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Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment

Year 2013, Volume: 3 Issue: 2, 364 - 371, 01.06.2013

Abstract

A comparative study of enrichment of crude glycerol via solvent extraction and adsorption was performed at a laboratory scale at ambient temperature (30 oC). Effect of various parameters on the properties of the obtained glycerol including glycerol-, ash- and contaminant contents and color, was explored. The results showed that the enrichment of glycerol by solvent extraction was significantly affected by the solvent type and ratio of solvent to pre-treated crude glycerol. The use of n-C3H7OH at a ratio of 2.0 gave the highest purity of glycerol, but the lowest color reduction. The use of C4H10O at a ratio of 1.0 gave a low glycerol content but the highest color removal. On the other hand, adsorption with activated carbon gave poor glycerol purity of 70.3 wt.% but it could decrease the color by more than 97.1%. The combined process of extraction with n-C3H7OH at a ratio of 2.0 followed by activated carbon adsorption gave the highest glycerol purity with color removal to a clear solution. The cost analysis of crude glycerol enrichment by the combined approach was also explored.

References

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  • K.C. Yong, T.L. Ooi, K. Dzulkefly, W.M.Z. Wan Yunus, A.H. Hazimah, “Refining of crude glycerine recovered from glyceol residue by simple vacuum distillation”, J. Oil Palm Res., vol. 13, pp. 39-44, December 2001.
Year 2013, Volume: 3 Issue: 2, 364 - 371, 01.06.2013

Abstract

References

  • M. Grayson, Kirk-Othmer encyclopedia of chemical technology, 3rd ed, vol. 11, New York, John Wiley, , pp. 921-922. Z. Wang, J. Zhuge, H. Fang, B.A. Prior, “Glycerol production by microbial fermentation: A review”, Biotechnol. Adv., vol. 19, pp. 201-223, June 2001.
  • M.J. Taherzadeh, L. Adler, G. Lidén, “Strategies for enhancing fermentative production of glycerol -a review”, Enzyme Microb. Technol., vol. 31, pp. 53-56, July 2002.
  • M. Hájek, F. Skopal, “Treatment of glycerol phase formed by biodiesel production”, Biores. Technol., vol. , pp. 3242-3245, May 2010.
  • M. Ayoub, A.Z. Abdullah, “Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry”, Renew. Sustain. Energ. Rev., vol. 16, pp. 2671 2686, June 2012.
  • Ministry of Thailand. http://www.dede.go.th/dede/ index.php?option=com_content&view=article&id=898&I temid=123&lang=th, Access date: 28 March 2013.
  • N. Rahmat, A.Z. Abdullah, A.R. Mohamed, “Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review”, Renew. Sustain. Energy Rev., vol. 14, pp. 987- , April 2010.
  • T.L. Ooi, K.L. Yong, K. Dzulkefly, W.M.Z. Wan Yunus, A.H. Hazimah, “Crude glycerine recovery from glycerol residue waste from a palmkernel oilmethyl ester plants”, J. Oil Palm Res., vol. 13, pp. 16-22, December 2001.
  • Lancrenon X, Fedders J, “An Innovation in Glycerin Purification”, articles/2388/an-innovation-in-glycerin-purification.
  • Biodiesel Magazine, May 2008. Access date: 28 March
  • F. Schaffner, P.Y. Pontalier, V. Sanchez, F. Lutin, “Bipolar electrodialysis for glycerin production from diester wastes”, Filtra. Separ., vol. 40, pp. 35-39, December 2003.
  • M. Carmona, J. Valverde, A. Prez, “PuriŞcation of glycerol/water solutions from biodiesel synthesis by ion exchange: sodium removal Part I”, J. Chem. Techno. Biotechnol., vol. 84, pp. 738-744, May 2009.
  • M. Carmona, A. Lech, A. de Lucas, A. Perez, J.F. Rodriguez, “PuriŞcation of glycerol/water solutions from biodiesel synthesis by ion exchange: sodium and chloride removal Part II”, J. Chem. Techno. Biotechnol., vol. 84, pp. 1130-1135, August 2009.
  • W.N.R.W. Isahak, M. Ismail, M.A. Yarmo, J.M. Jahim, J. Salimon, “Purification of crude glycerol from transesterification RBD palm oil over homogeneous and heterogeneous catalysts for the biolubricant preparation” J. Appl. Sci., vol. 10, pp. 2590-2595, November 2010.
  • S. Kongjao, S. Damronglerd, M. Hunsom, “PuriŞcation of crude glycerol derived from waste used- oil methyl ester plant”, Korean J. Chem. Eng., vol. 27, pp. 944-949, May 2010.
  • A. Javani, M. Hasheminejad, K. Tahvildari, M. Tabatabaei, “High quality potassium phosphate production through step-by-step glycerol enrichment: A strategy to economize biodiesel production”, Biores. Technol., vol. 104, pp. 788-790, January 2012.
  • R. Manosak, S. Limpattayanate, M. Hunsom. Sequential-refining of crude glycerol derived from waste used-oil methyl ester plant via a combined process of chemical and adsorption. Fuel Process. Technol., vol. 92, pp. 92-99, January 2010.
  • D.T. Johnson, K.A. Taconi, “The glycerin glut: options for the value-added conversion of crude glycerol resulting from biodiesel production”, Eng. Prog., vol. 26, pp. 338-343, October 2007.
  • J.A. Byers, “Solvent polarity and miscibility”, Available java/solvents.htm, Access date 28 March 2003. (Report)
  • F.L. Burton, H.D. Stensel, Wastewater engineering : treatment and reuse / Metcalf & Eddy, Inc, Revised by G. Tchobanoglous, 4th ed, Boston: McGraw-Hill, 2003, pp. I.A.W Tan, A.L. Ahmad, B.H. Hameed,
  • “Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies”, J. Hazard. Mater., vol. 154, pp. 337-346, June 2008.
  • K.C. Yong, T.L. Ooi, K. Dzulkefly, W.M.Z. Wan Yunus, A.H. Hazimah, “Refining of crude glycerine recovered from glyceol residue by simple vacuum distillation”, J. Oil Palm Res., vol. 13, pp. 39-44, December 2001.
There are 21 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Mali Hunsom This is me

