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Year 2015, , 173 - 180, 30.12.2015
https://doi.org/10.17350/HJSE19030000022

Abstract

References

  • Lazo L M, Burillo G. Novel comb-type hydrogels of net- [PP-g-AAc]-g-4VP synthesized by gamma radiation, with possible application on Cu2+ immobilization. Radiation Physics and Chemistry 79 (2010) 1–8.
  • Adem E, Burillo G, Bucio E, Magana C, Avalos-Borja M. Characterization of interpenetrating Networks of acrylicacid (AAc) and N-isopropylacrylamide (NIPAAm) synthesized by ionizing radiation. Radiation Physics and Chemistry 78 (2009) 549–552.
  • Zheng Y, Wang A. Evaluation of ammonium removal using a chitosan-g-poly (acrylic acid)/rectorite hydrogel composite. Journal of Hazardous Materials 171 (2009) 671–677.
  • Zheng Y, Zhu Y, Wang A. Highly efficient and selective adsorption of malachite green onto granular composite hydrogel. Chemical Engineering Journal 257 (2014) 66–73.
  • Panic VV, Velickovic SJ. Removal of model cationic dye by adsorption onto poly (methacrylic acid)/zeolite hydrogel composites: Kinetics, equilibrium study and image analysis. Separation and Purification Technology 122 (2014) 384– 394.
  • Pradhan AK, Rana PK, Sahoo PK. Biodegradability and swelling capacity of kaolin based chitosan-g-PHEMA nanocomposite hydrogel. International Journal of Biological Macromolecules 74 (2015) 620–626.
  • Li B, Huang H, Guo Y, Zhang Y. Diatomite-immobilized BiOI hybrid photocatalyst: Facile deposition synthesis and enhanced photocatalytic activity. Applied Surface Science 353 (2015) 1179–1185.
  • Yu TT, Li KL, Guo XL, Li F, Huang JM, Zhang YX. Facile decolorization of methylene blue by morphology- dependence Journal of Physical and Chemistry of Solids, http://dx.doi. org/10.1016/j.jpcs.2015.08.013.
  • Dehestaniathar S., Khajelakzay M, Ramezani-Farani M, Ijadpanah-Saravi H. Modified diatomite-supported CuO- TiO2 composite: Preparation, characterization and catalytic CO oxidation. Journal of the Taiwan Institute of Chemical Engineers 000 (2015) 1–7.
  • Ozkahraman B, Acar I, Emik S. Removal of cationic dyes from aqueous solutions with poly (N-isopropylacrylamide- co-itaconic acid) hydrogels. Polym. Bull. 66 (2011) 551–570.
  • Ortaboy S, Acar ET, Atun G, Emik S, Iyim TB, Gülcü G, Özgümüs S. Performance of acrylic monomer based terpolymer/montmorillonite nanocomposite hydrogels for U(VI) removal from aqueous solutions. Chemical Engineering Research and Design 91 (2013) 670–680.
  • Liua J, Lia Q, Sua Y, Yue Q, Gao B. Characterization and swelling–deswelling properties of wheat strawcellulose based semi-IPNs hydrogel. Carbohydrate Polymers 107 (2014) 232–240.
  • Huang Y, Zeng M, Ren J, Wang J, Fan L, Xu Q. Preparation and swelling properties of graphene oxide/poly(acrylic acid-co- acrylamide) super-absorbent hydrogel nanocomposites”, Colloids and Surfaces A: Physicochem. Eng. Aspects 401 (2012) 97– 106.
  • Hezaveh H, Muhamad II. Modification and swelling kinetic study of kappa-carrageenan-based hydrogel for controlled release study. Journal of the Taiwan Institute of Chemical Engineers 44 (2013) 182–19.
  • Sizir U, Kose DA, Yurdakul O. Synthesis, Spectroscopic and Thermal Characterization of Non-Metal Cation (NMC) Pentaborates Salts Containing 2-amino-5-nitropyridine and 2-amino-6-methylpyridine as Cation. Hittite Journal of Science and Engineering 2 (1) (2015) 91-96.
  • Chen J, Liu M, Liu H, Ma L. Synthesis, swelling and drug release behavior of poly (N,N-diethylacrylamide-co-N- hydroxymethyl acrylamide) hydrogel. Materials Science and Engineering C 29 (2009) 2116–2123.
  • Wang J, Ren S, Guo M. Preparation and humidity controlling behaviors of sepiolite/polyacrylic acid (sodium) composite. Procedia Engineering 27 (2012) 423 – 430.
  • Gao B, Hu H, Guo J, Li Y. Preparation of polymethacrylic acid-grafted HEMA/PVP microspheres and preliminary study on basic protein adsorption. Colloids and Surfaces B: Biointerfaces 77 (2010) 206–213.
  • Zheng L, Wang C, Shu Y, Yan X, Li L. Utilization of diatomite/ chitosan–Fe (III) composite for the removal of anionic azo dyes from wastewater: equilibrium, kinetics and thermodynamics. Colloids and Surfaces A: Physicochem. Eng. Aspects 468 (2015) 129–139.
  • Ali A M , Ajji Z. Investigation and characterization of PVA-g-AAc/Zolmembranes for possible practical use in separation processes. Radiation Physicsand Chemistry78(2009)927–932.
  • Meradia H, Atoui L, Bahloul L, Labiod K, Ismail F. Contribution to characterization of the diatomite for industrial application. International Conference on Technologies and Materials for Renewable Energy. Environment and Sustainability, TMREES15 Energy Procedia 00 (2015) 000–000.
  • Ganesh S B, Suresh S. U, Ajay S C. Effects of NCO:OH ratio and HEMA on the physicochemical properties of photocurable poly(ester-urethane)methacrylates. J. Coat. Technol. Res., 12 (3) 571–585, 2015.
  • Soto-Quintero A, Meneses-Acosta A, Romo-Uribe A. Tailoring the viscoelastic, swelling kinetics and antibacterial behavior of poly(ethylene glycol)-based hydrogels with polycaprolactone. European Polymer Journal 70 (2015) 1–17.
  • Meena A K, Mishra G K, Rai P K, Rajagopal C, Nagar P N. Removal heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent. Journal of Hazardous Materials B122 (2005) 161-170.
  • Amuda O S, Giwa A A, Bello L A. Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochemical Engineering Journal 36 (2007) 174-181.
  • Hui KS, Chao C Y H, Kot S C. Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash. Journal of Hazardous Materials B127 (2005) 89-101.
  • Mohammad M, Maitra S, Ahmad N, Bustam A, Sen T K, Dutta B K. Metal ion removal from aqueous solutions using physic seed hull. Journal of Hazardous Materials 179 (2010) 363- 372.
  • Ozkahraman B, Acar I, Güçlü K, Güçlü G. Synthesis of Zn(II) Ion-Imprinted Polymeric Adsorbent for Selective Removal of Zinc from Aqueous Solution. Polymer-Plastics Technology and Engineering 50 (2011) 216–219.

