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Review on Natural Dye-Sensitized Solar Cells (DSSCs)

Year 2016, , 34 - 41, 22.06.2016
https://doi.org/10.19072/ijet.96456

Abstract

In a conversion system of pure and non-convectional solar energy to electricity, dye sensitized solar cells (DSSCs) encourage the fabrication of photovoltaic devices providing high conversion efficiency at low cost. The dye as a sensitizer plays a vital role in performance evaluation of DSSCs. Natural dyes (organic dyes) has come to be a worth-while substitute to the rare and expensive inorganic sensitizers because of its cost effective, extreme availability and biodegradable. Different parts of a plant like fruits, leaves, flowers petals and bark have been tested over the years as sensitizers. The properties, together with some other parameters of these pigments give rise to improve in the operation standard of DSSCs. This review hash-out the history of DSSC with a focus on the recent developments of the natural dyes applications in this specific area with their overall appearance, the various components and the working principle of DSSCs as well as the work done over the years on natural dye based DSSCs.

References

  • M. Gratzel, (2003) Dye-sensitized solar cells, J. Photochem. Photobiol. C, 4: 145-153.
  • B. O’Regan, M. Gratzel, (1991) A Low-cost high-efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 353: 737-740.
  • J. O. Ozuomba, A. J. Ekpunobi, P. I. Ekwo, (2011) The viability of prophyrin local dye in the fabrication of dye-sensitized solar cells, Digest J. Nanomaterials and Biostructures, 6(3): 1043 – 1051.
  • M. Gratzel, (1991) Review article photo-electrochemical Cells, Nature 414, 338–344.
  • M.R. Narayan, (2012) Review: Dye sensitized Solar Cells based on natural photosensitizers, Renewable and Sustainable Energy Reviews 16:208– 215.
  • M. Grätzel, (2005) Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells, Inorg. Chem. 44: 6841-6851.
  • N.M. Gómez-Ortíz, I.A. Vázquez-Maldonado, A.R. Pérez-Espadas, G.J. Mena-Rejón, J.A. Azamar-Barrios, G. Oskam, (2009) Dye-sensitized solar cells with natural dyes extracted from a chiote seeds. Sol. Energy Mater. Sol. Cells, 94: 40-44.
  • A. Kay and M. Gratzel, (1993) Natural Pigment-Based Dye-Sensitized Solar Cells, J. Phys. Chem., 97 (23): 6272–6277.
  • M. K. Nazeeruddin, A. Kay, I. Rodicio, (1993) Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes, J. Amer. Chem. Soc., 115 (14): 6382-6390.
  • I. Jinchu, C.O Sreekala, K.S. Sreelatha, (2014) Dye sensitized solar cells using Natural dyes as chromophores – Review, Material Science Forum 741: 39-51.
  • C. Bauer, G. Boschloo, E. Mukhtar, A. Hagfeldt, (2002) Interfacial electron-transfer dynamics in Ru(tcterpy)(NCS)3- sensitized TiO2 nanocrystalline solar cells. J PhysChem B, 106:12693–704.
  • L. Antonio, S. Hegedus, (2003) Handbook of photovoltaic science and engineering. 1st ed.. UK: John Wiley & Sons Ltd Publishers
  • N.J. Cherepy, G.P. Smestad, M. Grätzel, J.Z. Zhang, (1997) Ultrafast electron injection: implications for a photo-electrochemical cell utilizing an anthocyanin dye-sensitized TiO2 nano-crystalline electrode. Journal of Physical Chemistry; 101: 9342–51.
