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Protection of Copper From Corrosion With Nicotinamide Inhibitor

Year 2021, Volume 8, Issue 3, 273 - 277, 29.09.2021
https://doi.org/10.17350/HJSE19030000239

Abstract

Copper is used extensively in industry since its superior metallic properties. Since the corrosion resistance of copper is low in acidic media, it is important to apply corrosion prevent methods. In this study, the environmentally friendly nicotinamide compound was used as an inhibitor to protect copper from corrosion. In this study, firstly, the Cyclic Voltammetry Technique was used to determine the electrochemical behavior of copper in 0.1 M HCl acid solution. Then, Tafel polarization method was applied to determine the corrosion behavior of copper in 0.1 M HCl acid solution in the absence of nicotinamide inhibitor and in the presence of 500 ppm, 750 ppm, 1000 ppm nicotinamide. The optimum time was determined for each concentration by keeping the inhibitor at these 3 different concentrations for 0, 15, 30, 45 and 60 minutes. The highest inhibition efficiency was obtained as 95.3% in 1000 ppm nicotinamide concentration in 30 minutes residence time, and the best corrosion potential was -0.145 V in 1000 ppm nicotinamide concentration in 45 minutes residence time. 750 ppm inhibitor concentration can be used in cases where the duration is not important, as the inhibition efficiency value is reached as 94.6% in a 60 minutes residence time at a 750 ppm nicotinamide concentration.

