Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties

Hatice Varol Özkavak; Hatice Asıl Uğurlu

doi:10.46460/ijiea.1070575

TR EN

AISI 304 Paslanmaz Çeliğin Spin Yöntemi Kullanılarak TiO2 Filmi İle Kaplanması ve Yapısal Özelliklerinin Araştırılması

Öz

Bu çalışmada iyi pasiflik, düşük iletkenlik ve iyi tribolojik özelliklere sahip TiO2 seramik oksit filmi sol jel spin kaplama yöntemi ile paslanmaz çelik (AISI 304) malzemesi kaplanmıştır. Kaplanan TiO2 filmlerin yapısına tavlama sıcaklığı ve süresinin etkisi incelenmiştir. Kaplama işlemi için Ethyl acetoacetate (EAcAc), etanol ve titanium kaynağı olarak Tetra-n-butyl orthotitanate (TBT) kullanılmıştır. TiO2 ince film kaplama işleminde spin döndürme hızı olarak 2600 devir/dakika seçilmiştir. Tavlama süresinin ve sıcaklığının kaplama yapısına etkisini incelemek amacıyla 1 ve 1,5 saat işlem sürelerinde ve 500 °C, 600 °C, 700 °C işlem sıcaklıklarında tavlama uygulanmıştır. Yapılan kaplamaların yapısal özellikleri XRD ve SEM analizleri ile incelenmiştir. Yapılan analizlere göre elde edilen piklerin anataz ve rutile fazında olduğu belirlenmiştir. XRD sonuçları incelendiğinde bütün sıcaklıklarda ve sürelerde baskın pikin Rutile (210) fazı olduğu görülmüştür. Ayrıca XRD analizlerinden R(210) fazı için kristal boyutu (D), dislokasyon yoğunluğu (δ) ve gerinim (ε) gibi parametreler belirlenmiştir. Çalışma sonrasında tavlama sıcaklığının ve süresinin yüzey morfolojisini değiştirdiği SEM analizleri belirlenmiştir.

Anahtar Kelimeler

İnce Film , Spin Kaplama , Tavlama sıcaklığı , Tavlama süresi , TiO2.

Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties

Abstract

In this study, TiO2 ceramic oxide film with good passivity, low conductivity and good tribological properties was coated on stainless steel (AISI 304) material by sol gel spin coating method. The effect of annealing temperature and time on the structure of the coated TiO2 films was investigated. Ethyl acetoacetate (EAcAc), ethanol and as titanium source Tetra-n-butyl orthotitanate (TBT) was used for the coating process. In the TiO2 thin film coating process, 2600 rpm was chosen as the spin rotation speed. In order to examine the effect of annealing time and temperature on the coating structure, annealing was applied at treatment times of 1 and 1.5 hours and at processing temperatures of 500 °C, 600 °C, 700 °C. The structural properties of the coatings were investigated by XRD and SEM analysis. It was determined that the peaks obtained according to the analyzes were in the anatase and rutile phases. When the XRD results were examined, it was seen that the dominant peak was the Rutile (210) phase at all temperatures and times. In addition, parameters such as crystal size (D), dislocation density (δ) and strain (ε) were determined for the R(210) phase from XRD analysis. After the study, SEM analyzes were determined that the annealing temperature and time changed the surface morphology.

Keywords

Annealing temperature , Annealing time , Spin Coating , Thin Films , TiO2.

References

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Hatice Varol Özkavak ^*
0000-0002-0314-0119
Türkiye

Hatice Asıl Uğurlu
0000-0002-1114-3627
Türkiye

Publication Date

June 28, 2022

Submission Date

February 9, 2022

Acceptance Date

May 9, 2022

Published in Issue

Year 2022 Volume: 6 Number: 1

DOI

https://doi.org/10.46460/ijiea.1070575

IZ

https://izlik.org/JA98UA39ZY

APA

Varol Özkavak, H., & Asıl Uğurlu, H. (2022). Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties. International Journal of Innovative Engineering Applications, 6(1), 97-102. https://doi.org/10.46460/ijiea.1070575

AMA

1.Varol Özkavak H, Asıl Uğurlu H. Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties. IJIEA. 2022;6(1):97-102. doi:10.46460/ijiea.1070575

Chicago

Varol Özkavak, Hatice, and Hatice Asıl Uğurlu. 2022. “Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties”. International Journal of Innovative Engineering Applications 6 (1): 97-102. https://doi.org/10.46460/ijiea.1070575.

EndNote

Varol Özkavak H, Asıl Uğurlu H (June 1, 2022) Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties. International Journal of Innovative Engineering Applications 6 1 97–102.

IEEE

[1]H. Varol Özkavak and H. Asıl Uğurlu, “Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties”, IJIEA, vol. 6, no. 1, pp. 97–102, June 2022, doi: 10.46460/ijiea.1070575.

ISNAD

Varol Özkavak, Hatice - Asıl Uğurlu, Hatice. “Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties”. International Journal of Innovative Engineering Applications 6/1 (June 1, 2022): 97-102. https://doi.org/10.46460/ijiea.1070575.

JAMA

1.Varol Özkavak H, Asıl Uğurlu H. Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties. IJIEA. 2022;6:97–102.

MLA

Varol Özkavak, Hatice, and Hatice Asıl Uğurlu. “Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties”. International Journal of Innovative Engineering Applications, vol. 6, no. 1, June 2022, pp. 97-102, doi:10.46460/ijiea.1070575.

Vancouver

1.Hatice Varol Özkavak, Hatice Asıl Uğurlu. Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties. IJIEA. 2022 Jun. 1;6(1):97-102. doi:10.46460/ijiea.1070575

This work is licensed under CC BY-NC 4.0

AISI 304 Paslanmaz Çeliğin Spin Yöntemi Kullanılarak TiO2 Filmi İle Kaplanması ve Yapısal Özelliklerinin Araştırılması

Öz

Anahtar Kelimeler

Coating TiO2 Film Using the Spin Method of AISI 304 Stainless Steel and Investigation of the Structural Properties

Abstract

Keywords

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

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