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Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene

Year 2021, Volume: 5 Issue: 1, 33 - 41, 30.06.2021
https://doi.org/10.32571/ijct.755761

Abstract

This study focused on the synthesis of silica-coated magnetic Fe3O4 (Fe3O4@SiO2) nanoparticles and their application for the improvement of the vapor-phase adsorption of benzene. The magnetic Fe3O4@SiO2 nanoparticles were synthesized according to the co-precipitation method, while their characterization was performed using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and Brunauer-Emmett-Teller (BET) surface area analyses. The experimental parameters were optimized to achieve the maximum adsorption capacity for the vapor-phase benzene by Box-Behnken design (BBD) under response surface methodology (RSM). The magnetic Fe3O4@SiO2 nanoparticles adsorbed 197.50 mg/g of the vapor-phase benzene under the following optimum conditions: 39.48 min residence time, 14.21 ppm initial benzene concentration and 26.51°C temperature. The Langmuir, Freundlich and Dubinin-Radushkevich (D-R) models were used to evaluate the adsorption equilibrium data, and the results were found to be well fitted to the D-R model. The kinetic data obeyed the pseudo-second-order kinetic model for the vapor-phase adsorption of benzene by magnetic Fe3O4@SiO2 nanoparticles. This study demonstrated the application potential of magnetic Fe3O4@SiO2 nanoparticles as promising low-cost nano-adsorbents for the vapor-phase adsorption of benzene.

Supporting Institution

Mardin Artuklu University Research Fund (MAUBAP)

Project Number

MAÜ.BAP.18.SHMYO.030

Thanks

The authors are grateful to the Mardin Artuklu University Research Fund (MAUBAP, Project No. MAÜ.BAP.18.SHMYO.030) for their financial support.

References

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Year 2021, Volume: 5 Issue: 1, 33 - 41, 30.06.2021
https://doi.org/10.32571/ijct.755761

Abstract

Project Number

MAÜ.BAP.18.SHMYO.030

References

  • Wallace, L. A. Environ. Health Perspect. 1989, 82, 165-169.
  • Yang, X.; Yi, H.; Tang, X.; Zhao, S.; Yang, Z.; Ma, Y.; Feng, T.; Cui, X. J. Environ. Sci. 2018, 67, 104-114.
  • Wibowo, N.; Setyadhi, L.; Wibowo, D.; Setiawan, J.; Ismadji, S. J. Hazard. Mater. 2007, 146 (1-2), 237-242.
  • Roto, R.; Yusran, Y.; Kuncaka, A. Appl. Surf. Sci. 2016, 377, 30-36.
  • Zandipak, R.; Sobhan Ardakani, S.; Shirzadi, A. Sep. Sci. Technol. 2020, 55 (3), 456-470.
  • Kutluay, S.; Baytar, O.; Şahin, Ö. J. Environ. Chem. Eng. 2019, 7 (2), 102947.
  • Zhao, Z.; Wang, S.; Yang, Y.; Li, X.; Li, J.; Li, Z. Chem. Eng. J. 2015, 259, 79-89.
  • Ma, C.; Li, C.; He, N.; Wang, F.; Ma, N.; Zhang, L.; Lu, Z.; Ali, Z.; Xi, Z.; Li, X. J. Biomed. Nanotechnol. 2012, 8 (6), 1000-1005.
  • Vohra, M. S. Arab. J. Sci. Eng. 2015, 40 (11), 3007-3017.
  • Padmavathy, V. Bioresour. Technol. 2008, 99 (8), 3100-3109.
  • Borandegi, M.; Nezamzadeh-Ejhieh, A. Colloids Surf. A. Physicochem. Eng. 2015, 479, 35-45.
  • Kutluay, S.; Baytar, O.; Şahin, Ö. Res. Eng. Struct. Mater. 2019, 5 (3), 279-298.
  • Zouboulis, A.; Loukidou, M.; Matis, K. Process Biochem. 2004, 39 (8), 909-916.
  • Kutluay, S. BEÜ Fen Bilimleri Dergisi 2019, 8 (4), 1432-1445.
  • Vora, S.; Khimani, M.; De, C. J. Dispers. Sci. Technol. 2013, 34 (7), 947-956.
  • Salih, W. M.; Gzar, H. A.; Hassan, N. F. J. Eng. 2012, 18 (9), 1042-1054.
  • Hu, Q.; Zhang, Z. J. Mol. Liq. 2019, 277, 646-648.
There are 17 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Articles
Authors

Mehmet Şakir Ece 0000-0002-9411-314X

Sinan Kutluay This is me 0000-0002-9411-314X

Ömer Şahin 0000-0003-4575-3762

Project Number MAÜ.BAP.18.SHMYO.030
Publication Date June 30, 2021
Published in Issue Year 2021 Volume: 5 Issue: 1

Cite

APA Ece, M. Ş., Kutluay, S., & Şahin, Ö. (2021). Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology, 5(1), 33-41. https://doi.org/10.32571/ijct.755761
AMA Ece MŞ, Kutluay S, Şahin Ö. Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. Int. J. Chem. Technol. June 2021;5(1):33-41. doi:10.32571/ijct.755761
Chicago Ece, Mehmet Şakir, Sinan Kutluay, and Ömer Şahin. “Silica-Coated Magnetic Fe3O4 Nanoparticles As Efficient Nano-Adsorbents for the Improvement of the Vapor-Phase Adsorption of Benzene”. International Journal of Chemistry and Technology 5, no. 1 (June 2021): 33-41. https://doi.org/10.32571/ijct.755761.
EndNote Ece MŞ, Kutluay S, Şahin Ö (June 1, 2021) Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology 5 1 33–41.
IEEE M. Ş. Ece, S. Kutluay, and Ö. Şahin, “Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene”, Int. J. Chem. Technol., vol. 5, no. 1, pp. 33–41, 2021, doi: 10.32571/ijct.755761.
ISNAD Ece, Mehmet Şakir et al. “Silica-Coated Magnetic Fe3O4 Nanoparticles As Efficient Nano-Adsorbents for the Improvement of the Vapor-Phase Adsorption of Benzene”. International Journal of Chemistry and Technology 5/1 (June 2021), 33-41. https://doi.org/10.32571/ijct.755761.
JAMA Ece MŞ, Kutluay S, Şahin Ö. Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. Int. J. Chem. Technol. 2021;5:33–41.
MLA Ece, Mehmet Şakir et al. “Silica-Coated Magnetic Fe3O4 Nanoparticles As Efficient Nano-Adsorbents for the Improvement of the Vapor-Phase Adsorption of Benzene”. International Journal of Chemistry and Technology, vol. 5, no. 1, 2021, pp. 33-41, doi:10.32571/ijct.755761.
Vancouver Ece MŞ, Kutluay S, Şahin Ö. Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. Int. J. Chem. Technol. 2021;5(1):33-41.

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