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Mikrodalga Yöntemi ile BaTiO3'ün Sentezi ve PANI/BaTiO3 Nanokompozitinin Yüksek Performanslı Boya Duyarlı Güneş Hücresinde Karşıt Elektrod Olarak Uygulaması

Year 2021, , 156 - 161, 31.12.2021

Recep Taş , Mahir Gülen

https://doi.org/10.46460/ijiea.929966

Abstract

DSSC mimarisinin gelişimi, potansiyel olarak daha düşük maliyetlerle fotovoltaik sistemler üretmek için heyecan verici yeni olanaklara ve fotovoltaik (PV) sistemlere kapı açmıştır. Bu nedenle, DSSC'ler hem enerji alanında hem de PV endüstrisinde çalışan araştırmacıların dikkatini çekmektedir. Düşük malzeme maliyetleri, kolay ve ucuz üretim süreçleri ve makul dönüşüm verimliliği nedeniyle BDGH'ler, diğer geleneksel güneş pillerine bir alternatif olarak kabul edilir. Bu çalışmada, BaTiO3 nanopartikülleri mikrodalga yöntemi kullanılarak hızlı ve düşük maliyetle üretildi. Elde edilen BaTiO3 kullanılarak, PANI / BaTiO3 nanokompozitleri başarıyla üretildi ve boyaya duyarlı güneş pillerinde (DSSC) karşı elektrot olarak kullanılabilirlikleri araştırıldı. Üretilen polimer ve nanokompozit filmler FT-IR, UV, SEM, CV ve elektrokimyasal empedans (EIS) ölçümleriyle karakterize edildi. Üretilen nanokompozitlerin fotovoltaik potansiyellerini karakterize etmek için DSSC'lerde karşı elektrot olarak kullanıldı. Fotovolaik analizde, nanokompozit DSSC'lerin dönüşüm verimliliği, polimer karşı elektrot hücrelerine kıyasla% 39 artmıştır. Sonuç olarak, üretilen nanokompozitlerin hem maliyet hem dayanıklılık hem de fotovoltaik performans açısından pahalı ve stokları sınırlı olan Pt yerine DSSC'lerde kullanılabileceği tespit edilmiştir.

