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SUPER PLASTICIZER POLYMER SYNTHESIS

Year 2024, Volume: 9 Issue: 1, 29 - 41, 10.06.2024

Abstract

In this study, it is aimed to synthesize more environmentally friendly and low-cost biopolymer based super plasticizers (SP) by using biopolymers (starch, chitosan polysaccharide, floral oils, etc.), acrylic acid, maleic anhydride, sodium vinyl sulphonate and various corn starches and various catalysts. These raw materials have been examined in terms of their water holding capacity, viscosity, bond structures and renewability. For the structure determination of the synthesized products, FT-IR, fluidity and compressive strength tests are performed. Because it is aimed also to meet the local consumption of cement materials additives in Turkey. In this process, it is to protect our environment by making it bio-based as much as we can, away from today's chemicals and petroleum derivatives. Three different types of polymer are synthesized: flower oil, bowine gelatine and mpeg5000. The ratio of sand:cement:water in the cement mixture used in the study is 2:1:0.45. Synthesized SP polymers were added to the cement mixture at a rate of 0.75%. In the experiments by connecting a plurality of parameters when selecting the appropriate optimal values according to the appropriate product and polymerizing bond products it was synthesized. FTIR results match the peaks in each raw material. So detailed generalization of the bond structure is appropriate. It can be said that bio raw material synthesis is encouraging in the future, and it can be found that form the compressive strength test, the flower oil being more resistant. As a result of this study, three types of polymeric additives were successfully synthesized and analyzed and performance tests were completed.

References

  • [1] Liu X., Wang Z., Zheng Y., Cui S., Lan M., Li H., Zhu J., Liang X. Preparation, Characterization and Performances of Powdered Polycarboxylate Superplasticizer with Bulk Polymerization. College of Materials Science and Engineering 2014; 7: 6169-6183.
  • [2] Arat R. Synthesis and Characterization of New Generationpolymeric Additives for Cem I Cement Mortar, MSc, İstanbul Technical University, İstanbul, Turkey, 2010, 1-68.
  • [3] Hui W., Huiling G., Jiaheng L., Ronguo Z., Yong L. Research on synthesis and action mechanism of polycarboxylate superplasticizer. Front. Chem. China 2007, 2(3): 322–325.
  • [4] Flatt R., Schober I. Superplasticizers and the Rheology of Concrete. In Nicolas Roussel. 1 st ed. Understanding the Rheology of Concrete. Woodhead, 2012.
  • [5] Houst Yves F., Bowen P., Perche F., Kauppi A., Borget P., Galmiche L., Le Meins J.F., Lafuma F., Flatt R.J., Schober I. Design and Function of Novel Superplasticizers for more Durable High performance Concrete (Superplast Project). Cement and Concrete Research, 2008, 38: 1197–1209.
  • [6] Liu X., Guan J. Yunsheng Z., Wang Z., Ren X. Synthesis of High Performance Polycarboxylate Superplasticizer through Redox Initiation System and its Application in Concrete. College of Materials Science and Engineering, 2016, 723: 681-686.
  • [7] Rongguo Z., Qiong L., Anfu Z., Yong L., Jiaheng L. The Synthesis Technique of Polyacrylic Acid Superplasticizer. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2008, 23, (6): 830-833.
  • [8] Dinakar, P., & Manu, S. N. Concrete Mix Design for High Strength Selfcompacting Concrete using Metakaolin. Materials and Design, 2014, 60: 661–668.
  • [9] Silvaa W., Bufalino L., Martins M., Júnior H., Tono G., Mendes L. Superabsorbent Ability Polymer to Reduce the Bulk Density of Extruded Cement Boards, Journal of Building Engineering, 2021, 43: 103130.
  • [10] Mechtcherine, V., Wyrzykowski, M., Schröfl, C. Application of Super Absorbent Polymers (SAP) in Concrete Construction, 2021, 54, 80.
  • [11] Sidiq A., Gravina R., Setunge S., Giustozzi F. The Effectiveness of Super Absorbent Polymers and Superplasticizer in Self-Healing of Cementitious Materials, Construction and Building Materials, 2020, 253: 119175.
  • [12] Mechtcherine, V., M. Gorges, C. Schroefl, A. Assmann, W. Brameshuber, A.N.B. Ribeiro, D. Cusson, J. Custdio, E.F. da Silva, and K. Ichimiya. Effect of Internal Curing by Using Superabsorbent Polymers (SAP) on Autogenous Shrinkage and Other Properties of a High-Performance Fine-Grained Concrete: Results of a RILEM Round-Robin Test. Materials and Structures, 2014, 47(3): 541-562.
  • [13] Snoeck, D. and N. De Belie. Repeated Autogenous Healing in Strain-Hardening Cementitious Composites by Using Superabsorbent Polymers. Journal of Materials in Civil Engineering, 2016, 28(1): 04015086.
  • [14] Cuenca, E., A. Tejedor, and L. Ferrara. A Methodology to Assess Crack-Sealing Effectiveness of Crystalline Admixtures Under Repeated Cracking-Healing Cycles. Construction and Building Materials, 2018, 179: 619-632.
  • [15] Abdollahnejad Z., Kheradmand M., Pacheco-Torgal F. Influence of two commercial superplasticizers and a biopolymer on the performance of waste-based alkali-activated mortars, Bio-based Materials and Biotechnologies for Eco-Efficient Construction, 2020, 43-46.
  • [16] Mermerdaş K., Manguri s., Nassani D., Mahdi S. Effect of aggregate properties on the mechanical and absorption characteristics of geopolymer mortar, Engineering Science and Technology an International Journal, 2017, 20:6.
  • [17] Salih S., Mohamed J. H. Effect of Plastic Optical Fibers on Properties of Translucent Concrete Boards, First International Conference on Engineering Sciences’ Applications, ICESA, 2014, 453-466.
  • [18] Werani M., Lei L. Influence of side chain length of MPEG – based polycarboxylate superplasticizers on their resistance towards intercalation into clay structures, Construction and Building Materials, 2021, 281:122621.
Year 2024, Volume: 9 Issue: 1, 29 - 41, 10.06.2024

