4-Cr23.6-Si1.4-Mo11 metal ceramic (CERMET) dental alloy is widely used in dentistry applications instead of expensive alloys. The biocompatibility of the Ni63.4-Cr23.6-Si1.4-Mo11 alloy may pose a problem due to the metals present in the alloy as a result of corrosion activity, so examining its microstructure and mechanical properties is quite important. 11mm diameter Ni63,4-Cr23,6-Si1,4-Mo11 alloy disc was produced using the standard casting method for analyzing. Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), Energy Dispersive X-ray Spectroscopy (EDX), Electrochemical Corrosion (Tafel extrapolation) and Micro Hardness test methods were used to examine the microstructure and mechanical properties of the alloy produced. According to the findings obtained from the results, the corrosion rate of the sample was measured as (940,3 x 10-3mpy) and the average Vickers hardness value was (366,54 kg x mm-2). It was seen that the alloy was in dendritic structure from SEM analysis, and Ni dominant XRD phase was detected in XRD tester. It was seen in SEM mapping that all the elements used in the alloy showed a homogeneous structure.

References

  • [1] Boroń, K., Zyska, A., “Tribological properties of nickel-based dental alloys”, Inżynieria Materiałowa, Vol. 39, Issue 5, Pages 92-196, 2015.
  • [2] Han-Cheol, C., “Electrochemical behavior of Co-Cr and Ni-Cr dental cast alloys”, Transactions of Nonferrous Metals Society of China, Vol. 19, Issue 4, Pages 785-790, 2009.
  • [3] Aygül, E., Yalçınkaya, S., Sahin, Y., “Biyomedikal uygulamalarda kullanılan co-cr-w ve co-cr-mo metal alaşımlarının eklemeli imalat yöntemi ile üretilmesi”, Mühendislik ve Multidisipliner Yaklaşımlar, 30-41, Güven Plus, İstanbul, 2019.
  • [4] Aygul, E., Yalcinkaya, S., Sahin, Y., “Corrosion Characteristics of an Additive-Manufacturing Cobalt-Chrome-Wolfram Biomedical Alloy Under Heat-Treated and Molybdenum-Doped Conditions”, Materıali ın Tehnologije, Vol. 54, Issue 4, Pages 535-540, 2020.
  • [5] Qian, C., Wu, X., Zhang, F., Yu, W., “Electrochemical impedance investigation of Ni-free Co-Cr-Mo and Co-Cr-Mo-Ni dental casting alloy for partial removable dental prosthesis frameworks”, The Journal of Prosthetic Dentistry, Vol. 116, Issue 1, Pages 112-118, 2016.
  • [6] Baciu, M., Baciu, E. R., Cimpoeşu, R., Gradinaru, I., “Study on Ni-Cr-Mo Dental Alloy Subjected to Electro Corrosion in Artificial Saliva”, In Advanced Materials Research Trans Tech Publications, Vol. 1143, Issue 1, Pages 7-12, 2017.
  • [7] Loch, J., Krzykała, A., Łukaszczyk, A., Augustyn-Pieniążek, J., “Corrosion Resistance and Microstructure of Recasting Cobalt Alloys Used in Dental Prosthetics”, Archives of Foundry Engineering, Vol. 17, Issue 2, Pages 63-68, 2017.
  • [8] Augustyn-Nadzieja, J., Łukaszczyk, A., Loch, J., “Effect of remelting of the Ni-22Cr-9Mo alloy on its microstructural and electrochemical properties”, Archives of Metallurgy and Materials, Vol. 62, Issue 1, Pages 411-418, 2017.
  • [9] Halem, Z., Halem, N., Abrudeanu, M., Chekroude, S., Petot, C., Petot-Ervas, G., “Transport properties of Al or Cr-doped nickel oxide relevant to the thermal oxidation of dilute Ni-Al and Ni-Cr alloys”, Solid State Ionics, Vol. 297, Issue 2, Pages 13-19, 2016.
  • [10] Kim, H. R., Jang, S. H., Kim, Y. K., Son, J. S., Min, B. K., Kim, K. H., Kwon, T. Y., “Microstructures and mechanical properties of Co-Cr dental alloys fabricated by three CAD/CAM-based processing techniques”, Materials, Vol. 9, Issue 7, Pages 596-603, 2016.
  • [11] Breme, J., Zhou, Y., Groh, L., “Development of a titanium alloy suitable for an optimized coating with hydroxyapatite”, Biomaterials, Vol. 16, Issue 3, Pages 239-244, 1995.
  • [12] Eliaz, N., “Corrosion of metallic biomaterials: A review”, Materials, Vol. 12, Issue 3, Pages 407-415, 2019.
  • [13] Manam, N. S., Harun, W. S. W., Shri, D. N. A., Ghani, S. A. C., Kurniawan, T., Ismail, M. H., Ibrahim, M., “Study of corrosion in biocompatible metals for implants: A review”, Journal of Alloys and Compounds, Vol. 701, Issue 3, Pages 698-715, 2017.
  • [14] Umoren, S. A., Solomon, M. M., Obot, I. B., Suleiman, R. K., “A critical review on the recent studies on plant biomaterials as corrosion inhibitors for industrial metals”, Journal of Industrial and Engineering Chemistry, Vol. 76, Issue 2, Pages 91-115, 2017.
  • [15] Mehta, K. K., Mukhopadhyay, P., Mandal, R. K., Singh, A. K., “Microstructure, texture, and orientation-dependent flow behavior of binary Ni-16Cr and Ni-16Mo solid solution alloys”, Metallurgical and Materials Transactions A, Vol. 46, Issue 8, Pages 3656-3669, 2015.
  • [16] Pathak, A., Singh, A. K., “Mechanical properties of Ni-based solid solution alloys: A first principles study”, Journal of applied research and technology, Vol. 15, Issue 5, Pages 449-453, 2017.
  • [17] Perricone, M. J., Dupont, J. N., “Effect of composition on the solidification behavior of several Ni-Cr-Mo and Fe-Ni-Cr-Mo alloys”, Metallurgical and Materials Transactions A, Vol. 37, Issue 4, Pages 1267-1280, 2006.