References

  • [1] A. Fateh, M. Aliofkhazraei, A.R. Rezvanian, Review of corrosive environments for copper and its corrosion inhibitors, Arabian Journal of Chemistry. 13 (2020) 481–544. https://doi.org/10.1016/j.arabjc.2017.05.021.
  • [2] R. Javaherdashti, How corrosion affects industry and life, Anti-Corrosion Methods and Materials. 47 (2000) 30–34. https://doi.org/10.1108/00035590010310003.
  • [3] X.F. Zhang, Y.Q. Chen, J.M. Hu, Robust superhydrophobic SiO2/polydimethylsiloxane films coated on mild steel for corrosion protection, Corrosion Science. 166 (2020). https://doi.org/10.1016/j.corsci.2020.108452.
  • [4] G. Tansuǧ, T. Tüken, E.S. Giray, G. Findikkiran, G. Siǧircik, O. Demirkol, M. Erbil, A new corrosion inhibitor for copper protection, Corrosion Science. 84 (2014) 21–29. https://doi.org/10.1016/j.corsci.2014.03.004.
  • [5] G. Moretti, F. Guidi, Tryptophan as copper corrosion inhibitor in 0.5 M aerated sulfuric acid, Corrosion Science. 44 (2002) 1995–2011. https://doi.org/10.1016/S0010-938X(02)00020-3.
  • [6] Q.B. Zhang, Y.X. Hua, Corrosion inhibition of mild steel by alkylimidazolium ionic liquids in hydrochloric acid, Electrochimica Acta. 54 (2009) 1881–1887. https://doi.org/10.1016/j.electacta.2008.10.025.
  • [7] R. Natarajan, F.S. Zahir Said Al Shibli, Synthesis of biomass derived product from Ziziphus spina-christi and application for surface protection of metal under acidic environment- Performance evaluation and thermodynamic studies, Chemosphere. 284 (2021) 131375. https://doi.org/10.1016/j.chemosphere.2021.131375.
  • [8] J.M. Gaidis, Chemistry of corrosion inhibitors, Cement and Concrete Composites. 26 (2004) 181–189. https://doi.org/10.1016/S0958-9465(03)00037-4.
  • [9] C.N. Hippolyte, B.Y. Serge, A. Sagne, J. Creus, T. Albert, Nicotinamide Inhibition Properties for Copper Corrosion in 3.5% NaCl Solution: Experimental and Theorical Investigations, Journal of Materials Science and Chemical Engineering. 06 (2018) 100–121. https://doi.org/10.4236/msce.2018.63008.
  • [10] H. Gerengi, H.I. Ugras, M.M. Solomon, S.A. Umoren, M. Kurtay, N. Atar, Synergistic corrosion inhibition effect of 1-ethyl-1-methylpyrrolidinium tetrafluoroborate and iodide ions for low carbon steel in HCl solution, Journal of Adhesion Science and Technology. 30 (2016) 2383–2403. https://doi.org/10.1080/01694243.2016.1183407.
  • [11] A. Asan, M. Kabasakaloǧlu, M. Işiklan, Z. Kiliç, Corrosion inhibition of brass in presence of terdentate ligands in chloride solution, Corrosion Science. 47 (2005). https://doi.org/10.1016/j.corsci.2004.07.031.
  • [12] R. Natarajan, F. Al Shibli, Corrosion inhibition of aluminum under basic conditions using Medicago sativa L. extract — thermodynamic studies, Korean Journal of Chemical Engineering. 38 (2021) 1–10. https://doi.org/10.1007/s11814-021-0851-z.
  • [13] M.M. Antonijevic, M.B. Petrovic Mihajlovic, Copper Corrosion Inhibitors. Period 2008-2014. A Review, International Journal of Electrochemical Science. 10 (2015) 1027–1053. http://electrochemsci.org/papers/vol10/100201027.pdf.
  • [14] B. Tan, S. Zhang, Y. Qiang, W. Li, H. Li, L. Feng, L. Guo, C. Xu, S. Chen, G. Zhang, Experimental and theoretical studies on the inhibition properties of three diphenyl disulfide derivatives on copper corrosion in acid medium, Journal of Molecular Liquids. 298 (2020) 111975. https://doi.org/10.1016/j.molliq.2019.111975.
  • [15] M. Bethencourt, F.J. Botana, J.J. Calvino, M. Marcos, M.A. Rodríguez-Chacón, Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: A review, Corrosion Science. 40 (1998) 1803–1819. https://doi.org/10.1016/S0010-938X(98)00077-8.
  • [16] P.B. Raja, M.G. Sethuraman, Natural products as corrosion inhibitor for metals in corrosive media - A review, Materials Letters. 62 (2008) 113–116. https://doi.org/10.1016/j.matlet.2007.04.079.
  • [17] P. Mourya, S. Banerjee, M.M. Singh, Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor, Corrosion Science. 85 (2014) 352–363. https://doi.org/10.1016/j.corsci.2014.04.036.
  • [18] S. Bashir, V. Sharma, S. Kumar, Z. Ghelichkhah, I.B. Obot, A. Kumar, Inhibition performances of nicotinamide against aluminum corrosion in an acidic medium, Portugaliae Electrochimica Acta. 38 (2020) 107–123. https://doi.org/10.4152/pea.202002107.
  • [19] X. Liu, X. Pan, M. Lu, Y. Sun, Z. Wang, Y. Zheng, Nicotinic acid derivatives as corrosion inhibitors for mild steel in hydrochloric acid solutions: an experimental and computational chemistry study, Journal of Adhesion Science and Technology. 35 (2021) 63–80. https://doi.org/10.1080/01694243.2020.1787934.
  • [20] G. Asan, A. Asan, H. Çelikkan, The effect of 2D-MoS2 doped polypyrrole coatings on brass corrosion, Journal of Molecular Structure. 1203 (2020). https://doi.org/10.1016/j.molstruc.2019.127318.
  • [21] M. Okutan, Electrochemical determination of ascorbic acid with thermally reduced graphene oxide, Journal of the Faculty of Engineering and Architecture of Gazi University. 35 (2020) 1589–1601. https://doi.org/10.17341/gazimmfd.645284.
  • [22] T.T. Calam, Investigation of the electrochemical behavior of phenol using 1H-1, 2, 4-triazole-3-thiol modified gold electrode and its voltammetric determination, Journal of the Faculty of Engineering and Architecture of Gazi University. 35 (2020) 835–844. https://doi.org/10.17341/gazimmfd.543608.
  • [23] R. Ravichandran, N. Rajendran, Electrochemical behaviour of brass in artificial seawater: Effect of organic inhibitors, Applied Surface Science. 241 (2005) 449–458. https://doi.org/10.1016/j.apsusc.2004.07.046.
  • [24] G. Moretti, F. Guidi, G. Grion, Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid, Corrosion Science. 46 (2004) 387–403. https://doi.org/10.1016/S0010-938X(03)00150-1.
  • [25] T. Ohtsuka, Corrosion protection of steels by conducting polymer coating, International Journal of Corrosion. 2012 (2012). https://doi.org/10.1155/2012/915090.

Year 2021, Volume 8, Issue 3, 273 - 277, 29.09.2021
https://doi.org/10.17350/HJSE19030000239