Abstract

References

  • [1] Liu X., Wang Z., Zheng Y., Cui S., Lan M., Li H., Zhu J., Liang X. Preparation, Characterization and Performances of Powdered Polycarboxylate Superplasticizer with Bulk Polymerization. College of Materials Science and Engineering 2014; 7: 6169-6183.
  • [2] Arat R. Synthesis and Characterization of New Generationpolymeric Additives for Cem I Cement Mortar, MSc, İstanbul Technical University, İstanbul, Turkey, 2010, 1-68.
  • [3] Hui W., Huiling G., Jiaheng L., Ronguo Z., Yong L. Research on synthesis and action mechanism of polycarboxylate superplasticizer. Front. Chem. China 2007, 2(3): 322–325.
  • [4] Flatt R., Schober I. Superplasticizers and the Rheology of Concrete. In Nicolas Roussel. 1 st ed. Understanding the Rheology of Concrete. Woodhead, 2012.
  • [5] Houst Yves F., Bowen P., Perche F., Kauppi A., Borget P., Galmiche L., Le Meins J.F., Lafuma F., Flatt R.J., Schober I. Design and Function of Novel Superplasticizers for more Durable High performance Concrete (Superplast Project). Cement and Concrete Research, 2008, 38: 1197–1209.
  • [6] Liu X., Guan J. Yunsheng Z., Wang Z., Ren X. Synthesis of High Performance Polycarboxylate Superplasticizer through Redox Initiation System and its Application in Concrete. College of Materials Science and Engineering, 2016, 723: 681-686.
  • [7] Rongguo Z., Qiong L., Anfu Z., Yong L., Jiaheng L. The Synthesis Technique of Polyacrylic Acid Superplasticizer. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2008, 23, (6): 830-833.
  • [8] Dinakar, P., & Manu, S. N. Concrete Mix Design for High Strength Selfcompacting Concrete using Metakaolin. Materials and Design, 2014, 60: 661–668.
  • [9] Silvaa W., Bufalino L., Martins M., Júnior H., Tono G., Mendes L. Superabsorbent Ability Polymer to Reduce the Bulk Density of Extruded Cement Boards, Journal of Building Engineering, 2021, 43: 103130.
  • [10] Mechtcherine, V., Wyrzykowski, M., Schröfl, C. Application of Super Absorbent Polymers (SAP) in Concrete Construction, 2021, 54, 80.
  • [11] Sidiq A., Gravina R., Setunge S., Giustozzi F. The Effectiveness of Super Absorbent Polymers and Superplasticizer in Self-Healing of Cementitious Materials, Construction and Building Materials, 2020, 253: 119175.
  • [12] Mechtcherine, V., M. Gorges, C. Schroefl, A. Assmann, W. Brameshuber, A.N.B. Ribeiro, D. Cusson, J. Custdio, E.F. da Silva, and K. Ichimiya. Effect of Internal Curing by Using Superabsorbent Polymers (SAP) on Autogenous Shrinkage and Other Properties of a High-Performance Fine-Grained Concrete: Results of a RILEM Round-Robin Test. Materials and Structures, 2014, 47(3): 541-562.
  • [13] Snoeck, D. and N. De Belie. Repeated Autogenous Healing in Strain-Hardening Cementitious Composites by Using Superabsorbent Polymers. Journal of Materials in Civil Engineering, 2016, 28(1): 04015086.
  • [14] Cuenca, E., A. Tejedor, and L. Ferrara. A Methodology to Assess Crack-Sealing Effectiveness of Crystalline Admixtures Under Repeated Cracking-Healing Cycles. Construction and Building Materials, 2018, 179: 619-632.
  • [15] Abdollahnejad Z., Kheradmand M., Pacheco-Torgal F. Influence of two commercial superplasticizers and a biopolymer on the performance of waste-based alkali-activated mortars, Bio-based Materials and Biotechnologies for Eco-Efficient Construction, 2020, 43-46.
  • [16] Mermerdaş K., Manguri s., Nassani D., Mahdi S. Effect of aggregate properties on the mechanical and absorption characteristics of geopolymer mortar, Engineering Science and Technology an International Journal, 2017, 20:6.
  • [17] Salih S., Mohamed J. H. Effect of Plastic Optical Fibers on Properties of Translucent Concrete Boards, First International Conference on Engineering Sciences’ Applications, ICESA, 2014, 453-466.
  • [18] Werani M., Lei L. Influence of side chain length of MPEG – based polycarboxylate superplasticizers on their resistance towards intercalation into clay structures, Construction and Building Materials, 2021, 281:122621.
There are 18 citations in total.

Details

Primary Language English
Subjects Chemical Engineering (Other)
Journal Section Research Article
Authors

Onur Davuça This is me 0000-0002-7171-3281

Canan Uraz 0000-0002-9072-1420

Publication Date June 10, 2024
Submission Date January 11, 2024
Acceptance Date June 10, 2024
Published in Issue Year 2024 Volume: 9 Issue: 1

Cite

APA Davuça, O., & Uraz, C. (2024). SUPER PLASTICIZER POLYMER SYNTHESIS. The International Journal of Energy and Engineering Sciences, 9(1), 29-41.

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