Investigation of Microstructure and Mechanical Properties (Ni-Cr-Mo) Dental Prosthesis

Year 2024, Volume: 1 Issue: 2, 62 - 66, 27.10.2024
https://doi.org/10.5281/zenodo.13996483

Abstract

Ni63.4-Cr23.6-Si1.4-Mo11 metal ceramic (CERMET) dental alloy is widely used in dentistry applications instead of expensive alloys. The biocompatibility of the Ni63.4-Cr23.6-Si1.4-Mo11 alloy may pose a problem due to the metals present in the alloy as a result of corrosion activity, so examining its microstructure and mechanical properties is quite important. 11mm diameter Ni63,4-Cr23,6-Si1,4-Mo11 alloy disc was produced using the standard casting method for analyzing. Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), Energy Dispersive X-ray Spectroscopy (EDX), Electrochemical Corrosion (Tafel extrapolation) and Micro Hardness test methods were used to examine the microstructure and mechanical properties of the alloy produced. According to the findings obtained from the results, the corrosion rate of the sample was measured as (940,3 x 10-3mpy) and the average Vickers hardness value was (366,54 kg x mm-2). It was seen that the alloy was in dendritic structure from SEM analysis, and Ni dominant XRD phase was detected in XRD tester. It was seen in SEM mapping that all the elements used in the alloy showed a homogeneous structure.

