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Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance

Year 2025, Volume: 10 Issue: 1, 1073 - 1102, 18.03.2025

Gizem Cihanoğlu

https://doi.org/10.58559/ijes.1591925

Abstract

In this study, a hydrothermal method was used to synthesize nickel hydroxide (Ni(OH)2) powders, which are active materials for use in nickel (Ni) electrodes located in nickel-zinc (NiZn) batteries. X-ray diffraction (XRD), scanning electron microscopy (SEM), zeta potential, Brunauer-Emmett-Teller (BET), and electrochemical characterization were used to characterize the cathode material in the prepared Ni electrodes. These results showed a β-phase Ni(OH)2 nanosphere with a well-crystalline structure. The electrochemical test results indicated the Ni electrode has a stable cyclic cycle in the half-cell. Based on the electrochemical performance results, the Ni electrode with Ni(OH)2, which was synthesized at 70oC for 3h of aging time (Ni_pH 12_3h_70oC), was the best-performing metal oxide. Compared with nickel electrodes, the NiCoZn electrode exhibited high OER (oxygen evolution reaction) and ORR (oxygen reduction reaction) activities because the combination of cobalt and zinc oxides with nickel provides excellent electrolyte access capability and promotes effective ion transfer through the active material. The NiZn battery with NiCoZn electrode showed a high capacity of 192.7 mAh gactive−1 at 10 mA cm−2 and cycling durability (after cycling at 10 mA cm−2 for 70 cycles). Benefiting from the excellent interaction between Ni, Co, and Zn, NiCoZn exhibited high onset potential and current density, suggesting that the NiCoZn electrode is a promising candidate as a high-performance configuration for Ni-based electrodes in NiZn batteries.

Keywords

Nickel hydroxide synthesis Nickel electrode NiZn batteries Battery performance

Thanks

The author would like to thank Prof. Dr. Özgenç EBİL for allowing the use of some of the equipment in his laboratory.

References

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Geliştirilmiş NiZn Batarya Performansı için Ni-tabanlı Elektrotların Üretimi ve Karakterizasyonu

Year 2025, Volume: 10 Issue: 1, 1073 - 1102, 18.03.2025

Gizem Cihanoğlu

https://doi.org/10.58559/ijes.1591925

Abstract

Bu çalışmada, nikel-çinko (NiZn) bataryasında nikel elektrot olarak kullanılmak üzere aktif malzeme olan nikel hidroksit (Ni(OH)2) tozlarını sentezlemek için hidrotermal yöntem kullanılmıştır. Hazırlanan Ni elektrotlardaki katot malzemesini karakterize etmek için X-ışını kırınımı (XRD), taramalı elektron mikroskobu (SEM), zeta potansiyeli, Brunauer-Emmett-Teller (BET) ve elektrokimyasal performans testleri kullanılmıştır. Sonuçlar, kristal yapıya sahip β-fazlı nano boyutta küresel Ni(OH)2 partiküllerin sentezlendiğini göstermiştir. Elektrokimyasal test sonuçları ise Ni elektrodun yarı hücrede kararlı bir çevrim döngüsüne sahip olduğunu göstermiştir. Elektrokimyasal performans sonuçlarına göre, sentez sıcaklığı 70oC olan ve sentez sonrası 3 saat boyunca bekletildikten sonra elde edilen Ni(OH)2 tozları ile hazırlanan Ni elektrot (Ni_pH12_3h_70oC) en iyi performans gösteren metal hidroksit olmuştur. Nikel elektrotlar birbiriyle karşılaştırıldığında, NiCoZn elektrot yüksek OER (oksijen evrim reaksiyonu) ve ORR (oksijen indirgeme reaksiyonu) aktiviteleri sergilemiştir, çünkü kobalt ve çinko oksitlerin nikel ile kombinasyonu mükemmel elektrolit erişim kabiliyeti ve aktif malzeme boyunca etkili iyon transferi sağlamaktadır. NiZn batarya içerisinde kullanılan NiCoZn elektrotu 10 mA cm-2 akım yoğunluğunda 192,7 mAh gaktif-1 değere ulaşarak yüksek bir kapasite ve kararlı bir çevrim döngüsü (10 mA cm-2'de 70 çevrim döngüsü sonucunda) sergilemiştir. NiCoZn elektrodu Ni, Co ve Zn arasındaki mükemmel etkileşmi ile, yüksek başlangıç potansiyeli ve akım yoğunluğu sergilemiş; bu da NiCoZn elektrotun NiZn bataryalardaki Ni-tabanlı elektrotlar için yüksek performanslı bir konfigürasyon olarak umut verici bir aday olduğunu göstermiştir.