  • G.P. Smestad, (1998) Education and solar conversion: demonstrating electron transfer, Sol Energy Mater Sol Cells; 55:157–78.
  • G. Calogero, G.D. Marco, (2008) Red Sicilian orange and purple eggplant fruite as natural sensitizers for dye-sensitized solar cells, Sol Energy Mater Sol Cells; 92:1341–6.
  • C. Bauer, G. Boschloo, E. Mukhtar, A. Hagfeldt (2002) Ultrafast studies of electron injection in Ru dye sensitized SnO2 nanocrystalline thin film, Int. J Photo- energy; 4:17–20.
  • Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide, L.Y. Han, (2006) Dye sensitized solar cells with conversion efficiency of 11.1%. Jpn J Appl Phys, 45: L638–L640.
  • R. Buscaino, C. Baiocchi, C. Barolo, C. Medana, M. Gratzel, M.D.K. Nazeeruddin, (2008) A mass spectrometric analysis of sensitizer solution used for dye sensitized solar cell. Inorg Chim Acta, 361:798–805.
  • D. Matthews, P. Infelta, M. Grätzel, (1996) Calculation of the photocurrent-potential characteristic for regenerative, sensitized semiconductor electrodes. Solar Energy Materials and Solar Cells, 44:119–55.
  • N.A. Ludin, A.M. Al-Alwani Mahmoud, A. Mohamad, A.H. Kadhum, K. Sopian, N. S. Abdul Karim, (2014) Review on the development of natural dye photosensitizer for dye-sensitized solar cells, Renewable and Sustainable Energy Reviews 31: 386–396.
  • Hao S, Wu J, Huang Y, Lin J. (2006). Natural dyes as photosensitizers for dye-sensitized solar cell. Sol. Energy 80: 209–214.
  • Hernandez-Martinez A.R., Estevez M, Vargas S, Quintanilla F, Radriguez R. (2012) Natural pigment based dye-sensitized solar cells. J Appl Res Technol., 10: 38–47.
  • Zhang D, Lanier S.M., Downing J.A., Avent J.L., Lum J., Mc Hale J.L. (2008) Betalain pigments for dye-sensitized solar cells. J Photo chem Photo bio l A: Chem, 195:72–80.
  • P.S. Greg, M. Grätzel (1998) Demonstrating electron transfer and nanotechnology: a natural dye sensitized nanocrystalline energy converter. J Chem Educ., 75:752–6.
  • Monari A, Assfeld X, Beley M, Gros P.C. (2011) Theoretical study of new ruthenium based dyes for dye-sensitized solar cells. J Phys Chem A, 115:3596–603.
  • M.K. Nazeeruddin, P. Péchy, T. Renouard, (2001) Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2 based solar cells. J Am Chem Soc., 123:1613–24.
  • A.O. Adeloye, P.A. Ajibade, (2011) A high molar extinction coefficient mono- anthracenyl bipyridyl heteroleptic Ruthenium(II) complex: synthesis, photo-physical and electrochemical properties. Molecules, 16:4615–31.
  • Yuancheng Q, Peng Q. (2012) Review articles: Ruthenium sensitizers and their application in dye sensitized solar cells. Int. J Photoenergy, 2012: 21 (Article ID291579).
  • Luque A, Hegedus S. (2003) Handbook of photovoltaic science and engineering. The Netherlands: Elsevier.
  • Chang H, Lo Y.J. (2010) Pomegranate leaves and mulberry fruit as natural sensitizers for dye sensitized solar cells. Sol Energy, 84:1833–7.
  • Kishiomoto S, Maoka T, Sumitomo K, Ohmya A. (2005) Analysis of carotenoid composition in petals of calendula (Calendula of ficinalis L).Biosci Biotechnol Biochem., 69:2122–8.
