Reduction of operation temperature in SOFCs utilizing perovskites: Review

Nagihan Delibaş; Soudabeh Bahrami Gharamaleki; Masrour Mansouri; Aligholi Niaie

doi:10.35860/iarej.972864

Review

Reduction of operation temperature in SOFCs utilizing perovskites: Review

Year 2022, Volume: 6 Issue: 1, 56 - 67, 15.04.2022

Nagihan Delibaş Soudabeh Bahrami Gharamaleki Masrour Mansouri Aligholi Niaie

https://doi.org/10.35860/iarej.972864

Cited By: 5

Abstract

Fuel cells are electrochemical devices utilized for converting chemical energy to electrical energy. Solid Oxide Fuel Cells (SOFCs) have several advantages over other kinds. For instance, high energy efficiency expanded fuel flexibility, low environmental pollutant emission are the properties of SOFCs that make them superior to other fuel cell types. Due to these special characteristics, SOFCs are gained a great deal of attraction. These fuel cells consist of different main operating parts, a cathode, an anode, and electrolyte which each of them demands special materials to operate with the most efficiency. SOFCs mostly operate in high temperatures (800-1000 ᵒC). Reducing the operating temperature to lower than 600 ᵒC or intermediate temperatures 600-800 ᵒC is one of the methods that can make them more practical devices. Perovskite oxides can be used effectively as all main parts of SOFCs because of their excellent properties like electrical and ionic conductivities, oxygen ion vacancies, great catalytic properties, thermal durability, and chemical stability to decrease the operating temperature. In this review, numerous perovskite-based materials utilized in the anode and the cathode electrodes of SOFCs are investigated in the most recent, advanced, and novel works. The perovskite materials, their properties, and their influence on the fuel cell’s performance, and in some cases the sulfur tolerance of the materials when H2S co-exists in the fuel of the fuel cell are reviewed in this paper Adding different dopants in A-site and B-site of the perovskite oxides is the most effective way to modify the characteristics of the materials. This review can provide great data on the possible perovskite oxides with the capability of enhancing the efficiency of SOFCs by reducing the operating temperature, and their most decisive and significant characteristics, like composition, structure, electrical conductivity, electrochemical and mechanical properties for research groups working on solid oxide fuel cells.

Keywords

Fuel cell, SOFC, Perovskite

Supporting Institution

the University of Sakarya-Turkey & the University of Tabriz -Iran

Thanks

We would like to thank the University of Tabriz and the University of Sakarya for their kind cooperation in project planning and support.

References

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Year 2022, Volume: 6 Issue: 1, 56 - 67, 15.04.2022

