Hydrothermal Synthesis of Mordenite Type Zeolite

Year 2023, , 86 - 90, 30.06.2023

Sabiha Anas Boussaa , Djamel Nıbou Karima Benfadel Lamia Talbı Assia Boukezzata Yahia Ouadah Djaouida Allam Samira Kaci

https://doi.org/10.22399/ijcesen.1284632

Abstract

Zeolite is a crystalline alumino-silicate microporous material, which has been widely used as ion-exchangers, adsorbent and catalyst.
Recently, several researches highlights the progress of zeolite-based catalysts in the CO2 conversion to valuable products.
In the present work, hydrothermal synthesis of mordenite zeolite crystals, with composition of the chemical products Al2O3, 12.5 SiO2,2.4 NaOH, 110 H2O at 160°C for 96 hours (4 days) at Ph 11 is described.
Results of characterization of the mordenite zeolite by XRD, FTIR, EDAX, SEM, TGA, are presented and discussed.
In the present work, hydrothermal synthesis and characterization of mordenite zeolite crystals is described.

Keywords

zeolite, synthesis, Hydrothermal, mordenite, characterization

Supporting Institution

Dgrsdt, crtse

Thanks

CRTSE/DGRSDT

References

• [1]Eduardo Pérez-Botella, Susana Valencia, and Fernando Rey (2022). Zeolites in Adsorption Processes: State of the Art Future Prospects. Chemical Reviews 122(24);17647-17695 doi.:10.1021/acs.chemrev.2c00140
• [2]Milad Rasouli, Nakisa Yaghobi, Fatemeh Allahgholipour, Hossein Atashi. (2014). Para-xylene adsorption separation process using nano-zeolite Ba-X, Chemical Engineering Research and Design 92(6):1192–1199 doi.:10.1016/j.cherd.2013.10.008
• [3] Liu, M. N., Xie, Z. X., Luo, Q. X., Zhang, J., Chen, H., Xu, L. & Hao, Q. Q. (2022). Synthesis of Nanosized Mordenite with Enhanced Catalytic Performance in the Alkylation of Benzene with Benzyl Alcohol. Industrial & Engineering Chemistry Research,61(2);1078-1088. doi:10.1021/acs.iecr.1c03419
• [4] Li, S., van de Poll, R. C., Kosinov, N., & Hensen, E. J. (2022). Facile synthesis of nanosized mordenite and beta zeolites with improved catalytic performance: non-surfactant diquaternary ammonium compounds as structure-directing agents. Inorganic Chemistry Frontiers. 2022,9, 3200-3216 doi:10.1039/D2QI00696K
• [5] Du, T., Cui, M., Chao, Y., Xiao, Y., Ren, Z., An, Y., & Meng, C. (2022). Preparation and photocatalytic properties of highly dispersed samarium vanadate nanoparticles supported on H-mordenite composites by template-free method. Journal of Photochemistry and Photobiology A: Chemistry, 433; 114207. doi:10.1016/j.jphotochem.2022.114207
• [6] Collins, F., Rozhkovskaya, A., Outram, J. G., & Millar, G. J. (2020). A critical review of waste resources, synthesis, and applications for Zeolite LTA. Microporous and mesoporous Materials, 291; 109667. https:doi.org/10.1016/j.micromeso.2019.109667
• [7] Ghasemi, Z., Sourinejad, I., Kazemian, H., & Rohani, S. (2018). Application of zeolites in aquaculture industry: a review. Reviews in Aquaculture, 10(1); 75-95. doi.org/10.1111/raq.12148
• [8] Madhu, J., Ramakrishnan, V. M., Santhanam, A., Natarajan, M., Palanisamy, B., Velauthapillai, D and Pugazhendhi, A. (2022). Comparison of three different structures of zeolites prepared by template- free hydrothermal method and its CO2 adsorption properties. Environmental Research, 214; 113949. doi: 10.1016/j.envres.2022.113949
• [9] Weckhuysen, B. M., & Yu, J. (2015). Recent advances in zeolite chemistry and catalysis. Chemical Society Reviews, 44(20); 7022-7024. doi:10.1039/C5CS90100F
• [10] Yoldi, M., Fuentes-Ordoñez, E. G., Korili, S. A., & Gil, A. (2019). Zeolite synthesis from industrial wastes. Microporous and Mesoporous materials, 287; 183-191. doi:10.1016/j.micromeso.2019.06.009
• [11]Lin, C. C., Dambrowitz, K. A., & Kuznicki, S. M. (2012). Evolving applications of zeolite molecular sieves. The Canadian Journal of Chemical Engineering, 90(2);207-216. doi: 10.1002/cjce.20667
• [12]Moshoeshoe, M., Nadiye-Tabbiruka, M. S., & Obuseng, V. (2017). A review of the chemistry, structure, properties and applications of zeolites. Am. J.Mater.Sci,7(5);196-221. doi:10.5923/j.materials.20170705.12
• [13]Houhoune, F., Khemaissia, S., Nibou, D., Chegrouche, S., & Menacer, S. (2018). Kinetic study and sorption mechanism of uranium (VI) onto NaY zeolite. In AIP Conference Proceedings (Vol. 1994, No. 1, p. 070008). AIP Publishing LLC. doi.org/10.1063/1.5048180
• [14]Baouali, N. Y., Nibou, D., & Amokrane, S. (2022). NaY Zeolite and TiO2 Impregnated NaY Zeolite for the Adsorption and Photocatalytic Degradation of Methylene Blue under Sunlight. Iran. J. Chem.Chem. Eng. Volume 41, Issue 6 - Serial Number 116 June 2022,1907-1920 doi ; 10.30492/IJCCE.2021.128624.4168