  • Keka S, Saha P.D., Datta S. (2012) Extraction of natural dye from etals Flam of forest (Buteamonosperma) flower: process optimization using response surface methodology (RSM). J Dyes Pigment, 94: 212–6.
  • Nishantha M.R., Yapa YPYP, Perera VPS. (2012) Sensitization of photoelectrochemical solar cells with a natural dye extracted from Kopsia flavida fruit. Proceed Tech Sess., 28:54–8.
  • Davies KM. (2004) Plant pigments and their manipulation, USA: Blackwell Publishing Ltd. Annual Plant Reviews; 342.
  • Calogero G, Marco G.D., Cazzanti S., Caramori S., Argazzi R., Carlo A.D., (2010) Efficient dye-sensitized solar cells using red turnip and purple wild Sicilian prickly pear fruits. International Journal of Molecular Sciences 11: 254–267.
  • Zhou H., Wu L., Gao Y., Ma T. (2011) ‘Dye-sensitized solar cells using 20 natural dyes as sensitizers’. J. Photochem. Photobiol. A: Chem. 219: 188–194.
  • Wongcharee K., Meeyoo V., Chavadej S. (2007) Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Sol. Energy Mater. Sol. Cells, 91: 566–571.
  • Hao S, Wu J, Huang Y, Lin J. (2006) Natural dyes as photosensitizers for dye-sensitized solar cell. Sol. Energy 80: 209–214.
  • Gòmez-Ortíz N.M., Vázquez-Maldonado I.A., Pérez-Espadas A.R., Mena-Rejón G.J., Azamar-Barrios J.A., Oskam G. (2009) Dye-sensitized solar cells with natural dyes extracted from achiote seeds. Sol. Energy Mater. Sol. Cells, 94: 40-44.
  • Yamazaki E, Murayama M, Nishikawa N, Hashimoto N, Shoyama M, Kurita O. (2007) Utilization ofnatural carotenoids as photosensitizers for dye-sensitized solar cells. Sol. Energy 81: 512–516.
  • Polo AS, Iha NYM. (2006) Blue sensitizers for solar cells: natural dyes from Calafate and Jaboticaba. Sol. Energy Mater. Sol. Cells, 90: 1936–1944.
  • Hernández-Martínez AR, Vargas S, Estevez M, Rodríguez R. (2010) Dye-sensitized solar cells from extracted bracts bougainvillea betalain pigments. In: 1st International Congress on Instrumentation and Applied Sciences, 1–15.
  • G.A. Armstrong, J.E. Hearst (1996) Carotenoids 2: Genetics and molecular biology of carotenoid pigment biosynthesis. FASEB J. 10 (2): 228–37. PMID 8641556.
  • X.F. Wang, J. Xiang, P. Wang, Y. Koyama (2005) Dye sensitized solar cells using chlorophyll a derivate as the sensitizer and carotenoids having different conjugation lengths as redox spacers. Chem Phys Lett., 408: 409–14.
  • H. Chang, M.J. Kao, T.L. Chen, H.G. Kuo, K.C. Choand, X.-P. Lin, (2011) Natural sensitizer for dye-sensitized solar cells using three layers of photoelectrode thin films with a Schottky barrier. Am J Eng Appl Sci., 4: 214–22.
  • H.I. Scheer In: B.R. Green, W.W. Parson, Editors. (2003) Light-harvesting antennas in photosynthesis. Dordrecht: Kluwer Academic Publishers; p. 513.
  • X.F. Wang, K. Osomu, H. Eiji, Z. Haoshen, S. Shin ichi, T. Hitoshi, (2010). TiO2 and ZnO based solar cells using a chlorophyll a derivative sensitizer for light-harvesting and energy conversion. J Photochem Photobiol A: Chem, 210: 145–52.
Year 2016, , 34 - 41, 22.06.2016
https://doi.org/10.19072/ijet.96456