Nagihan Delibaş Soudabeh Bahrami Gharamaleki Masrour Mansouri Aligholi Niaie

https://doi.org/10.35860/iarej.972864

Cited By: 5

Abstract

References

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2. Turkboyları, E.Y. and A.N. Yuksel, Use of solar panels in greenhouse soil disinfection, International Advanced Researches and Engineering Journal, 2018. 2(2): p. 195-199.
3. Sengodan, S., et al., Layered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cells, Nature materials, 2015. 14(2): p. 205-209.
4. Abdalla, A.M., et al., Achievements and trends of solid oxide fuel cells in clean energy field: a perspective review, Frontiers in Energy, 2018: p. 1-24.
5. Mendonça, C., A. Ferreira, and D.M. Santos, Towards the Commercialization of Solid Oxide Fuel Cells, Recent Advances in Materials and Integration Strategies. Fuels, 2021. 2(4): p. 393-419.
6. Jun, A., et al., Perovskite as a cathode material: a review of its role in solid‐oxide fuel cell technology, ChemElectroChem, 2016. 3(4): p. 511-530.
7. Afroze, S., et al., Latest development of double perovskite electrode materials for solid oxide fuel cells: a review, Frontiers in Energy, 2019. 13(4): p. 770-797.
8. Wachsman, E.D. and K.T. Lee, Lowering the temperature of solid oxide fuel cells, Science, 2011. 334(6058): p. 935-939.
9. Thakur, S., O. Pandey, and K. Singh, A comparative structural, thermal and electrical study of Ca2+, Sr2+ substituted BiMnO3, Solid State Ionics, 2014. 268: p. 23-30.
10. Kaur, P. and K. Singh, Review of perovskite-structure related cathode materials for solid oxide fuel cells, Ceramics International, 2020. 46(5): p. 5521-5535.
11. Ding, P., et al., Review on Ruddlesden–Popper perovskites as cathode for solid oxide fuel cells, Journal of Physics: Materials, 2021. 4(2): p. 022002.
12. Tarragó, D.P., et al., Perovskites used in fuel cells. Pan, Likun; Zhu, Guang (ed.). Perovskite materials: synthesis, characterisation, properties, and applications [recurso eletrônico], [Rijeka, Croatia]: InTech, 2016. ch. 21, p. 619-637, 2016.
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15. Zhou, X., et al., Progress in La-doped SrTiO 3 (LST)-based anode materials for solid oxide fuel cells, Rsc Advances, 2014. 4(1): p. 118-131.
16. Johnsson, M. and P. Lemmens, Crystallography and chemistry of perovskites, Handbook of magnetism and advanced magnetic materials, 2007.
17. Burnwal, S.K., S. Bharadwaj, and P. Kistaiah, Review on MIEC cathode materials for solid oxide fuel cells, Journal of Molecular and Engineering Materials, 2016. 4(02): p. 1630001.
18. Sengodan, S., et al., Self-decorated MnO nanoparticles on double perovskite solid oxide fuel cell anode by in situ exsolution, ACS Sustainable Chemistry & Engineering, 2017. 5(10): p. 9207-9213.
19. Klyndyuk, A.I., et al., Layered Oxygen-Deficient Double Perovskites as Promising Cathode Materials for Solid Oxide Fuel Cells, Materials, 2022. 15(1): p. 141.
20. Gazda, M., et al. Perovskites in solid oxide fuel cells. in Solid State Phenomena, 2012. Trans Tech Publ.
21. Hussain, S. and L. Yangping, Review of solid oxide fuel cell materials: cathode, anode, and electrolyte, Energy Transitions, 2020: p. 1-14.
22. Lan, R., et al., A perovskite oxide with high conductivities in both air and reducing atmosphere for use as electrode for solid oxide fuel cells, Scientific reports, 2016. 6(1): p. 1-8.
23. Zhou, Q., et al., Electrochemical performances of LaBaCuFeO+x and LaBaCuCoO5+x as potential cathode materials for intermediate-temperature solid oxide fuel cells, Electrochemistry Communications, 2009. 11(1): p. 80-83.
24. Meng, X., et al., Characterization of Pr1-xSrxCo0.8Fe0.2O3- δ (0.2≤ x≤ 0.6) cathode materials for intermediate-temperature solid oxide fuel cells, Journal of Power Sources, 2008. 183(2): p. 581-585.
25. Ding, H. and X. Xue, Cobalt-free layered perovskite GdBaFe2O5+x as a novel cathode for intermediate temperature solid oxide fuel cells, Journal of Power Sources, 2010. 195(15): p. 4718-4721.
26. Bebelis, S., et al., Electrochemical characterization of perovskite-based SOFC cathodes, Journal of applied electrochemistry, 2007. 37(1): p. 15-20.
27. Zhou, Q., et al., LaSrMnCoO5+ δ as cathode for intermediate-temperature solid oxide fuel cells, Electrochemistry communications, 2012. 19: p. 36-38.