Synthesis and characterization of Poly HEMA-co-AAc /Diatomite hydrogel composites: Their application for heavy metal removal from the aqueous solution

Year 2015, , 173 - 180, 30.12.2015
https://doi.org/10.17350/HJSE19030000022

Abstract

P oly 2-hydroxyethyl methacrylate-co-acrylic acid /diatomite hydrogel composite DHC materials were synthesized using in situ free radical addition polymerization technique. The effects of particle size and amount of diatomite were investigated on swelling properties such as the swelling degree SD , equilibrium swelling degree ESD and water retention WR of DHC. The particle size and amount of diatomite were not affected clearly in the swelling properties. The synthesized DHC with the particle size of -45μm and the amount of 5 wt % of diatomite showed the highest swelling properties. The SD g/g , WR % and ESD % values of hydrogel were increased up to 29.2, 45.5 and 96.7 from 1.1, 41.3 and 89.3 by adding diatomite into the structure of hydrogel, respectively. The hydrogel and DHC were characterized using Fourier transform infrared spectrometer FTIR and an optical microscope. Also, their thermal behavior was analyzed by differential scanning calorimeter DSC . The FTIR spectrums showed that diatomite incorporated into the hydrogel matrix at the high amount of diatomite. The DSC results indicated that the glass transition temperature Tg and melting temperature Tm of hydrogel increased with the addition of 2 wt % diatomite. The adsorption studies were performed using the hydrogel composite including 5 wt % of diatomite