Keywords

Polianilin BaTiO3 Mikrodalga Metodu Kompozit Boya Duyarlı Güneş hücresi

Supporting Institution

Bartın Üniversitesi

References

  • Biswas S, Mondal A, Mukherjee D, Pramanik P (1986). A Chemical Method for the Deposition of Bismuth Sulfide Thin-Films. J Electrochem Soc 133:48-52
  • Bousalem S, Zeggai FZ, Baltach H, Benyoucef A (2020). Physical and electrochemical investigations on hybrid materials synthesized by polyaniline with various amounts of ZnO nanoparticle. Chemical Physics Letters 741
  • Henshaw G, Parkin IP, Shaw G (1996). Convenient, low-energy synthesis of metal sulfides and selenides; PbE, Ag(2)E, ZnE, CdE (E=S, Se). Chem Commun 1095-1096
  • Jangid NK, Jadoun S, Kaur N (2020). A review on high-throughput synthesis, deposition of thin films and properties of polyaniline. Eur Polym J 125
  • Kim YH, Kim M, Oh S, Jung H, Kim Y, Yoon TS, Kim YS, Lee HH (2012). Organic memory device with polyaniline nanoparticles embedded as charging elements. Appl Phys Lett 100:
  • Luo FL, Li J, Yuan HY, Xiao D (2014). Rapid synthesis of three-dimensional flower-like cobalt sulfide hierarchitectures by microwave assisted heating method for high-performance supercapacitors. Electrochim Acta 123:183-189
  • Maison W, Kleeberg R, Heimann RB, Phanichphant S (2003). Phase content, tetragonality, and crystallite size of nanoscaled barium titanate synthesized by the catecholate process: effect of calcination temperature. J Eur Ceram Soc 23:127-132
  • Mangal S, Adhikari S, Banerji P (2009). Aluminum/polyaniline/GaAs metal-insulator-semiconductor solar cell: Effect of tunneling on device performance. Appl Phys Lett 94:
  • Matteazzi P, Lecaer G (1992). Mechanically Activated Room-Temperature Reduction of Sulfides. Mat Sci Eng a-Struct 156:229-237
  • Qiu LB, Jiang Y, Sun XM, Liu XK, Peng HS (2014). Surface-nanostructured cactus-like carbon microspheres for efficient photovoltaic devices. J Mater Chem A 2:15132-15138
  • Routkevitch D, Bigioni T, Moskovits M, Xu JM (1996). Electrochemical fabrication of CdS nanowire arrays in porous anodic aluminum oxide templates. J Phys Chem-Us 100:14037-14047
  • Sengupta LC, Sengupta S (1997). Novel ferroelectric materials for phased array antennas. Ieee T Ultrason Ferr 44:792-797
  • Sengupta LC, Stowell S, Ngo E, ODay ME, Lancto R (1995). Barium strontium titanate and non-ferroelectric oxide ceramic composites for use in phased array antennas. Integr Ferroelectr 8:77-88
  • Sonmezoglu S, Akyurek C, Akin S (2012). High-efficiency dye-sensitized solar cells using ferrocene-based electrolytes and natural photosensitizers. J Phys D Appl Phys 45:
  • Sonmezoglu S, Tas R, Akin S, Can M (2012). Polyaniline micro-rods based heterojunction solar cell: Structural and photovoltaic properties. Appl Phys Lett 101:
  • Tas R, Can M, Sonmezoglu S (2015). Preparation and characterization of polyaniline microrods synthesized by using dodecylbenzene sulfonic acid and periodic acid. Turk J Chem 39:589-599
  • Tas R, Gulen M, Can M, Sonmezoglu S (2016). Effects of solvent and copper-doping on polyaniline conducting polymer and its application as a counter electrode for efficient and cost-effective dye-sensitized solar cells. Synthetic Met 212:75-83
  • Verma AK, Rauchfuss TB (1995). Chalcogenospecific Synthesis of 1,2-Se2s6 Using Zns6(Tmeda). Inorg Chem 34:6199-&
  • Wang KL, Zhang QB, Sun ML, Wei XG, Zhu YM (2001). Rare earth elements modification of laser-clad nickel-based alloy coatings. Appl Surf Sci 174:191-200
  • Wei W, Wang H, Hu YH (2014). A review on PEDOT-based counter electrodes for dye-sensitized solar cells. Int J Energ Res 38:1099-1111
  • Wu JH, Yue GT, Xiao YM, Huang ML, Lin JM, Fan LQ, Lan Z, Lin JY (2012). Glucose Aided Preparation of Tungsten Sulfide/Multi-Wall Carbon Nanotube Hybrid and Use as Counter Electrode in Dye-Sensitized Solar Cells. Acs Appl Mater Inter 4:6530-6536
  • Xia JB, Chen L, Yanagida S (2011). Application of polypyrrole as a counter electrode for a dye-sensitized solar cell. J Mater Chem 21:4644-4649
  • Xiao S, Li XP, Sun WW, Guan BQ, Wang Y (2016). General and facile synthesis of metal sulfide nanostructures: In situ microwave synthesis and application as binder-free cathode for Li-ion batteries. Chemical Engineering Journal 306:251-259
  • Yu SH, Qian YT, Shu L, Xie Y, Yang L, Wang CS (1998). Solvent thermal synthesis and characterization of ultrafine powder of bismuth sulfide. Mater Lett 35:116-119
  • Yu SH, Yang J, Wu YS, Han ZH, Xie Y, Qian YT (1998). Hydrothermal preparation and characterization of rod-like ultrafine powders of bismuth sulfide. Mater Res Bull 33:1661-1666
  • Zhang XL, Liu JH, Li SM, Tan XH, Zhang JD, Yu M, Zhao MG (2013). DNA assembled single-walled carbon nanotube nanocomposites for high efficiency dye-sensitized solar cells. J Mater Chem A 1:11070-11077
  • Zheng XJ, Deng J, Wang N, Deng DH, Zhang WH, Bao XH, Li C (2014). Podlike N-Doped Carbon Nanotubes Encapsulating FeNi Alloy Nanoparticles: High-Performance Counter Electrode Materials for Dye-Sensitized Solar Cells. Angewandte Chemie-International Edition 53:7023-7027
  • Zhu JJ, Liu SW, Palchik O, Koltypin Y, Gedanken A (2000). A novel sonochemical method for the preparation of nanophasic sulfides: Synthesis of HgS and PbS nanoparticles. Journal of Solid State Chemistry 153:342-348

Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell

Year 2021, , 156 - 161, 31.12.2021

Recep Taş , Mahir Gülen

https://doi.org/10.46460/ijiea.929966

Abstract

Boya duyarlı Güneş Pili (DSSC) mimarisinin geliştirilmesi, potansiyel olarak daha düşük maliyetlerle elektrik üretmek için heyecan verici yeni olanaklara ve fotovoltaik (PV) sistemlere kapı açmıştır. Bu nedenle, DSSC'ler hem enerji alanında hem de PV endüstrisinde çalışan araştırmacıların dikkatini çekmektedir. Düşük malzeme maliyetleri, kolay ve ucuz üretim süreçleri ve makul dönüşüm verimliliği nedeniyle, DSSC'ler diğer geleneksel güneş pillerine bir alternatif olarak kabul edilir. Bu çalışmada, BaTiO3 nanopartikülleri mikrodalga yöntemi kullanılarak hızlı ve düşük maliyetle üretildi. Elde edilen BaTiO3 kullanılarak Polianilin (PANI) / BaTiO3 nanokompozitler başarıyla hassaslaştırıldı ve DSSC'de karşı elektrot olarak kullanılabilirlikleri araştırıldı. Kaplanmış PANI ve nanokompozit filmler, Fourier-transform kızılötesi spektroskopi (FT-IR), X-ışını difraktometrisi (XRD), taramalı elektron mikroskobu (SEM), Döngüsel Voltametri (CV) ve Elektrokimyasal Empedans Spektroskopisi (EIS) ölçümleriyle karakterize edildi. Elde edilen nanokompozit filmlerin fotovoltaik potansiyellerini karakterize etmek için DSSC mimarisinde bir karşı elektrot (CE) olarak kullanıldı. Fotovoltaik analizde, nanokompozit CE kullanan DSSC'nin dönüşüm verimliliği, saf PANI CE kullanan hücrelere kıyasla% 39 artmıştır. Sonuç olarak, sentezlenen nanokompozitlerin hem maliyet hem dayanıklılık hem de fotovoltaik performans açısından pahalı ve stokları sınırlı olan Pt yerine DSSC'lerde CE olarak kullanılabileceği tespit edilmiştir.

