Optimization, isotherm and kinetics studies of azo dye adsorption on eggshell membrane

Year 2019, Volume: 3 Issue: 1, 52 - 60, 28.06.2019

Ayşe Dinçer , Mervecan Sevildik Tülin Aydemir

https://doi.org/10.32571/ijct.538736

Cited By: 10

Abstract

      Eggshell
membrane (ESM) was used as an adsorbent for adsorption of reactive red 195
(RR195) and reactive black 5 (RB5) dyes from aqueous solutions. The
experimental conditions were optimized via batch system experiments for maximum
azo dyes removal. Adsorption of the dyes was pH dependent highly, and the
maximum adsorption of RR195 and RB5 occurred at pH 3.0 and 2.0, respectively. For
both dyes, the adsorption process was seen to be obeyed pseudo-second order
kinetic  and the Langmuir isotherm
models. Maximum adsorption capacities (Q_max) of ESM for RR195 dye
and RB5 were found as 76.9 and 333.33 mg g^-1, respectively. The thermodynamic parameters were calculated and the adsorption
of the dyes was found to be as exothermic and spontaneous.  Moreover, the structural characterization of the ESM was performed by FTIR and
SEM analysis.

Keywords

Eggshell membrane, reactive red 195, reactive black 5, adsorption

References

• 1. Hassaan, M.A.; El Nemr, A. Am. J. Environ. Sci. Eng. 2017, 1 (3), 64-67.
• 2. Benkhaya, S.; El Harfi, S.; El Harfi, A. Appl. J. Envir. Eng. Sci. 2017, 3 (3), 311-320.
• 3. Singh, P.K.; Singh. R.L. Int. J. Appl. Sci. Biotechnol. 2017, 5 (2), 108-126.
• 4. El-Naggar, M.E.; Radwan, E.K; El-Wakeel, S.T.; Kafafy, H.; Gad-Allah, T.A.; El-Kalliny, A.S.; Shaheen, T.I. Int. J. Biol. Macromol. 2018, 113, 248-258.
• 5. Mahmoud, M.E.; Nabil, G.M.; El-Mallah, N.M.; Bassiouny, H.I.; Kumar, S.; Abdel-Fattah, T.M. J. Ind. Eng. Chem. 2016, 37, 156-167.
• 6. Kamranifar, M.; Khodadadi, M.; Samiei, V.; Dehdashti, B.; Sepehr, M.N.; Rafati, L.; Nasseh, N.; J. Mol. Liq. 2018, 255, 572-577.
• 7. Karadağ, D.; Turan, M.; Akgul, E.; Tok, S.; Faki, A. J. Chem. Eng. Data 2007, 52, 1615-1620.
• 8. Nawahwi, M.Z.; Ibrahim, Z.; Yahya, A. J. Bioremed. Biodeg. 2013, 4, 1-7.
• 9. Jager, D.; Kupka, D.; Vaclavikova, M.; Ivanicova, L.; Gallios. G. Chemosphere 2018, 190, 405-416.
• 10. Al-Degs, Y.S.; El-Barghouthi, M.I.; El-Sheikh, A.H.; Walker, G.M. Dyes Pigments 2007, 77 (1), 1-8.
• 11. Ghaedi, M.; Sadeghian, B.; Pebdani, A.A; Sahraei, R.; Daneshfar, A.; Duran, C. Chem. Eng. J. 2012, 187, 133-141.
• 12. Aljeboree, A.M.; Alshirifi, A.N.; Alkaim, A.F. Arab. J. Chem. 2017, 10, S3381-S3393.
• 13. Arami, M.; Limaee, N.Y.; Mahmoodi, N.M. Chemosphere. 2006, 65, 1999-2008.
• 14. Belessi, V.; Romanos. G.; Boukos, N.; Lambropouloud, D.; Trapalis, C. J. Hazard. Mater. 2009, 170, 836-844.
• 15. Yi, F.; Guo, Z.X.; Zhang, L.X.; Yu, J.; Li, Q. Biomaterials 2004, 25, 4591-4599.
• 16. Tsai, W.T.; Yang, J.M.; Lai, C.W.; Cheng, Y.H.; Lin, C.C.; Yeh, C.W. Bioresource Technol. 2006, 97, 488-493.
• 17. Abdel-Khalek, M.A.; Abdel Rahman, M.K.; Francis, A.A. J. Environ. Chem. Eng. 2017, 5, 319-327.
• 18. Xin, Y.; Li, C.; Liu, J.; Liu, J.; Liu, Y.; He, W.; Gao, Y. R. Soc. Open sci. 2018, 5, 180532.
• 19. Karan, S.K.; Maiti, S.; Paria, S.; Maitra, A.; Si, S.K.; Kim, J.K; Khatua, B.B. Mater. Today 2018, 9, 114-125.
• 20. Hussien, M.A.; El-Bindary, A.A.; El-Sonbati, A.Z.; Shoair, A.F.; El-Boz, R.A. J. Mater. Environ. Sci. 2016, 7 (11), 4214-4225.
• 21. Munagapati, V.S.; Yarramuthi, V.; Kim, Y.; Lee, K.M.; Kim. D.S. Ecotoxicol. Environ. Saf. 2018, 148, 601-607.
• 22. Aksu. Z.; Dönmez, G. Chemosphere 2003, 50, 1075-1083.
• 23. Paşka, O.; Ianoş, R.; Pãcurariu, C.; Brãdeanu, A. Water Sci. Technol. 2014, 69, 1234-1240.
• 24. Mohebali, S.; Bastani, D.; Shayesteh, H. J. Mol. Struct. 2019, 1176, 181-193.
• 25. Dotto, G.L.; Lima, E.C.; Pinto, L.A. Bioresour. Technol. 2012, 103, 123-130.
• 26. Zhou, L.; Jin, J.; Liu, Z.; Liang, X.; Shang, C. J. Hazard. Mater. 2011, 185, 1045-1052.
• 27. Zhou, Z.; Lin, S.; Yue, T.; Lee, T. J. Food Eng. 2014, 126, 133-141.
• 28. Li, H.; Huang, G.; An. C.; Hu, J.; Yang, S. Ind. Eng. Chem. Res. 2013, 52, 15923-15931.
• 29. Chiou, M.S.; Li, H.Y. J. Hazard. Mater. 2002, 93, 233-248.
• 30. Sun, D.; Zhang, X.; Wu, Y.; Liu, X. J. Hazard. Mater. 2010, 181, 335-342.
• 31. Özcan, A.; Öncü, E.M.; Özcan, A.S. J. Hazard. Mater. 2006, 129, 1-3.
• 32. Nawi, M.A.; Sabar, S.; Jawad, A.H.; Sheilatina, Wan Ngah W.S. Biochem. Eng. J. 2010, 49, 317-325.
• 33. Kyzas, G.Z.; Travlou. N.A.; Kalogirou, O.; Deliyanni, E.A. Materials 2013, 6, 1360-1376.
• 34. Adane, B.; Siraj, K.; Meka, N. Green Chem. Lett. Rev. 2015, 8 (3-4), 1-12.
• 35. Foo, K.Y.; Hameed, B.H. Chem. Eng. J. 2010, 156, 2-10.
• 36. Chang, M.; Shih, Y. J. Environ. Manage. 2018, 224, 235–242.
• 37. Xue Z, Zhao S, Zhao Z, Li, P.; Gao, J. J. Mater. Sci. 2016, 51, 4928-4941.
• 38. Chen A, Li Y, Yu Y, Li, Y.; Xia, K.; Wang, Y.; Li, S. J. Mater. Sci. 2016, 51, 7016-7028.