References

  • Lazo L M, Burillo G. Novel comb-type hydrogels of net- [PP-g-AAc]-g-4VP synthesized by gamma radiation, with possible application on Cu2+ immobilization. Radiation Physics and Chemistry 79 (2010) 1–8.
  • Adem E, Burillo G, Bucio E, Magana C, Avalos-Borja M. Characterization of interpenetrating Networks of acrylicacid (AAc) and N-isopropylacrylamide (NIPAAm) synthesized by ionizing radiation. Radiation Physics and Chemistry 78 (2009) 549–552.
  • Zheng Y, Wang A. Evaluation of ammonium removal using a chitosan-g-poly (acrylic acid)/rectorite hydrogel composite. Journal of Hazardous Materials 171 (2009) 671–677.
  • Zheng Y, Zhu Y, Wang A. Highly efficient and selective adsorption of malachite green onto granular composite hydrogel. Chemical Engineering Journal 257 (2014) 66–73.
  • Panic VV, Velickovic SJ. Removal of model cationic dye by adsorption onto poly (methacrylic acid)/zeolite hydrogel composites: Kinetics, equilibrium study and image analysis. Separation and Purification Technology 122 (2014) 384– 394.
  • Pradhan AK, Rana PK, Sahoo PK. Biodegradability and swelling capacity of kaolin based chitosan-g-PHEMA nanocomposite hydrogel. International Journal of Biological Macromolecules 74 (2015) 620–626.
  • Li B, Huang H, Guo Y, Zhang Y. Diatomite-immobilized BiOI hybrid photocatalyst: Facile deposition synthesis and enhanced photocatalytic activity. Applied Surface Science 353 (2015) 1179–1185.
  • Yu TT, Li KL, Guo XL, Li F, Huang JM, Zhang YX. Facile decolorization of methylene blue by morphology- dependence Journal of Physical and Chemistry of Solids, http://dx.doi. org/10.1016/j.jpcs.2015.08.013.
  • Dehestaniathar S., Khajelakzay M, Ramezani-Farani M, Ijadpanah-Saravi H. Modified diatomite-supported CuO- TiO2 composite: Preparation, characterization and catalytic CO oxidation. Journal of the Taiwan Institute of Chemical Engineers 000 (2015) 1–7.
  • Ozkahraman B, Acar I, Emik S. Removal of cationic dyes from aqueous solutions with poly (N-isopropylacrylamide- co-itaconic acid) hydrogels. Polym. Bull. 66 (2011) 551–570.
  • Ortaboy S, Acar ET, Atun G, Emik S, Iyim TB, Gülcü G, Özgümüs S. Performance of acrylic monomer based terpolymer/montmorillonite nanocomposite hydrogels for U(VI) removal from aqueous solutions. Chemical Engineering Research and Design 91 (2013) 670–680.
  • Liua J, Lia Q, Sua Y, Yue Q, Gao B. Characterization and swelling–deswelling properties of wheat strawcellulose based semi-IPNs hydrogel. Carbohydrate Polymers 107 (2014) 232–240.
  • Huang Y, Zeng M, Ren J, Wang J, Fan L, Xu Q. Preparation and swelling properties of graphene oxide/poly(acrylic acid-co- acrylamide) super-absorbent hydrogel nanocomposites”, Colloids and Surfaces A: Physicochem. Eng. Aspects 401 (2012) 97– 106.
  • Hezaveh H, Muhamad II. Modification and swelling kinetic study of kappa-carrageenan-based hydrogel for controlled release study. Journal of the Taiwan Institute of Chemical Engineers 44 (2013) 182–19.
  • Sizir U, Kose DA, Yurdakul O. Synthesis, Spectroscopic and Thermal Characterization of Non-Metal Cation (NMC) Pentaborates Salts Containing 2-amino-5-nitropyridine and 2-amino-6-methylpyridine as Cation. Hittite Journal of Science and Engineering 2 (1) (2015) 91-96.