Keywords

Polyaniline BaTiO3 Microwave Method Composite Dye Sensitive Solar Cell

References

  • Biswas S, Mondal A, Mukherjee D, Pramanik P (1986). A Chemical Method for the Deposition of Bismuth Sulfide Thin-Films. J Electrochem Soc 133:48-52
  • Bousalem S, Zeggai FZ, Baltach H, Benyoucef A (2020). Physical and electrochemical investigations on hybrid materials synthesized by polyaniline with various amounts of ZnO nanoparticle. Chemical Physics Letters 741
  • Henshaw G, Parkin IP, Shaw G (1996). Convenient, low-energy synthesis of metal sulfides and selenides; PbE, Ag(2)E, ZnE, CdE (E=S, Se). Chem Commun 1095-1096
  • Jangid NK, Jadoun S, Kaur N (2020). A review on high-throughput synthesis, deposition of thin films and properties of polyaniline. Eur Polym J 125
  • Kim YH, Kim M, Oh S, Jung H, Kim Y, Yoon TS, Kim YS, Lee HH (2012). Organic memory device with polyaniline nanoparticles embedded as charging elements. Appl Phys Lett 100:
  • Luo FL, Li J, Yuan HY, Xiao D (2014). Rapid synthesis of three-dimensional flower-like cobalt sulfide hierarchitectures by microwave assisted heating method for high-performance supercapacitors. Electrochim Acta 123:183-189
  • Maison W, Kleeberg R, Heimann RB, Phanichphant S (2003). Phase content, tetragonality, and crystallite size of nanoscaled barium titanate synthesized by the catecholate process: effect of calcination temperature. J Eur Ceram Soc 23:127-132
  • Mangal S, Adhikari S, Banerji P (2009). Aluminum/polyaniline/GaAs metal-insulator-semiconductor solar cell: Effect of tunneling on device performance. Appl Phys Lett 94:
  • Matteazzi P, Lecaer G (1992). Mechanically Activated Room-Temperature Reduction of Sulfides. Mat Sci Eng a-Struct 156:229-237
  • Qiu LB, Jiang Y, Sun XM, Liu XK, Peng HS (2014). Surface-nanostructured cactus-like carbon microspheres for efficient photovoltaic devices. J Mater Chem A 2:15132-15138
  • Routkevitch D, Bigioni T, Moskovits M, Xu JM (1996). Electrochemical fabrication of CdS nanowire arrays in porous anodic aluminum oxide templates. J Phys Chem-Us 100:14037-14047
  • Sengupta LC, Sengupta S (1997). Novel ferroelectric materials for phased array antennas. Ieee T Ultrason Ferr 44:792-797
  • Sengupta LC, Stowell S, Ngo E, ODay ME, Lancto R (1995). Barium strontium titanate and non-ferroelectric oxide ceramic composites for use in phased array antennas. Integr Ferroelectr 8:77-88
  • Sonmezoglu S, Akyurek C, Akin S (2012). High-efficiency dye-sensitized solar cells using ferrocene-based electrolytes and natural photosensitizers. J Phys D Appl Phys 45:
  • Sonmezoglu S, Tas R, Akin S, Can M (2012). Polyaniline micro-rods based heterojunction solar cell: Structural and photovoltaic properties. Appl Phys Lett 101:
  • Tas R, Can M, Sonmezoglu S (2015). Preparation and characterization of polyaniline microrods synthesized by using dodecylbenzene sulfonic acid and periodic acid. Turk J Chem 39:589-599
  • Tas R, Gulen M, Can M, Sonmezoglu S (2016). Effects of solvent and copper-doping on polyaniline conducting polymer and its application as a counter electrode for efficient and cost-effective dye-sensitized solar cells. Synthetic Met 212:75-83
  • Verma AK, Rauchfuss TB (1995). Chalcogenospecific Synthesis of 1,2-Se2s6 Using Zns6(Tmeda). Inorg Chem 34:6199-&
  • Wang KL, Zhang QB, Sun ML, Wei XG, Zhu YM (2001). Rare earth elements modification of laser-clad nickel-based alloy coatings. Appl Surf Sci 174:191-200
  • Wei W, Wang H, Hu YH (2014). A review on PEDOT-based counter electrodes for dye-sensitized solar cells. Int J Energ Res 38:1099-1111
  • Wu JH, Yue GT, Xiao YM, Huang ML, Lin JM, Fan LQ, Lan Z, Lin JY (2012). Glucose Aided Preparation of Tungsten Sulfide/Multi-Wall Carbon Nanotube Hybrid and Use as Counter Electrode in Dye-Sensitized Solar Cells. Acs Appl Mater Inter 4:6530-6536
  • Xia JB, Chen L, Yanagida S (2011). Application of polypyrrole as a counter electrode for a dye-sensitized solar cell. J Mater Chem 21:4644-4649
  • Xiao S, Li XP, Sun WW, Guan BQ, Wang Y (2016). General and facile synthesis of metal sulfide nanostructures: In situ microwave synthesis and application as binder-free cathode for Li-ion batteries. Chemical Engineering Journal 306:251-259
  • Yu SH, Qian YT, Shu L, Xie Y, Yang L, Wang CS (1998). Solvent thermal synthesis and characterization of ultrafine powder of bismuth sulfide. Mater Lett 35:116-119
  • Yu SH, Yang J, Wu YS, Han ZH, Xie Y, Qian YT (1998). Hydrothermal preparation and characterization of rod-like ultrafine powders of bismuth sulfide. Mater Res Bull 33:1661-1666
  • Zhang XL, Liu JH, Li SM, Tan XH, Zhang JD, Yu M, Zhao MG (2013). DNA assembled single-walled carbon nanotube nanocomposites for high efficiency dye-sensitized solar cells. J Mater Chem A 1:11070-11077
  • Zheng XJ, Deng J, Wang N, Deng DH, Zhang WH, Bao XH, Li C (2014). Podlike N-Doped Carbon Nanotubes Encapsulating FeNi Alloy Nanoparticles: High-Performance Counter Electrode Materials for Dye-Sensitized Solar Cells. Angewandte Chemie-International Edition 53:7023-7027
  • Zhu JJ, Liu SW, Palchik O, Koltypin Y, Gedanken A (2000). A novel sonochemical method for the preparation of nanophasic sulfides: Synthesis of HgS and PbS nanoparticles. Journal of Solid State Chemistry 153:342-348
There are 28 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Recep Taş 0000-0002-3743-7770