Payia Saila This is me

Penpisuth Chaiyakam This is me

Winata Kositnan This is me

Publication Date June 1, 2013
Published in Issue Year 2013 Volume: 3 Issue: 2

Cite

APA Hunsom, M., Saila, P., Chaiyakam, P., Kositnan, W. (2013). Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment. International Journal Of Renewable Energy Research, 3(2), 364-371.
AMA Hunsom M, Saila P, Chaiyakam P, Kositnan W. Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment. International Journal Of Renewable Energy Research. June 2013;3(2):364-371.
Chicago Hunsom, Mali, Payia Saila, Penpisuth Chaiyakam, and Winata Kositnan. “Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment”. International Journal Of Renewable Energy Research 3, no. 2 (June 2013): 364-71.
EndNote Hunsom M, Saila P, Chaiyakam P, Kositnan W (June 1, 2013) Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment. International Journal Of Renewable Energy Research 3 2 364–371.
IEEE M. Hunsom, P. Saila, P. Chaiyakam, and W. Kositnan, “Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment”, International Journal Of Renewable Energy Research, vol. 3, no. 2, pp. 364–371, 2013.
ISNAD Hunsom, Mali et al. “Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment”. International Journal Of Renewable Energy Research 3/2 (June 2013), 364-371.
JAMA Hunsom M, Saila P, Chaiyakam P, Kositnan W. Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment. International Journal Of Renewable Energy Research. 2013;3:364–371.
MLA Hunsom, Mali et al. “Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment”. International Journal Of Renewable Energy Research, vol. 3, no. 2, 2013, pp. 364-71.
Vancouver Hunsom M, Saila P, Chaiyakam P, Kositnan W. Comparison and Combination of Solvent Extraction and Adsorption for Crude Glycerol Enrichment. International Journal Of Renewable Energy Research. 2013;3(2):364-71.