Abstract

References

  • [1] A. Fateh, M. Aliofkhazraei, A.R. Rezvanian, Review of corrosive environments for copper and its corrosion inhibitors, Arabian Journal of Chemistry. 13 (2020) 481–544. https://doi.org/10.1016/j.arabjc.2017.05.021.
  • [2] R. Javaherdashti, How corrosion affects industry and life, Anti-Corrosion Methods and Materials. 47 (2000) 30–34. https://doi.org/10.1108/00035590010310003.
  • [3] X.F. Zhang, Y.Q. Chen, J.M. Hu, Robust superhydrophobic SiO2/polydimethylsiloxane films coated on mild steel for corrosion protection, Corrosion Science. 166 (2020). https://doi.org/10.1016/j.corsci.2020.108452.
  • [4] G. Tansuǧ, T. Tüken, E.S. Giray, G. Findikkiran, G. Siǧircik, O. Demirkol, M. Erbil, A new corrosion inhibitor for copper protection, Corrosion Science. 84 (2014) 21–29. https://doi.org/10.1016/j.corsci.2014.03.004.
  • [5] G. Moretti, F. Guidi, Tryptophan as copper corrosion inhibitor in 0.5 M aerated sulfuric acid, Corrosion Science. 44 (2002) 1995–2011. https://doi.org/10.1016/S0010-938X(02)00020-3.
  • [6] Q.B. Zhang, Y.X. Hua, Corrosion inhibition of mild steel by alkylimidazolium ionic liquids in hydrochloric acid, Electrochimica Acta. 54 (2009) 1881–1887. https://doi.org/10.1016/j.electacta.2008.10.025.
  • [7] R. Natarajan, F.S. Zahir Said Al Shibli, Synthesis of biomass derived product from Ziziphus spina-christi and application for surface protection of metal under acidic environment- Performance evaluation and thermodynamic studies, Chemosphere. 284 (2021) 131375. https://doi.org/10.1016/j.chemosphere.2021.131375.
  • [8] J.M. Gaidis, Chemistry of corrosion inhibitors, Cement and Concrete Composites. 26 (2004) 181–189. https://doi.org/10.1016/S0958-9465(03)00037-4.
  • [9] C.N. Hippolyte, B.Y. Serge, A. Sagne, J. Creus, T. Albert, Nicotinamide Inhibition Properties for Copper Corrosion in 3.5% NaCl Solution: Experimental and Theorical Investigations, Journal of Materials Science and Chemical Engineering. 06 (2018) 100–121. https://doi.org/10.4236/msce.2018.63008.
  • [10] H. Gerengi, H.I. Ugras, M.M. Solomon, S.A. Umoren, M. Kurtay, N. Atar, Synergistic corrosion inhibition effect of 1-ethyl-1-methylpyrrolidinium tetrafluoroborate and iodide ions for low carbon steel in HCl solution, Journal of Adhesion Science and Technology. 30 (2016) 2383–2403. https://doi.org/10.1080/01694243.2016.1183407.
  • [11] A. Asan, M. Kabasakaloǧlu, M. Işiklan, Z. Kiliç, Corrosion inhibition of brass in presence of terdentate ligands in chloride solution, Corrosion Science. 47 (2005). https://doi.org/10.1016/j.corsci.2004.07.031.
  • [12] R. Natarajan, F. Al Shibli, Corrosion inhibition of aluminum under basic conditions using Medicago sativa L. extract — thermodynamic studies, Korean Journal of Chemical Engineering. 38 (2021) 1–10. https://doi.org/10.1007/s11814-021-0851-z.
  • [13] M.M. Antonijevic, M.B. Petrovic Mihajlovic, Copper Corrosion Inhibitors. Period 2008-2014. A Review, International Journal of Electrochemical Science. 10 (2015) 1027–1053. http://electrochemsci.org/papers/vol10/100201027.pdf.
  • [14] B. Tan, S. Zhang, Y. Qiang, W. Li, H. Li, L. Feng, L. Guo, C. Xu, S. Chen, G. Zhang, Experimental and theoretical studies on the inhibition properties of three diphenyl disulfide derivatives on copper corrosion in acid medium, Journal of Molecular Liquids. 298 (2020) 111975. https://doi.org/10.1016/j.molliq.2019.111975.
  • [15] M. Bethencourt, F.J. Botana, J.J. Calvino, M. Marcos, M.A. Rodríguez-Chacón, Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: A review, Corrosion Science. 40 (1998) 1803–1819. https://doi.org/10.1016/S0010-938X(98)00077-8.
  • [16] P.B. Raja, M.G. Sethuraman, Natural products as corrosion inhibitor for metals in corrosive media - A review, Materials Letters. 62 (2008) 113–116. https://doi.org/10.1016/j.matlet.2007.04.079.
  • [17] P. Mourya, S. Banerjee, M.M. Singh, Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor, Corrosion Science. 85 (2014) 352–363. https://doi.org/10.1016/j.corsci.2014.04.036.
  • [18] S. Bashir, V. Sharma, S. Kumar, Z. Ghelichkhah, I.B. Obot, A. Kumar, Inhibition performances of nicotinamide against aluminum corrosion in an acidic medium, Portugaliae Electrochimica Acta. 38 (2020) 107–123. https://doi.org/10.4152/pea.202002107.
  • [19] X. Liu, X. Pan, M. Lu, Y. Sun, Z. Wang, Y. Zheng, Nicotinic acid derivatives as corrosion inhibitors for mild steel in hydrochloric acid solutions: an experimental and computational chemistry study, Journal of Adhesion Science and Technology. 35 (2021) 63–80. https://doi.org/10.1080/01694243.2020.1787934.
  • [20] G. Asan, A. Asan, H. Çelikkan, The effect of 2D-MoS2 doped polypyrrole coatings on brass corrosion, Journal of Molecular Structure. 1203 (2020). https://doi.org/10.1016/j.molstruc.2019.127318.
  • [21] M. Okutan, Electrochemical determination of ascorbic acid with thermally reduced graphene oxide, Journal of the Faculty of Engineering and Architecture of Gazi University. 35 (2020) 1589–1601. https://doi.org/10.17341/gazimmfd.645284.
  • [22] T.T. Calam, Investigation of the electrochemical behavior of phenol using 1H-1, 2, 4-triazole-3-thiol modified gold electrode and its voltammetric determination, Journal of the Faculty of Engineering and Architecture of Gazi University. 35 (2020) 835–844. https://doi.org/10.17341/gazimmfd.543608.
  • [23] R. Ravichandran, N. Rajendran, Electrochemical behaviour of brass in artificial seawater: Effect of organic inhibitors, Applied Surface Science. 241 (2005) 449–458. https://doi.org/10.1016/j.apsusc.2004.07.046.
  • [24] G. Moretti, F. Guidi, G. Grion, Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid, Corrosion Science. 46 (2004) 387–403. https://doi.org/10.1016/S0010-938X(03)00150-1.
  • [25] T. Ohtsuka, Corrosion protection of steels by conducting polymer coating, International Journal of Corrosion. 2012 (2012). https://doi.org/10.1155/2012/915090.