Mahir Gülen 0000-0002-6001-8494

Publication Date December 31, 2021
Submission Date April 30, 2021
Published in Issue Year 2021

Cite

APA Taş, R., & Gülen, M. (2021). Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell. International Journal of Innovative Engineering Applications, 5(2), 156-161. https://doi.org/10.46460/ijiea.929966
AMA Taş R, Gülen M. Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell. ijiea, IJIEA. December 2021;5(2):156-161. doi:10.46460/ijiea.929966
Chicago Taş, Recep, and Mahir Gülen. “Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite As Counter Electrode in High Performance Dye Sensitized Solar Cell”. International Journal of Innovative Engineering Applications 5, no. 2 (December 2021): 156-61. https://doi.org/10.46460/ijiea.929966.
EndNote Taş R, Gülen M (December 1, 2021) Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell. International Journal of Innovative Engineering Applications 5 2 156–161.
IEEE R. Taş and M. Gülen, “Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell”, ijiea, IJIEA, vol. 5, no. 2, pp. 156–161, 2021, doi: 10.46460/ijiea.929966.
ISNAD Taş, Recep - Gülen, Mahir. “Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite As Counter Electrode in High Performance Dye Sensitized Solar Cell”. International Journal of Innovative Engineering Applications 5/2 (December 2021), 156-161. https://doi.org/10.46460/ijiea.929966.
JAMA Taş R, Gülen M. Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell. ijiea, IJIEA. 2021;5:156–161.
MLA Taş, Recep and Mahir Gülen. “Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite As Counter Electrode in High Performance Dye Sensitized Solar Cell”. International Journal of Innovative Engineering Applications, vol. 5, no. 2, 2021, pp. 156-61, doi:10.46460/ijiea.929966.
Vancouver Taş R, Gülen M. Synthesis of BaTiO3 Via Microwave Method and Applicatıon of PANI/BaTiO3 Nanocomposite as Counter Electrode in High Performance Dye Sensitized Solar Cell. ijiea, IJIEA. 2021;5(2):156-61.