Abstract

References

  • M. Gratzel, (2003) Dye-sensitized solar cells, J. Photochem. Photobiol. C, 4: 145-153.
  • B. O’Regan, M. Gratzel, (1991) A Low-cost high-efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 353: 737-740.
  • J. O. Ozuomba, A. J. Ekpunobi, P. I. Ekwo, (2011) The viability of prophyrin local dye in the fabrication of dye-sensitized solar cells, Digest J. Nanomaterials and Biostructures, 6(3): 1043 – 1051.
  • M. Gratzel, (1991) Review article photo-electrochemical Cells, Nature 414, 338–344.
  • M.R. Narayan, (2012) Review: Dye sensitized Solar Cells based on natural photosensitizers, Renewable and Sustainable Energy Reviews 16:208– 215.
  • M. Grätzel, (2005) Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells, Inorg. Chem. 44: 6841-6851.
  • N.M. Gómez-Ortíz, I.A. Vázquez-Maldonado, A.R. Pérez-Espadas, G.J. Mena-Rejón, J.A. Azamar-Barrios, G. Oskam, (2009) Dye-sensitized solar cells with natural dyes extracted from a chiote seeds. Sol. Energy Mater. Sol. Cells, 94: 40-44.
  • A. Kay and M. Gratzel, (1993) Natural Pigment-Based Dye-Sensitized Solar Cells, J. Phys. Chem., 97 (23): 6272–6277.
  • M. K. Nazeeruddin, A. Kay, I. Rodicio, (1993) Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes, J. Amer. Chem. Soc., 115 (14): 6382-6390.
  • I. Jinchu, C.O Sreekala, K.S. Sreelatha, (2014) Dye sensitized solar cells using Natural dyes as chromophores – Review, Material Science Forum 741: 39-51.
  • C. Bauer, G. Boschloo, E. Mukhtar, A. Hagfeldt, (2002) Interfacial electron-transfer dynamics in Ru(tcterpy)(NCS)3- sensitized TiO2 nanocrystalline solar cells. J PhysChem B, 106:12693–704.
  • L. Antonio, S. Hegedus, (2003) Handbook of photovoltaic science and engineering. 1st ed.. UK: John Wiley & Sons Ltd Publishers
  • N.J. Cherepy, G.P. Smestad, M. Grätzel, J.Z. Zhang, (1997) Ultrafast electron injection: implications for a photo-electrochemical cell utilizing an anthocyanin dye-sensitized TiO2 nano-crystalline electrode. Journal of Physical Chemistry; 101: 9342–51.
  • G.P. Smestad, (1998) Education and solar conversion: demonstrating electron transfer, Sol Energy Mater Sol Cells; 55:157–78.
  • G. Calogero, G.D. Marco, (2008) Red Sicilian orange and purple eggplant fruite as natural sensitizers for dye-sensitized solar cells, Sol Energy Mater Sol Cells; 92:1341–6.
  • C. Bauer, G. Boschloo, E. Mukhtar, A. Hagfeldt (2002) Ultrafast studies of electron injection in Ru dye sensitized SnO2 nanocrystalline thin film, Int. J Photo- energy; 4:17–20.
  • Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide, L.Y. Han, (2006) Dye sensitized solar cells with conversion efficiency of 11.1%. Jpn J Appl Phys, 45: L638–L640.
  • R. Buscaino, C. Baiocchi, C. Barolo, C. Medana, M. Gratzel, M.D.K. Nazeeruddin, (2008) A mass spectrometric analysis of sensitizer solution used for dye sensitized solar cell. Inorg Chim Acta, 361:798–805.
  • D. Matthews, P. Infelta, M. Grätzel, (1996) Calculation of the photocurrent-potential characteristic for regenerative, sensitized semiconductor electrodes. Solar Energy Materials and Solar Cells, 44:119–55.
  • N.A. Ludin, A.M. Al-Alwani Mahmoud, A. Mohamad, A.H. Kadhum, K. Sopian, N. S. Abdul Karim, (2014) Review on the development of natural dye photosensitizer for dye-sensitized solar cells, Renewable and Sustainable Energy Reviews 31: 386–396.
  • Hao S, Wu J, Huang Y, Lin J. (2006). Natural dyes as photosensitizers for dye-sensitized solar cell. Sol. Energy 80: 209–214.
  • Hernandez-Martinez A.R., Estevez M, Vargas S, Quintanilla F, Radriguez R. (2012) Natural pigment based dye-sensitized solar cells. J Appl Res Technol., 10: 38–47.
  • Zhang D, Lanier S.M., Downing J.A., Avent J.L., Lum J., Mc Hale J.L. (2008) Betalain pigments for dye-sensitized solar cells. J Photo chem Photo bio l A: Chem, 195:72–80.
  • P.S. Greg, M. Grätzel (1998) Demonstrating electron transfer and nanotechnology: a natural dye sensitized nanocrystalline energy converter. J Chem Educ., 75:752–6.
  • Monari A, Assfeld X, Beley M, Gros P.C. (2011) Theoretical study of new ruthenium based dyes for dye-sensitized solar cells. J Phys Chem A, 115:3596–603.
