Determination of the distribution of different filling materials in SBR matrix compounds by image processing

Year 2020, Volume: 4 Issue: 1, 8 - 13, 15.04.2020

Saban Bulbul Hasan Serdar

https://doi.org/10.35860/iarej.695197

Abstract

In this study, the distribution of walnut shell ash and cone ash, which were used in different proportions as the filling materials of SBR rubber compounds, in the matrix were investigated by the developed image processing program. Styrene-Butadiene Rubber (SBR 1502) was employed as the main matrix material. Adhering to the same compound in the experiments, in addition to the carbon black in the compound, 5 different and 10% by mass of Walnut Shell Ash (WSA) was added to the dough, and the Cone Ash (CA) by 5% and 10% by mass, creating a total of 5 different compounds. SEM images of the rupture surfaces were taken and transferred to the developed image processing program, in which the areas covered by walnut shell ash and cone ash in the images were determined. The number of designated surface areas and the area it covers on the image were removed.

Keywords

Cone ash, Filling, SBR, İmage Processing, Walnut Shell

References

• 1. Bülbül, Ş., M. Yaşar, and N. Akçakale, Effect of changing of filling materials in NR-SBR type elastomer-based rubber materials on mechanical properties. Polymer(Korea), 2014. 38(5): p. 664-670.
• 2. Hedayatollah, S.G. and J.A. Azam, Nanocomposites based on natural rubber, organic nano clay and nano-calcium carbonate: a study on the structure, cure behavior, static and dynamic-mechanical properties. Applied Clay Science, 2016. 119: p. 348–357.
• 3. De, D., P.K. Panda, M. Roy and S. Bhunia, Reinforcing Effect of Reclaim Rubber on Natural Rubber/Polybutadiene Rubber Blends. Materials and Design, 2013. 46: p. 142-150.
• 4. Malas, A., P. Pal and C.K. Das, Effect of expanded graphite and modified graphite flakes and the physical and thermo-mechanical properties of Styrene Butadiene Rubber/Polybutadiene Rubber (SBR/BR) blends. Materials and Design, 2014. 55, p. 664-673.
• 5. Mohan, T.P., J. Kuriakose and K. Kanny, Water up Take and mechanical properties of Natural Rubber–Styrene Butadine Rubber (NR-SBR) – nanoclay composites. J. of Industrial and Engineering Chemistry, 2012. 18: p. 979-985.
• 6. Akçakale, N. and Ş. Bülbül, The effect of mica powder and wollastonit fillings on the mechanical properties of NR/SBR type elastomer compounds. J. Rubb. Res., 2017. p. 20(3): p.157-167.
• 7. Furtado, C.R.G., J.L. Leblanc and R.C.R. Nunes, Fatigue resistance of mica-carbon black Styrene Butadiene Rubber (SBR) compounds. Eur. Polymer J., 1999. 35: p. 1319–1325.
• 8. Furtado, C.R.G., J.L. Leblanc and R.C.R. Nunes, Mica as additional filler in SBR-Silica compounds. Eur. Polymer J., 2000. 36: p.1717–1723.
• 9. Saramolee, P., K. Sahakaro, N. Lopattananon, .K. and J.W.M. Noordermeer, Compatibilisation of silica-filled natural rubber compounds by functionalised low molecular weight polymer. J. of Rubber Research, 2016. 19(1): p. 28–42.
• 10. Alfaro, E.F., D.B. Dias and L.G.A. Silva, The study of ionizing radiation effects on polypropylene and rice husk ash composite. Radiation Physics and Chemistry, 2013. 84: p.163–165.
• 11. Kim, S.M. and K.J. Kim, Effects of accelerators on the vulcanization properties of silica vs. carbon black filled natural rubber compounds. Polymer (Korea), 2013. 37(3): p. 269-275.
• 12. Ge, X., M.C. Le and U.R. Cho, Fabrication of EPDM rubber/organo-bentonite composites, influence of hydrochloric acid on the characteristics of modified bentonite and final products. Polymer (Korea), 2014. 38(1): p. 62-68.
• 13. Prasertsri, S., F. Lagarde, N., Rattanasom, C. Sirisinha and P. Daniel, Raman spectroscopy and Thermal Analysis of Gum and Silica-Filled NR/SBR Blends Prepared from Latex System. Polymer Testing, 2013. 32: 852–861.
• 14. Yan, G., Z. Junchi, Y. Xin, H. Dongli, X. Meimei and Z. Liqun, Preparation and performance of silica/sbr master batches with high silica loading by latex compounding method. Composites Part B, 2016. 85: p. 130–139.
• 15. Bülbül, Ş. The effect of various inorganic and organic fillers on the mechanical properties of NR-SBR type elastomer materials [dissertation] Karabük (TR): Karabük University; 2014.
• 16. Bülbül, Ş. Doğal atık malzemelerle yeni NBR bazli bileşiklerin hazirlanmasi ve karakterizasyonu. BSEU Journal of Science, 2019. 6 (Prof. Dr. Fuat SEZGİN Bilim Yılı Özel Sayısı) p. 42-49.
• 17. Sabzekar, M., M.P. Chenar, G. Zohuri, and S.M. Mortazavi, Investigation of mechanical, thermal, and morphological properties of EPDM compounds containing reclaimed rubber. Rubber Chemistry and Technology, 2017. 90: p. 765–776.
• 18. Sastry, S.S., B. Rao, K.B. Mahalakshmi, K. MALLİKA, C.N. Rao and, H.S. Tiong, Image analysis studies for phase transitions of ferroelectric liquid crystals. ISRN Condensed Matter Physics, 2012, p. 1-8.
• 19. Sudheer, K. P. and R.K. Panda, Digital image processing for determining drop sizes from irrigation spray nozzles. Agricultural Water Management, 2000. p. 45(2): 159-167.
• 20. Sastry, S.S., M. Sailaja, S. Lakshminarayana and S.T. Ha, Computation of Liquid Crystal Display Device Parameters Through Image Analysis, Int. Journal of Engineering Research and Application, 2017. 7(7): p. 24-31.
• 21. Fan, H., F. Xie, Y. Li, Z. Jiang, and J. Liu, Automatic segmentation of dermoscopy images using saliency combined with Otsu threshold. Computers in biology and Medicine, 2017. 85: p.75-85.
• 22. Flegler, S.L., J.W. Heckman and K.L. Klomparens, Scanning and transmission electron microscopy. England: Oxford University Press, ISBN 0-19-510751-9, 1993.
• 23. Sezgin M. and B. Sankur, Survey over image thresholding techniques and quantitative performance evaluation. Journal of Electronic Imaging, 2004. 13(1): 146–165.
• 24. N. Akcakale, Effects of carburized rice husk powders on physical properties of elastomer based materials, KGK-Kautschuk Gummi Kunststoffe, (2017) 70 (10-17): p. 49–54.