Research Article
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Year 2021, Volume: 5 Issue: 1, 1 - 5, 30.06.2021
https://doi.org/10.32571/ijct.785497

Abstract

References

  • 1. İzgi, M. S.; Şahin, Ö.; Erhan, O.; Horoz, S. Iğdır Üniv. Fen Bil. Ens. Derg. 2017, 7 (4), 151-160.
  • 2. Christian, P. A.; Eylem, C.; Nanjundaswamy, K. S.; Zhang, F.; Wang, Google Patents: 2007.
  • 3. Tutar, F.; Mehmet, E., Uluslararası İktisadi ve İdari İncelemeler Dergisi 2011, (6), 61-67.
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  • 7. Huynh, K.; Napolitano, K.; Wang, R.; Jessop, P. G.; Davis, B. R. Int. J of Hyd. Energy. 2013, 38 (14), 5775-5782.
  • 8. Su, C.-C.; Lu, M.-C.; Wang, S.-L.; Huang, Y.-H. RSC advances. 2012, 2 (5), 2073-2079.
  • 9. İzgi, M. S.; Şahin, Ö.; Saka. Int. J. of Hyd. Energy 2016, 41 (3), 1600-1608.
  • 10. İzgi, M. S. Energy. Sour., Part A: Reco. Utilization and En. Effect 2016, 38 (17), 2590-2597.
  • 11. Sait Izgi, M.; Şahin, Ö.; Saka, C. Materials and Manufac. Processes 2019, 34 (14), 1620-1626.
  • 12. Kazici, H. Ç.; Yildiz, F.; İzgi, M. S.; Ulaş, B.; Kivrak, H. Int. J. of Hydrogen Energy 2019, 44 (21), 10561-10572.
  • 13. Jeong, S.; Kim, R.; Cho, E.; Kim, H.-J.; Nam, S.-W.; Oh, I.-H.; Hong, S.-A.; Kim, S. H. Journal of Power Sources 2005, 144 (1), 129-134.
  • 14. Salinas-Torres, D.; Navlani-García, M.; Kuwahara, Y.; Mori, K.; Yamashita, H. Catalysis Today 2019, 324, 90-96.
  • 15. Jia, H.; Chen, X.; Song, X.; Zheng, X.; Guan, X.; Liu, P. Int. J. of Energy Research 2019, 43 (1), 535-543.
  • 16. İzgi, M. S.; Baytar, O.; Şahin, Ö.; Kazıcı, H. Ç, Int. J. of Hydrogen Energy 2020. doi.org/10.1016/j.ijhydene.2020.04.034
  • 17. Rakap, M., Renewable Energy 2020, 155, 1222-1230.

Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst

Year 2021, Volume: 5 Issue: 1, 1 - 5, 30.06.2021
https://doi.org/10.32571/ijct.785497

Abstract

Ammonia boron is one of the chemical compounds with high energy density that eliminates the problem of storing hydrogen, a clean energy source. Ammonia borane (NH3BH3), one of the chemical hydrogen storage compounds; High hydrogen capacity (19.6% H2 by mass) has a very important place in hydrogen fuel technology due to its stable structure in its aqueous solution.

The main parameter determining the ammonia borane hydrolysis, hydrogen production efficiency and reaction course is catalyst. Different structures and methods are used for catalyst production. One of these methods is catalysts produced from transition metal complexes with high catalytic effect and low cost. This study focuses on the hydrolysis of hydrogen production parameters from ammonia borane through the synthesized Co-Cr-B catalyst using the low cost of cobalt (Co) and chromium (Cr). The synthesized Co-Cr-B catalyst was interacted with the ammonia borane solution. Later, optimum conditions for the hydrolysis of ammonia bora were determined by catalyst amount, different NaOH concentration and catalytic activity at different temperatures. Reaction kinetics were examined based on the data obtained. The activation energy of the reaction was 22.3 kJ mol-1, the degree of reaction was determined as the 1st degree.