  • M.K. Nazeeruddin, P. Péchy, T. Renouard, (2001) Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2 based solar cells. J Am Chem Soc., 123:1613–24.
  • A.O. Adeloye, P.A. Ajibade, (2011) A high molar extinction coefficient mono- anthracenyl bipyridyl heteroleptic Ruthenium(II) complex: synthesis, photo-physical and electrochemical properties. Molecules, 16:4615–31.
  • Yuancheng Q, Peng Q. (2012) Review articles: Ruthenium sensitizers and their application in dye sensitized solar cells. Int. J Photoenergy, 2012: 21 (Article ID291579).
  • Luque A, Hegedus S. (2003) Handbook of photovoltaic science and engineering. The Netherlands: Elsevier.
  • Chang H, Lo Y.J. (2010) Pomegranate leaves and mulberry fruit as natural sensitizers for dye sensitized solar cells. Sol Energy, 84:1833–7.
  • Kishiomoto S, Maoka T, Sumitomo K, Ohmya A. (2005) Analysis of carotenoid composition in petals of calendula (Calendula of ficinalis L).Biosci Biotechnol Biochem., 69:2122–8.
  • Keka S, Saha P.D., Datta S. (2012) Extraction of natural dye from etals Flam of forest (Buteamonosperma) flower: process optimization using response surface methodology (RSM). J Dyes Pigment, 94: 212–6.
  • Nishantha M.R., Yapa YPYP, Perera VPS. (2012) Sensitization of photoelectrochemical solar cells with a natural dye extracted from Kopsia flavida fruit. Proceed Tech Sess., 28:54–8.
  • Davies KM. (2004) Plant pigments and their manipulation, USA: Blackwell Publishing Ltd. Annual Plant Reviews; 342.
  • Calogero G, Marco G.D., Cazzanti S., Caramori S., Argazzi R., Carlo A.D., (2010) Efficient dye-sensitized solar cells using red turnip and purple wild Sicilian prickly pear fruits. International Journal of Molecular Sciences 11: 254–267.
  • Zhou H., Wu L., Gao Y., Ma T. (2011) ‘Dye-sensitized solar cells using 20 natural dyes as sensitizers’. J. Photochem. Photobiol. A: Chem. 219: 188–194.
  • Wongcharee K., Meeyoo V., Chavadej S. (2007) Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Sol. Energy Mater. Sol. Cells, 91: 566–571.
  • Hao S, Wu J, Huang Y, Lin J. (2006) Natural dyes as photosensitizers for dye-sensitized solar cell. Sol. Energy 80: 209–214.
  • Gòmez-Ortíz N.M., Vázquez-Maldonado I.A., Pérez-Espadas A.R., Mena-Rejón G.J., Azamar-Barrios J.A., Oskam G. (2009) Dye-sensitized solar cells with natural dyes extracted from achiote seeds. Sol. Energy Mater. Sol. Cells, 94: 40-44.
  • Yamazaki E, Murayama M, Nishikawa N, Hashimoto N, Shoyama M, Kurita O. (2007) Utilization ofnatural carotenoids as photosensitizers for dye-sensitized solar cells. Sol. Energy 81: 512–516.
  • Polo AS, Iha NYM. (2006) Blue sensitizers for solar cells: natural dyes from Calafate and Jaboticaba. Sol. Energy Mater. Sol. Cells, 90: 1936–1944.
  • Hernández-Martínez AR, Vargas S, Estevez M, Rodríguez R. (2010) Dye-sensitized solar cells from extracted bracts bougainvillea betalain pigments. In: 1st International Congress on Instrumentation and Applied Sciences, 1–15.
  • G.A. Armstrong, J.E. Hearst (1996) Carotenoids 2: Genetics and molecular biology of carotenoid pigment biosynthesis. FASEB J. 10 (2): 228–37. PMID 8641556.
  • X.F. Wang, J. Xiang, P. Wang, Y. Koyama (2005) Dye sensitized solar cells using chlorophyll a derivate as the sensitizer and carotenoids having different conjugation lengths as redox spacers. Chem Phys Lett., 408: 409–14.
  • H. Chang, M.J. Kao, T.L. Chen, H.G. Kuo, K.C. Choand, X.-P. Lin, (2011) Natural sensitizer for dye-sensitized solar cells using three layers of photoelectrode thin films with a Schottky barrier. Am J Eng Appl Sci., 4: 214–22.
  • H.I. Scheer In: B.R. Green, W.W. Parson, Editors. (2003) Light-harvesting antennas in photosynthesis. Dordrecht: Kluwer Academic Publishers; p. 513.
  • X.F. Wang, K. Osomu, H. Eiji, Z. Haoshen, S. Shin ichi, T. Hitoshi, (2010). TiO2 and ZnO based solar cells using a chlorophyll a derivative sensitizer for light-harvesting and energy conversion. J Photochem Photobiol A: Chem, 210: 145–52.
There are 47 citations in total.

