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Year 2016, Volume 3, Issue 2, 73 - 80, 31.12.2016
https://doi.org/10.17350/HJSE19030000034

Abstract

References

  • 1. Polsongkram D, Chamninok P, Pukird S, Chow L, Lupan O, Chai G, Khallaf H, Park S, Schulte A. Effect of synthesis conditions on the growth of ZnO nanorods via hydrothermal method. Physica B 403 (2008) 3713-3717.
  • 2. Zhang J, Sun L, Yin J, Su H, Liao C, Yan C. Control of ZnO morphology via a simple solution route. Chem. Mater. 14 (2002) 4172-4177.
  • 3. Rai P, Kwack W, Yu Y. Solvothermal synthesis of ZnO nanostructures and their morphology-dependent gassensing properties. Applied Materials Interfaces 5 (2013) 3026-3032.
  • 4. Singh O, Kohli N, Singh RC. Precursor controlled morphology of zinc oxide and its sensing behaviour. Sensors and Actuators B, 178 (2013) 149-154.
  • 5. Korotcenkov G, The role of morphology and crystallographic structure of metal oxides in response of conductometrictype gas sensing. Materials Science and Engineering Reports 61(2008) 1-39.
  • 7. Zhang H, Yang D, Yi YJ, Ma XY, Xu J, Que DL. Low temperature synthesis of flowerlike ZnO nanostructures by cetyltrimethylammonium bromide-assisted hydrothermal process. Journal of Physical Chemistry B, 108, 13 (2004) 3955–3958.
  • 8. Li WJ, Shi EW, Zhong WZ, Yin ZW. Growth mechanism and growth habit of oxide crystals. J. Cryst. Growth, 203 (1999) 186-196.
  • 9. Ozer IO, Texture development in ZnO-based varistors, effects of inversion boundaries on texture development and relationships between texture and electrical characteristics, Anadolu University, Doctorate thesis, May 2010.
  • 10. Mullin JW. Crystallisation, third ed. Butterworth/Heinemann, Oxford, 1997.

Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis

Year 2016, Volume 3, Issue 2, 73 - 80, 31.12.2016
https://doi.org/10.17350/HJSE19030000034

Abstract

Semiconducting metal oxide sensors have been widely studied due to their small dimensions, low cost and low power consumption. ZnO is a potential material for gas sensor applications because of its high piezoelectric coefficient, great stability of its hexagonal phase and its pyroelectric property. Hydrothermal synthesis is one of the most useful methods to produce homogeneous, nanosized ZnO powders with high purity, controlled particle size and morphology. The research objectives of this study were to understand formation and growth process of ZnO particles with various morphologies and to investigate role of starting materials, i.e., zinc chloride ZnCl2 and zinc nitrate hexahydrate Zn NO3 2 .6H2 O on the particle morphology. ZnO particles with various morphologies were synthesized via an unstirred hydrothermal method. When using ZnCl2 as a precursor, the final morphology was rod like with a taped tip length of the rod 0.5-1 μm after 12 h at 100 °C. On the other hand, final morphology of the produced ZnO particles was branch rod like 5-10 μm when using Zn NO3 2 .6H2 O as precursor under the same synthesis conditions. Accordingly, a proposed growth mechanism has been suggested.

References

  • 1. Polsongkram D, Chamninok P, Pukird S, Chow L, Lupan O, Chai G, Khallaf H, Park S, Schulte A. Effect of synthesis conditions on the growth of ZnO nanorods via hydrothermal method. Physica B 403 (2008) 3713-3717.
  • 2. Zhang J, Sun L, Yin J, Su H, Liao C, Yan C. Control of ZnO morphology via a simple solution route. Chem. Mater. 14 (2002) 4172-4177.
  • 3. Rai P, Kwack W, Yu Y. Solvothermal synthesis of ZnO nanostructures and their morphology-dependent gassensing properties. Applied Materials Interfaces 5 (2013) 3026-3032.
  • 4. Singh O, Kohli N, Singh RC. Precursor controlled morphology of zinc oxide and its sensing behaviour. Sensors and Actuators B, 178 (2013) 149-154.
  • 5. Korotcenkov G, The role of morphology and crystallographic structure of metal oxides in response of conductometrictype gas sensing. Materials Science and Engineering Reports 61(2008) 1-39.
  • 7. Zhang H, Yang D, Yi YJ, Ma XY, Xu J, Que DL. Low temperature synthesis of flowerlike ZnO nanostructures by cetyltrimethylammonium bromide-assisted hydrothermal process. Journal of Physical Chemistry B, 108, 13 (2004) 3955–3958.
  • 8. Li WJ, Shi EW, Zhong WZ, Yin ZW. Growth mechanism and growth habit of oxide crystals. J. Cryst. Growth, 203 (1999) 186-196.
  • 9. Ozer IO, Texture development in ZnO-based varistors, effects of inversion boundaries on texture development and relationships between texture and electrical characteristics, Anadolu University, Doctorate thesis, May 2010.
  • 10. Mullin JW. Crystallisation, third ed. Butterworth/Heinemann, Oxford, 1997.