  • Chen J, Liu M, Liu H, Ma L. Synthesis, swelling and drug release behavior of poly (N,N-diethylacrylamide-co-N- hydroxymethyl acrylamide) hydrogel. Materials Science and Engineering C 29 (2009) 2116–2123.
  • Wang J, Ren S, Guo M. Preparation and humidity controlling behaviors of sepiolite/polyacrylic acid (sodium) composite. Procedia Engineering 27 (2012) 423 – 430.
  • Gao B, Hu H, Guo J, Li Y. Preparation of polymethacrylic acid-grafted HEMA/PVP microspheres and preliminary study on basic protein adsorption. Colloids and Surfaces B: Biointerfaces 77 (2010) 206–213.
  • Zheng L, Wang C, Shu Y, Yan X, Li L. Utilization of diatomite/ chitosan–Fe (III) composite for the removal of anionic azo dyes from wastewater: equilibrium, kinetics and thermodynamics. Colloids and Surfaces A: Physicochem. Eng. Aspects 468 (2015) 129–139.
  • Ali A M , Ajji Z. Investigation and characterization of PVA-g-AAc/Zolmembranes for possible practical use in separation processes. Radiation Physicsand Chemistry78(2009)927–932.
  • Meradia H, Atoui L, Bahloul L, Labiod K, Ismail F. Contribution to characterization of the diatomite for industrial application. International Conference on Technologies and Materials for Renewable Energy. Environment and Sustainability, TMREES15 Energy Procedia 00 (2015) 000–000.
  • Ganesh S B, Suresh S. U, Ajay S C. Effects of NCO:OH ratio and HEMA on the physicochemical properties of photocurable poly(ester-urethane)methacrylates. J. Coat. Technol. Res., 12 (3) 571–585, 2015.
  • Soto-Quintero A, Meneses-Acosta A, Romo-Uribe A. Tailoring the viscoelastic, swelling kinetics and antibacterial behavior of poly(ethylene glycol)-based hydrogels with polycaprolactone. European Polymer Journal 70 (2015) 1–17.
  • Meena A K, Mishra G K, Rai P K, Rajagopal C, Nagar P N. Removal heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent. Journal of Hazardous Materials B122 (2005) 161-170.
  • Amuda O S, Giwa A A, Bello L A. Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochemical Engineering Journal 36 (2007) 174-181.
  • Hui KS, Chao C Y H, Kot S C. Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash. Journal of Hazardous Materials B127 (2005) 89-101.
  • Mohammad M, Maitra S, Ahmad N, Bustam A, Sen T K, Dutta B K. Metal ion removal from aqueous solutions using physic seed hull. Journal of Hazardous Materials 179 (2010) 363- 372.
  • Ozkahraman B, Acar I, Güçlü K, Güçlü G. Synthesis of Zn(II) Ion-Imprinted Polymeric Adsorbent for Selective Removal of Zinc from Aqueous Solution. Polymer-Plastics Technology and Engineering 50 (2011) 216–219.
There are 28 citations in total.

Details

Primary Language English
Journal Section Research Article
Authors

Filiz Boran This is me

Filiz Akti This is me

Publication Date December 30, 2015
Published in Issue Year 2015

Cite

Vancouver Boran F, Akti F. Synthesis and characterization of Poly HEMA-co-AAc /Diatomite hydrogel composites: Their application for heavy metal removal from the aqueous solution. Hittite J Sci Eng. 2015;2(2):173-80.

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