Photochemical Reaction of Metal Carbonyls [M(CO)6 (M=Cr,Mo,W)] with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone

Year 2019, , 27 - 31, 30.06.2019

Sema Sert

https://doi.org/10.38061/idunas.463196

Abstract

The new complexes, [M(CO)₅(msh4)]
(Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of
metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes
has been investigated by using elemental analyses; FT-IR; EI-MS and ¹H
NMR spectrometric methods. According to all spectroscopic data, msh4 is
monodaentate and coordinate via thiophene ring sulfur.

Keywords

Metal carbonyls; Methanesulfonylhydrazone; Photochemical Reactions.

Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone

Abstract

The new complexes, [M(CO)5(msh4)] (Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur.

Keywords

Metal carbonys, Methanesulfonylhydrazone, Photochemical Reactions

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