References

  • 1. İzgi, M. S.; Şahin, Ö.; Erhan, O.; Horoz, S. Iğdır Üniv. Fen Bil. Ens. Derg. 2017, 7 (4), 151-160.
  • 2. Christian, P. A.; Eylem, C.; Nanjundaswamy, K. S.; Zhang, F.; Wang, Google Patents: 2007.
  • 3. Tutar, F.; Mehmet, E., Uluslararası İktisadi ve İdari İncelemeler Dergisi 2011, (6), 61-67.
  • 4. Şahin, Ö.; İzgi, M. S.; Onat, E.; Saka, C. Int. J. of Hyd. Energy, 2016, 41 (4), 2539-2546.
  • 5. Fernandes, R.; Patel, N.; Miotello, A, Applied Catalysis B: Environ. 2009, 92 (1-2), 68-74.
  • 6. Ding, X.-L.; Yuan, X.; Jia, C.; Ma, Z.-F. Int. J. of Hyd. Energy. 2010, 35 (20), 11077-11084.
  • 7. Huynh, K.; Napolitano, K.; Wang, R.; Jessop, P. G.; Davis, B. R. Int. J of Hyd. Energy. 2013, 38 (14), 5775-5782.
  • 8. Su, C.-C.; Lu, M.-C.; Wang, S.-L.; Huang, Y.-H. RSC advances. 2012, 2 (5), 2073-2079.
  • 9. İzgi, M. S.; Şahin, Ö.; Saka. Int. J. of Hyd. Energy 2016, 41 (3), 1600-1608.
  • 10. İzgi, M. S. Energy. Sour., Part A: Reco. Utilization and En. Effect 2016, 38 (17), 2590-2597.
  • 11. Sait Izgi, M.; Şahin, Ö.; Saka, C. Materials and Manufac. Processes 2019, 34 (14), 1620-1626.
  • 12. Kazici, H. Ç.; Yildiz, F.; İzgi, M. S.; Ulaş, B.; Kivrak, H. Int. J. of Hydrogen Energy 2019, 44 (21), 10561-10572.
  • 13. Jeong, S.; Kim, R.; Cho, E.; Kim, H.-J.; Nam, S.-W.; Oh, I.-H.; Hong, S.-A.; Kim, S. H. Journal of Power Sources 2005, 144 (1), 129-134.
  • 14. Salinas-Torres, D.; Navlani-García, M.; Kuwahara, Y.; Mori, K.; Yamashita, H. Catalysis Today 2019, 324, 90-96.
  • 15. Jia, H.; Chen, X.; Song, X.; Zheng, X.; Guan, X.; Liu, P. Int. J. of Energy Research 2019, 43 (1), 535-543.
  • 16. İzgi, M. S.; Baytar, O.; Şahin, Ö.; Kazıcı, H. Ç, Int. J. of Hydrogen Energy 2020. doi.org/10.1016/j.ijhydene.2020.04.034
  • 17. Rakap, M., Renewable Energy 2020, 155, 1222-1230.
There are 17 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Erhan Onat 0000-0003-1638-0151

Mehmet Sait İzgi 0000-0003-3685-3219

Publication Date June 30, 2021
Published in Issue Year 2021 Volume: 5 Issue: 1

Cite

APA Onat, E., & İzgi, M. S. (2021). Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst. International Journal of Chemistry and Technology, 5(1), 1-5. https://doi.org/10.32571/ijct.785497
AMA Onat E, İzgi MS. Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst. Int. J. Chem. Technol. June 2021;5(1):1-5. doi:10.32571/ijct.785497
Chicago Onat, Erhan, and Mehmet Sait İzgi. “Hydrogen Generation by Hydrolysis of Ammonia Borohydride Using the Nano-Bimetallic Catalyst”. International Journal of Chemistry and Technology 5, no. 1 (June 2021): 1-5. https://doi.org/10.32571/ijct.785497.
EndNote Onat E, İzgi MS (June 1, 2021) Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst. International Journal of Chemistry and Technology 5 1 1–5.
IEEE E. Onat and M. S. İzgi, “Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst”, Int. J. Chem. Technol., vol. 5, no. 1, pp. 1–5, 2021, doi: 10.32571/ijct.785497.
ISNAD Onat, Erhan - İzgi, Mehmet Sait. “Hydrogen Generation by Hydrolysis of Ammonia Borohydride Using the Nano-Bimetallic Catalyst”. International Journal of Chemistry and Technology 5/1 (June 2021), 1-5. https://doi.org/10.32571/ijct.785497.
JAMA Onat E, İzgi MS. Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst. Int. J. Chem. Technol. 2021;5:1–5.
MLA Onat, Erhan and Mehmet Sait İzgi. “Hydrogen Generation by Hydrolysis of Ammonia Borohydride Using the Nano-Bimetallic Catalyst”. International Journal of Chemistry and Technology, vol. 5, no. 1, 2021, pp. 1-5, doi:10.32571/ijct.785497.
Vancouver Onat E, İzgi MS. Hydrogen generation by hydrolysis of ammonia borohydride using the Nano-Bimetallic catalyst. Int. J. Chem. Technol. 2021;5(1):1-5.