Keywords

nikel hidroksit sentezi nikel elektrot NiZn batarya batarya performansı,

References

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  • [2] Jindra J. Progress in sealed Ni-Zn cells, 1991–1995. Journal of Power Sources 1997; 66: 15- 25.
  • [3] Ma M, Tu JP, Yuan YF, Wang XL, Li KF, Mao F, Zeng ZY. Electrochemical performance of ZnO nanoplates as anode materials for Ni/Zn secondary batteries. Journal of Power Sources 2008; 179: 395-400.
  • [4] Huang H, Zhang L, Zhang WK, Gan YP, Shao H. Preparation and electrochemical properties of ZnO/conductive-ceramic nanocomposite as anode material for Ni/Zn rechargeable battery. Journal of Power Sources 2008; 184: 663-667.
  • [5] Wiston BR, Ashok M. Electrochemical performance of hydrothermally synthesized flowerlike α-nickel hydroxide. Vacuum 2019; 160: 12-17.
  • [6] Zhao J, Zhang Q. Synthesis of Ni(OH)2 nanoflakes through a novel ion diffusion method controlled by ion exchange membrane and electrochemical supercapacitive properties. Electrochimica Acta 2015; 184: 47-57.
  • [7] Hu WK, Gao XP, Noréus D, Burchardt T, Nakstad NK. Evaluation of nano-crystal sized αnickel hydroxide as an electrode material for alkaline rechargeable cells. Journal of Power Sources 2006; 160: 704-710.
  • [8] Ash B, Mishra KG, Subbaiah T, Paramguru RK, Mishra BK. Electrochemical studies on electrolytic preparation of battery grade nickel hydroxide–Effect of (OH)− to Ni2+ ratio. Journal of Power Sources 2015; 275: 55-63.
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  • [10] Zhou H, Zhou Z. Preparation, structure and electrochemical performances of nanosized cathode active material Ni(OH)2. Solid State Ionics 2005; 176: 1909-1914.
  • [11] Yang D, Wang R, He M, Zhang J, Liu Z. Ribbon and boardlike nanostructures of nickel hydroxide: synthesis, characterization, and electrochemical properties. The Journal of Physical Chemistry B 2005; 109: 7654-7658.
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  • [18] Matsui K, Kyotani T, Tomita A. Hydrothermal synthesis of single-crystal Ni(OH)2 nanorods in a carbon-coated anodic alumina film. Advanced Materials 2002; 14: 1216-1219.
  • [19] Tan Y, Srinivasan S, Choi KS. Electrochemical deposition of mesoporous nickel hydroxide films from dilute surfactant solutions. Journal of the American Chemical Society 2005; 127: 3596- 3604.
  • [20] Chen D, Gao L. A new and facile route to ultrafine nanowires, superthin flakes and uniform nanodisks of nickel hydroxide. Chemical Physics Letters 2005; 405: 159-164.
  • [21] Peng MX, Shen XQ, Wang LS, Wei YH. Structural characteristics of spherical Ni(OH)2 and its charge-discharge process mechanism. Journal of Central South University of Technology 2005; 12: 5-8.
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  • [29] Kumari L, Li WZ. Self-assembly of β-Ni(OH)2 nanoflakelets to form hollow submicrospheres by hydrothermal route. Physica E: Low-dimensional Systems and Nanostructures 2009; 41: 1289- 1292.
  • [30] Wang BN, Chen XY, Zhang DW. Controllable synthesis and characterization of CuO, βNi(OH)2 and Co3O4 nanocrystals in the MCln–NH4VO3–NaOH system. Journal of Physics and Chemistry of Solids 2010; 71: 285-289.
  • [31] Vidotti M, Greco CV, Ponzio EA, Torresi SIC. Sonochemically synthesized Ni(OH)2 and Co(OH)2 nanoparticles and their application in electrochromic electrodes. Electrochemistry Communications 2006; 8: 554-560.
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There are 82 citations in total.

Details

Primary Language English
Subjects Electrochemical Energy Storage and Conversion
Journal Section Research Article
Authors

Gizem Cihanoğlu 0000-0002-1524-7634

Publication Date March 18, 2025
Submission Date November 27, 2024
Acceptance Date January 11, 2025
Published in Issue Year 2025 Volume: 10 Issue: 1

Cite

APA Cihanoğlu, G. (2025). Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance. International Journal of Energy Studies, 10(1), 1073-1102. https://doi.org/10.58559/ijes.1591925
AMA Cihanoğlu G. Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance. Int J Energy Studies. March 2025;10(1):1073-1102. doi:10.58559/ijes.1591925
Chicago Cihanoğlu, Gizem. “Fabrication and Characterization of Ni-Based Electrodes for Improved NiZn Battery Performance”. International Journal of Energy Studies 10, no. 1 (March 2025): 1073-1102. https://doi.org/10.58559/ijes.1591925.
EndNote Cihanoğlu G (March 1, 2025) Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance. International Journal of Energy Studies 10 1 1073–1102.
IEEE G. Cihanoğlu, “Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance”, Int J Energy Studies, vol. 10, no. 1, pp. 1073–1102, 2025, doi: 10.58559/ijes.1591925.
ISNAD Cihanoğlu, Gizem. “Fabrication and Characterization of Ni-Based Electrodes for Improved NiZn Battery Performance”. International Journal of Energy Studies 10/1 (March 2025), 1073-1102. https://doi.org/10.58559/ijes.1591925.
JAMA Cihanoğlu G. Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance. Int J Energy Studies. 2025;10:1073–1102.
MLA Cihanoğlu, Gizem. “Fabrication and Characterization of Ni-Based Electrodes for Improved NiZn Battery Performance”. International Journal of Energy Studies, vol. 10, no. 1, 2025, pp. 1073-02, doi:10.58559/ijes.1591925.
Vancouver Cihanoğlu G. Fabrication and characterization of Ni-based electrodes for improved NiZn battery performance. Int J Energy Studies. 2025;10(1):1073-102.
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