Details

Primary Language English
Journal Section Research Article
Authors

Emel OZEL This is me
Anadolu University, Department of Materials Science and Engineering, Eskisehir, TURKEY


Ikbal Gözde TUNCOLU>
Anadolu University, Department of Materials Science and Engineering, Eskisehir, TURKEY
0000-0002-3852-9853


Cem ACİKSARİ This is me
Anadolu University, Department of Materials Science and Engineering, Eskisehir, TURKEY


Ender SUVACİ This is me
Anadolu University, Department of Materials Science and Engineering, Eskisehir, TURKEY

Publication Date December 31, 2016
Application Date
Acceptance Date
Published in Issue Year 2016, Volume 3, Issue 2

Cite

Bibtex @ { hjse860017, journal = {Hittite Journal of Science and Engineering}, eissn = {2148-4171}, address = {Hitit Üniversitesi Mühendislik Fakültesi Kuzey Kampüsü Çevre Yolu Bulvarı 19030 Çorum / TÜRKİYE}, publisher = {Hitit University}, year = {2016}, volume = {3}, number = {2}, pages = {73 - 80}, doi = {10.17350/HJSE19030000034}, title = {Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis}, key = {cite}, author = {Ozel, Emel and Tuncolu, Ikbal Gözde and Aciksari, Cem and Suvaci, Ender} }
APA Ozel, E. , Tuncolu, I. G. , Aciksari, C. & Suvaci, E. (2016). Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis . Hittite Journal of Science and Engineering , 3 (2) , 73-80 . DOI: 10.17350/HJSE19030000034
MLA Ozel, E. , Tuncolu, I. G. , Aciksari, C. , Suvaci, E. "Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis" . Hittite Journal of Science and Engineering 3 (2016 ): 73-80 <https://dergipark.org.tr/en/pub/hjse/issue/59669/860017>
Chicago Ozel, E. , Tuncolu, I. G. , Aciksari, C. , Suvaci, E. "Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis". Hittite Journal of Science and Engineering 3 (2016 ): 73-80
RIS TY - JOUR T1 - Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis AU - EmelOzel, Ikbal GözdeTuncolu, CemAciksari, EnderSuvaci Y1 - 2016 PY - 2016 N1 - doi: 10.17350/HJSE19030000034 DO - 10.17350/HJSE19030000034 T2 - Hittite Journal of Science and Engineering JF - Journal JO - JOR SP - 73 EP - 80 VL - 3 IS - 2 SN - -2148-4171 M3 - doi: 10.17350/HJSE19030000034 UR - https://doi.org/10.17350/HJSE19030000034 Y2 - 2022 ER -
EndNote %0 Hittite Journal of Science and Engineering Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis %A Emel Ozel , Ikbal Gözde Tuncolu , Cem Aciksari , Ender Suvaci %T Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis %D 2016 %J Hittite Journal of Science and Engineering %P -2148-4171 %V 3 %N 2 %R doi: 10.17350/HJSE19030000034 %U 10.17350/HJSE19030000034
ISNAD Ozel, Emel , Tuncolu, Ikbal Gözde , Aciksari, Cem , Suvaci, Ender . "Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis". Hittite Journal of Science and Engineering 3 / 2 (December 2016): 73-80 . https://doi.org/10.17350/HJSE19030000034
AMA Ozel E. , Tuncolu I. G. , Aciksari C. , Suvaci E. Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis. Hittite J Sci Eng. 2016; 3(2): 73-80.
Vancouver Ozel E. , Tuncolu I. G. , Aciksari C. , Suvaci E. Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis. Hittite Journal of Science and Engineering. 2016; 3(2): 73-80.
IEEE E. Ozel , I. G. Tuncolu , C. Aciksari and E. Suvaci , "Effect of Precursor Type on Zinc Oxide Formation and Morphology Development during Hydrothermal Synthesis", Hittite Journal of Science and Engineering, vol. 3, no. 2, pp. 73-80, Dec. 2016, doi:10.17350/HJSE19030000034