28. Irshad, M., et al., Electrochemical evaluation of mixed ionic electronic perovskite cathode LaNi1-xCoxO3-- δ for IT-SOFC synthesized by high temperature decomposition, International Journal of Hydrogen Energy, 2021. 46(17): p. 10448-10456.
29. Ling, Y., et al., Investigation of cobalt-free cathode material Sm0.5Sr0.5Fe0.8Cu0.2O3− δ for intermediate temperature solid oxide fuel cell, International journal of hydrogen energy, 2010. 35(13): p. 6905-6910.
30. Shen, F. and K. Lu, Perovskite-type La0.6Sr0.4Co0.2Fe0.8O3, Ba0.5Sr0.5Co0.2Fe0.8O3, and Sm0.5Sr0.5Co0.2Fe0.8O3 cathode materials and their chromium poisoning for solid oxide fuel cells, Electrochimica Acta, 2016. 211: p. 445-452.
31. Mostafavi, E., A. Babaei, and A. Ataie, La0.6Sr0.4Co0.2Fe0.8O3 perovskite cathode for intermediate temperature solid oxide fuel cells: a comparative study, Iranian Journal of Hydrogen & Fuel Cell, 2015. 1(4): p. 239-246.
32. Choi, S., et al., Chemical compatibility, redox behavior, and electrochemical performance of Nd1-xSrxCoO3− δ cathodes based on Ce1.9Gd0.1O1.95 for intermediate-temperature solid oxide fuel cells, Electrochimica acta, 2012. 81: p. 217-223.
33. Wu, Y.-C., et al, Properties and microstructural analysis of La1-xSrxCoO3−δ (x= 0–0.6) cathode materials, Ceramics International, 2017. 43(2): p. 2460-2470.
34. Hammouche, A., E. Siebert, and A. Hammou, Crystallographic, thermal and electrochemical properties of the system La1-xSrxMnO3 for high temperature solid electrolyte fuel cells, Materials Research Bulletin, 1989. 24(3): p. 367-380.
35. Ullmann, H., et al., Correlation between thermal expansion and oxide ion transport in mixed conducting perovskite-type oxides for SOFC cathodes, Solid state ionics, 2000. 138(1-2): p. 79-90.
36. Kong, X., et al., NdBaCu2O5+ δ and NdBa0.5Sr0.5Cu2O5+ δ layered perovskite oxides as cathode materials for IT-SOFCs, International Journal of Hydrogen Energy, 2015. 40(46): p. 16477-16483.
37. Baumann, F., et al., Quantitative comparison of mixed conducting SOFC cathode materials by means of thin film model electrodes, Journal of The Electrochemical Society, 2007. 154(9): p. B931.
38. Gędziorowski, B., et al, La1-xBaxCo0.2Fe0.8O3- δ perovskites for application in intermediate temperature SOFCs, Solid State Ionics, 2012. 225: p. 437-442.
39. Li, N., et al., Characterization of GdBaCo2O5+ δ cathode for IT-SOFCs, Journal of Alloys and Compounds, 2008. 454(1-2): p. 274-279.
40. Park, S., et al., Strontium doping effect on high-performance PrBa1-xSrxCo2O5+ δ as a cathode material for IT-SOFCs, ECS Electrochemistry Letters, 2012. 1(5): p. F29.
41. Ishihara, T., et al., Doped PrMnO3 perovskite oxide as a new cathode of solid oxide fuel cells for low temperature operation, Journal of the Electrochemical Society, 1995. 142(5): p. 1519.
42. Zhou, X. and F. Zhou, Application of La0.3Sr0.7Fe0.7Ti0.3O3-δ GDC electrolyte in LT-SOFC, International Journal of Hydrogen Energy, 2021. 46(15): p. 9988-9995.
43. Aliotta, C., et al., Direct methane oxidation on La1-xSrxCr1-yFeyO3- δ perovskite-type oxides as potential anode for intermediate temperature solid oxide fuel cells, Applied Catalysis B: Environmental, 2016. 180: p. 424-433.
44. Cowin, P.I., et al., Recent progress in the development of anode materials for solid oxide fuel cells, Advanced Energy Materials, 2011. 1(3): p. 314-332.
45. Cheng, Y., et al., Investigation of Ba fully occupied A-site BaCo0.7Fe0.3-xNbxO3- δ perovskite stabilized by low concentration of Nb for oxygen permeation membrane, Journal of Membrane Science, 2008. 322(2): p. 484-490.
46. Chen, X., et al., High-performance cathode-supported SOFC with perovskite anode operating in weakly humidified hydrogen and methane, Fuel Cells Bulletin, 2007. 2007(6): p. 12-16.
47. Danilovic, N., et al., Correlation of fuel cell anode electrocatalytic and ex situ catalytic activity of perovskites La0.75Sr0.255Cr0.5X0.5O3- δ (X= Ti, Mn, Fe, Co), Chemistry of Materials, 2010. 22(3): p. 957-965.
48. Fowler, D.E., et al., Stable, low polarization resistance solid oxide fuel cell anodes: La1-x Sr x Cr1-xFe x O3- δ (x= 0.2–0.67), Chemistry of Materials, 2014. 26(10): p. 3113-3120.
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There are 76 citations in total.