Details

Primary Language English
Subjects Basic Sciences
Journal Section Research Articles
Authors

Gülden ASAN (Primary Author)
0000-0002-6075-159X
Türkiye

Publication Date September 29, 2021
Application Date August 21, 2021
Acceptance Date September 27, 2021
Published in Issue Year 2021, Volume 8, Issue 3

Cite

Bibtex @research article { hjse985665, journal = {Hittite Journal of Science and Engineering}, issn = {}, eissn = {2148-4171}, address = {Hitit Üniversitesi Mühendislik Fakültesi Kuzey Kampüsü Çevre Yolu Bulvarı 19030 Çorum / TÜRKİYE}, publisher = {Hitit University}, year = {2021}, volume = {8}, pages = {273 - 277}, doi = {10.17350/HJSE19030000239}, title = {Protection of Copper From Corrosion With Nicotinamide Inhibitor}, key = {cite}, author = {Asan, Gülden} }
APA Asan, G. (2021). Protection of Copper From Corrosion With Nicotinamide Inhibitor . Hittite Journal of Science and Engineering , 8 (3) , 273-277 . DOI: 10.17350/HJSE19030000239
MLA Asan, G. "Protection of Copper From Corrosion With Nicotinamide Inhibitor" . Hittite Journal of Science and Engineering 8 (2021 ): 273-277 <https://dergipark.org.tr/en/pub/hjse/issue/65166/985665>
Chicago Asan, G. "Protection of Copper From Corrosion With Nicotinamide Inhibitor". Hittite Journal of Science and Engineering 8 (2021 ): 273-277
RIS TY - JOUR T1 - Protection of Copper From Corrosion With Nicotinamide Inhibitor AU - Gülden Asan Y1 - 2021 PY - 2021 N1 - doi: 10.17350/HJSE19030000239 DO - 10.17350/HJSE19030000239 T2 - Hittite Journal of Science and Engineering JF - Journal JO - JOR SP - 273 EP - 277 VL - 8 IS - 3 SN - -2148-4171 M3 - doi: 10.17350/HJSE19030000239 UR - https://doi.org/10.17350/HJSE19030000239 Y2 - 2021 ER -
EndNote %0 Hittite Journal of Science and Engineering Protection of Copper From Corrosion With Nicotinamide Inhibitor %A Gülden Asan %T Protection of Copper From Corrosion With Nicotinamide Inhibitor %D 2021 %J Hittite Journal of Science and Engineering %P -2148-4171 %V 8 %N 3 %R doi: 10.17350/HJSE19030000239 %U 10.17350/HJSE19030000239
ISNAD Asan, Gülden . "Protection of Copper From Corrosion With Nicotinamide Inhibitor". Hittite Journal of Science and Engineering 8 / 3 (September 2021): 273-277 . https://doi.org/10.17350/HJSE19030000239
AMA Asan G. Protection of Copper From Corrosion With Nicotinamide Inhibitor. Hittite J Sci Eng. 2021; 8(3): 273-277.
Vancouver Asan G. Protection of Copper From Corrosion With Nicotinamide Inhibitor. Hittite Journal of Science and Engineering. 2021; 8(3): 273-277.
IEEE G. Asan , "Protection of Copper From Corrosion With Nicotinamide Inhibitor", Hittite Journal of Science and Engineering, vol. 8, no. 3, pp. 273-277, Sep. 2021, doi:10.17350/HJSE19030000239