Details

Journal Section Articles
Authors

Oluwaseun Adedokun

Kamil Titilope This is me

Ayodeji Oladiran Awodugba This is me

Publication Date June 22, 2016
Published in Issue Year 2016

Cite

APA Adedokun, O., Titilope, K., & Awodugba, A. O. (2016). Review on Natural Dye-Sensitized Solar Cells (DSSCs). International Journal of Engineering Technologies IJET, 2(2), 34-41. https://doi.org/10.19072/ijet.96456
AMA Adedokun O, Titilope K, Awodugba AO. Review on Natural Dye-Sensitized Solar Cells (DSSCs). IJET. June 2016;2(2):34-41. doi:10.19072/ijet.96456
Chicago Adedokun, Oluwaseun, Kamil Titilope, and Ayodeji Oladiran Awodugba. “Review on Natural Dye-Sensitized Solar Cells (DSSCs)”. International Journal of Engineering Technologies IJET 2, no. 2 (June 2016): 34-41. https://doi.org/10.19072/ijet.96456.
EndNote Adedokun O, Titilope K, Awodugba AO (June 1, 2016) Review on Natural Dye-Sensitized Solar Cells (DSSCs). International Journal of Engineering Technologies IJET 2 2 34–41.
IEEE O. Adedokun, K. Titilope, and A. O. Awodugba, “Review on Natural Dye-Sensitized Solar Cells (DSSCs)”, IJET, vol. 2, no. 2, pp. 34–41, 2016, doi: 10.19072/ijet.96456.
ISNAD Adedokun, Oluwaseun et al. “Review on Natural Dye-Sensitized Solar Cells (DSSCs)”. International Journal of Engineering Technologies IJET 2/2 (June 2016), 34-41. https://doi.org/10.19072/ijet.96456.
JAMA Adedokun O, Titilope K, Awodugba AO. Review on Natural Dye-Sensitized Solar Cells (DSSCs). IJET. 2016;2:34–41.
MLA Adedokun, Oluwaseun et al. “Review on Natural Dye-Sensitized Solar Cells (DSSCs)”. International Journal of Engineering Technologies IJET, vol. 2, no. 2, 2016, pp. 34-41, doi:10.19072/ijet.96456.
Vancouver Adedokun O, Titilope K, Awodugba AO. Review on Natural Dye-Sensitized Solar Cells (DSSCs). IJET. 2016;2(2):34-41.

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