Details

Primary Language	English
Subjects	Energy Systems Engineering (Other)
Journal Section	Review Articles
Authors	Nagihan Delibaş 0000-0001-5752-062X Soudabeh Bahrami Gharamaleki 0000-0002-2060-7032 Masrour Mansouri 0000-0002-3277-9894 Aligholi Niaie 0000-0001-5580-4266
Publication Date	April 15, 2022
Submission Date	July 19, 2021
Acceptance Date	March 17, 2022
Published in Issue	Year 2022 Volume: 6 Issue: 1

Cite

APA	Delibaş, N., Bahrami Gharamaleki, S., Mansouri, M., Niaie, A. (2022). Reduction of operation temperature in SOFCs utilizing perovskites: Review. International Advanced Researches and Engineering Journal, 6(1), 56-67. https://doi.org/10.35860/iarej.972864
AMA	Delibaş N, Bahrami Gharamaleki S, Mansouri M, Niaie A. Reduction of operation temperature in SOFCs utilizing perovskites: Review. Int. Adv. Res. Eng. J. April 2022;6(1):56-67. doi:10.35860/iarej.972864
Chicago	Delibaş, Nagihan, Soudabeh Bahrami Gharamaleki, Masrour Mansouri, and Aligholi Niaie. “Reduction of Operation Temperature in SOFCs Utilizing Perovskites: Review”. International Advanced Researches and Engineering Journal 6, no. 1 (April 2022): 56-67. https://doi.org/10.35860/iarej.972864.
EndNote	Delibaş N, Bahrami Gharamaleki S, Mansouri M, Niaie A (April 1, 2022) Reduction of operation temperature in SOFCs utilizing perovskites: Review. International Advanced Researches and Engineering Journal 6 1 56–67.
IEEE	N. Delibaş, S. Bahrami Gharamaleki, M. Mansouri, and A. Niaie, “Reduction of operation temperature in SOFCs utilizing perovskites: Review”, Int. Adv. Res. Eng. J., vol. 6, no. 1, pp. 56–67, 2022, doi: 10.35860/iarej.972864.
ISNAD	Delibaş, Nagihan et al. “Reduction of Operation Temperature in SOFCs Utilizing Perovskites: Review”. International Advanced Researches and Engineering Journal 6/1 (April 2022), 56-67. https://doi.org/10.35860/iarej.972864.
JAMA	Delibaş N, Bahrami Gharamaleki S, Mansouri M, Niaie A. Reduction of operation temperature in SOFCs utilizing perovskites: Review. Int. Adv. Res. Eng. J. 2022;6:56–67.
MLA	Delibaş, Nagihan et al. “Reduction of Operation Temperature in SOFCs Utilizing Perovskites: Review”. International Advanced Researches and Engineering Journal, vol. 6, no. 1, 2022, pp. 56-67, doi:10.35860/iarej.972864.
Vancouver	Delibaş N, Bahrami Gharamaleki S, Mansouri M, Niaie A. Reduction of operation temperature in SOFCs utilizing perovskites: Review. Int. Adv. Res. Eng. J. 2022;6(1):56-67.