References

  • [1] Boroń, K., Zyska, A., “Tribological properties of nickel-based dental alloys”, Inżynieria Materiałowa, Vol. 39, Issue 5, Pages 92-196, 2015.
  • [2] Han-Cheol, C., “Electrochemical behavior of Co-Cr and Ni-Cr dental cast alloys”, Transactions of Nonferrous Metals Society of China, Vol. 19, Issue 4, Pages 785-790, 2009.
  • [3] Aygül, E., Yalçınkaya, S., Sahin, Y., “Biyomedikal uygulamalarda kullanılan co-cr-w ve co-cr-mo metal alaşımlarının eklemeli imalat yöntemi ile üretilmesi”, Mühendislik ve Multidisipliner Yaklaşımlar, 30-41, Güven Plus, İstanbul, 2019.
  • [4] Aygul, E., Yalcinkaya, S., Sahin, Y., “Corrosion Characteristics of an Additive-Manufacturing Cobalt-Chrome-Wolfram Biomedical Alloy Under Heat-Treated and Molybdenum-Doped Conditions”, Materıali ın Tehnologije, Vol. 54, Issue 4, Pages 535-540, 2020.
  • [5] Qian, C., Wu, X., Zhang, F., Yu, W., “Electrochemical impedance investigation of Ni-free Co-Cr-Mo and Co-Cr-Mo-Ni dental casting alloy for partial removable dental prosthesis frameworks”, The Journal of Prosthetic Dentistry, Vol. 116, Issue 1, Pages 112-118, 2016.
  • [6] Baciu, M., Baciu, E. R., Cimpoeşu, R., Gradinaru, I., “Study on Ni-Cr-Mo Dental Alloy Subjected to Electro Corrosion in Artificial Saliva”, In Advanced Materials Research Trans Tech Publications, Vol. 1143, Issue 1, Pages 7-12, 2017.
  • [7] Loch, J., Krzykała, A., Łukaszczyk, A., Augustyn-Pieniążek, J., “Corrosion Resistance and Microstructure of Recasting Cobalt Alloys Used in Dental Prosthetics”, Archives of Foundry Engineering, Vol. 17, Issue 2, Pages 63-68, 2017.
  • [8] Augustyn-Nadzieja, J., Łukaszczyk, A., Loch, J., “Effect of remelting of the Ni-22Cr-9Mo alloy on its microstructural and electrochemical properties”, Archives of Metallurgy and Materials, Vol. 62, Issue 1, Pages 411-418, 2017.
  • [9] Halem, Z., Halem, N., Abrudeanu, M., Chekroude, S., Petot, C., Petot-Ervas, G., “Transport properties of Al or Cr-doped nickel oxide relevant to the thermal oxidation of dilute Ni-Al and Ni-Cr alloys”, Solid State Ionics, Vol. 297, Issue 2, Pages 13-19, 2016.
  • [10] Kim, H. R., Jang, S. H., Kim, Y. K., Son, J. S., Min, B. K., Kim, K. H., Kwon, T. Y., “Microstructures and mechanical properties of Co-Cr dental alloys fabricated by three CAD/CAM-based processing techniques”, Materials, Vol. 9, Issue 7, Pages 596-603, 2016.
  • [11] Breme, J., Zhou, Y., Groh, L., “Development of a titanium alloy suitable for an optimized coating with hydroxyapatite”, Biomaterials, Vol. 16, Issue 3, Pages 239-244, 1995.
  • [12] Eliaz, N., “Corrosion of metallic biomaterials: A review”, Materials, Vol. 12, Issue 3, Pages 407-415, 2019.
  • [13] Manam, N. S., Harun, W. S. W., Shri, D. N. A., Ghani, S. A. C., Kurniawan, T., Ismail, M. H., Ibrahim, M., “Study of corrosion in biocompatible metals for implants: A review”, Journal of Alloys and Compounds, Vol. 701, Issue 3, Pages 698-715, 2017.
  • [14] Umoren, S. A., Solomon, M. M., Obot, I. B., Suleiman, R. K., “A critical review on the recent studies on plant biomaterials as corrosion inhibitors for industrial metals”, Journal of Industrial and Engineering Chemistry, Vol. 76, Issue 2, Pages 91-115, 2017.
  • [15] Mehta, K. K., Mukhopadhyay, P., Mandal, R. K., Singh, A. K., “Microstructure, texture, and orientation-dependent flow behavior of binary Ni-16Cr and Ni-16Mo solid solution alloys”, Metallurgical and Materials Transactions A, Vol. 46, Issue 8, Pages 3656-3669, 2015.
  • [16] Pathak, A., Singh, A. K., “Mechanical properties of Ni-based solid solution alloys: A first principles study”, Journal of applied research and technology, Vol. 15, Issue 5, Pages 449-453, 2017.
  • [17] Perricone, M. J., Dupont, J. N., “Effect of composition on the solidification behavior of several Ni-Cr-Mo and Fe-Ni-Cr-Mo alloys”, Metallurgical and Materials Transactions A, Vol. 37, Issue 4, Pages 1267-1280, 2006.
There are 17 citations in total.

Details

Primary Language English
Subjects Biomaterials in Biomedical Engineering
Journal Section Research Article
Authors

Ebuzer Aygül 0000-0003-0930-3975

Publication Date October 27, 2024
Submission Date March 7, 2024
Acceptance Date October 11, 2024
Published in Issue Year 2024 Volume: 1 Issue: 2

Cite

APA Aygül, E. (2024). Investigation of Microstructure and Mechanical Properties (Ni-Cr-Mo) Dental Prosthesis. Hendese Teknik Bilimler Ve Mühendislik Dergisi, 1(2), 62-66. https://doi.org/10.5281/zenodo.13996483