Fabrication and Analysis Of 2D/3D Heterojunction Between Continuous Few-layer WS2 Film and Si (100)†
Year 2021,
Volume: 8 Issue: 1, 1 - 5, 31.03.2021
Merve Acar
Soheil Mobtakeri
Mehmet Ertuğrul
Emre Gür
Abstract
Transition metal dichalcogenide (TDMCs) placed on a 3D semiconductor substrate haveleads to significant advances in the electronic industry with new opportunities based on 2D/3D heterojunction based diverse devices without any restrictions, such as lattice compatibility. In this study, magnetron sputtering technique was used to grow layered tungsten disulfide (WS2) thin films onto p-Si and thus WS2/p-Si heterojunctions were created. The structural and chemical parameters of this sputtered WS2 films were investigated using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). Electrical characterization of WS2/p-Si heterojunction was also obtained to investigate Log (I)-V and linear I-V characteristics. A typical diode like I-V behavior was observed with a five-ordered rectifying ratio. It was observed that the heterojunction has a barrier height of 0.48 eV, the leakage current at -0.2 V is 2.25×10-6 A and the ideality factor is 5.7. This work show that single step magnetron sputtering WS2/p-Si heterojunction has great importance for heterojunction based future nanoelectronic devices.
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Year 2021,
Volume: 8 Issue: 1, 1 - 5, 31.03.2021
Merve Acar
Soheil Mobtakeri
Mehmet Ertuğrul
Emre Gür
References
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Liu, B. L.; Abbas, A.; Zhou, C. W., Two-Dimensional Semiconductors: From Materials Preparation to Electronic Applications. Adv Electron Mater 2017, 3 (7).
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- Nourbakhsh, A.; Zubair, A.; Dresselhaus, M. S.; Palacios, T. s., Transport properties of a MoS2/WSe2 heterojunction transistor and its potential for application. Nano Lett 2016, 16 (2), 1359-1366.
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- Yu, Y.; Fong, P. W.; Wang, S.; Surya, C., Fabrication of WS 2/GaN pn Junction by Wafer-Scale WS 2 Thin Film Transfer. Sci Rep-Uk 2016, 6, 37833.
- Zhao, Z. H.; Wu, D.; Guo, J. W.; Wu, E. P.; Jia, C.; Shi, Z. F.; Tian, Y. T.; Li, X. J.; Tian, Y. Z., Synthesis of large-area 2D WS2 films and fabrication of a heterostructure for self-powered ultraviolet photodetection and imaging applications. J Mater Chem C 2019, 7 (39), 12121-12126.
- Tang, H.; Zhang, H.; Chen, X.; Wang, Y.; Zhang, X.; Cai, P.; Bao, W., Recent progress in devices and circuits based on wafer-scale transition metal dichalcogenides. Science China Information Sciences 2019, 62 (12), 220401.
- Zavabeti, A.; Jannat, A.; Zhong, L.; Haidry, A. A.; Yao, Z.; Ou, J. Z., Two-Dimensional Materials in Large-Areas: Synthesis, Properties and Applications. Nano-Micro Lett 2020, 12 (1), 1-34.
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- Cai, Z.; Liu, B.; Zou, X.; Cheng, H.-M., Chemical vapor deposition growth and applications of two-dimensional materials and their heterostructures. Chemical reviews 2018, 118 (13), 6091-6133.
- Berkdemir, A.; Gutiérrez, H. R.; Botello-Méndez, A. R.; Perea-López, N.; Elías, A. L.; Chia, C.-I.; Wang, B.; Crespi, V. H.; López-Urías, F.; Charlier, J.-C., Identification of individual and few layers of WS 2 using Raman spectroscopy. Sci Rep-Uk 2013, 3 (1), 1-8.
- Gora, V.; Chawanda, A.; Nyamhere, C.; Auret, F. D.; Mazunga, F.; Jaure, T.; Chibaya, B.; Omotoso, E.; Danga, H. T.; Tunhuma, S. M., Comparison of nickel, cobalt, palladium, and tungsten Schottky contacts on n-4H-silicon carbide. Physica B: Condensed Matter 2018, 535, 333-337.
- Wong, S. L.; Liu, H.; Chi, D., Recent progress in chemical vapor deposition growth of two-dimensional transition metal dichalcogenides. Progress in Crystal Growth and Characterization of Materials 2016, 62 (3), 9-28.
- Koçak, Y.; Gür, E., Growth control of WS2; from 2D layer by layer to 3D vertical standing Nano-Walls. Acs Appl Mater Inter 2020.