Removal of Chrysoidine Y from Aqueous Solutions by Agricultural Waste Material

Abstract

The aim of this study was to search the adsorption of Chrysoidine Y azo dye onto pistachio shell as an adsorbent. The influence on the sorption of contact time, pH, particle size, initial dye concentration and adsorbent dosage, ionic strength, as well as the efficiency of the regeneration and reuse of adsorbent have been searched. The maximum sorption was found at -0.212 to +0.106 mm, at pH 5, at 2.5 hours contact time, at 1.0-1.25 g/100 mL adsorbent dosage. The adsorption kinetic studies revealed that the pseudo-second-order model provided the best correlation, and the rate-limiting step might be chemical sorption. And the Freundlich isotherm was feasible to identify the adsorption process. Pistachio shell demonstrated a well performance for the removal of Chrysoidine Y from aqueous solution with an adsorption capacity of 79.37 mg/g. It was observed that the adsorbent material could be regenerated with 1.2 M CH3COOH in 43% yield. After regeneration, it was determined that adsorbent can be used for a few more repetitions without losing much efficiency. This work shows that pistachio shell can be used as a favorable and effective adsorbent for the removal of Chrysoidine Y azo dye from aqueous solution.

Keywords

• adsorption
• Chrysoidine Y
• agricultural waste
• kinetic
• isoterms

Tarımsal Atık Materyal Kullanılarak Sucul Çözeltiden Chrysoidine Y Boyasının Giderimi

Abstract

Bu çalışmanın amacı, adsorbent olarak Antep fıstığı kabuğu kullanılarak Chrysoidine Y azo boyasının adsorpsiyonunu araştırmaktır. Temas süresi, pH, partikül boyutu, başlangıç boya ve adsorbent dozajı, iyonik yükün sorpsiyona etkisi ve ayrıca adsorbentin rejenerasyon ve yeniden kullanım verimliliği araştırılmıştır. Maksimum sorpsiyon -0,212 +0,106 mm partikül boyutu, pH 5, 2,5 saat denge süresi ve 1,0-1,25 g/100 mL adsorbent dozajında elde edilmiştir. Adsorpsiyon kinetik çalışmaları verilerin yalancı ikinci derece kinetik modelle en iyi korelasyonu sağladığını, bu durumda kimyasal sorpsiyonun hız sınırlayıcı aşama olabileceği belirlenmiştir. Korelasyon katsayılarına göre adsorpsiyon prosesinin Freundlich izotermine daha çok uyduğu görülmektedir. Fıstık kabukları 79,37 mg/g adsorpsiyon kapasitesi ile sucul çözeltiden Chrysoidine Y’nin giderimi için iyi bir performans göstermiştir. Adsorbent materyalin 1,2 molar CH3COOH ile %43 verimle rejenere edilebildiği, rejenerasyondan sonra verimde çok fazla kayıp olmaksızın birkaç tekrar şeklinde adsorbentin yeniden kullanılabileceği belirlenmiştir. Bu çalışma sonuçları sucul çözeltiden Chrysoidine Y azo boyasının gideriminde verimli ve uygun bir adsorbent olarak fıstık kabuklarının kullanılabileceğini göstermiştir.

Keywords

• Adsorpsiyon
• Chrysoidine Y
• tarımsal atık
• kinetik
• izoterm

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