Korozyon Önleyici Ajan Olarak Kolofan ve Türevleri

Year 2023, Volume: 5 Issue: 3, 231 - 236, 30.12.2023

Ahsen Ezel Bildik Dal , Mehmet Güle

https://doi.org/10.53472/jenas.1382148

Abstract

Kolofon, başta Çam türleri olmak üzere çeşitli kaynaklardan elde edilmektedir. Kolofonın baskın bileşenleri reçine asitleridir ve abietik asit birincil reçine asidini oluşturur. Korozif ortamlarda metalik yüzey korozyonu ve alaşım çözünmesini önleyici ajan olarak kolofon ve türevleri irdelenmektedir. Korozyon inhibitörü olarak kolofon türevlerinin yeni bir yaklaşım ve temel kimyasal reaksiyonları olarak verilmiştir. Toksisite araştırmaları, kolofoninin ve türevlerinin neredeyse toksik olmayan bileşenler içerdiğini doğrulamaktadır. Böylece, kolofoninin endüstriyel uygulamalarda artan kullanımı güçlenmiştir.
Naval stores olarak da adlandırılan kolofoninin, gemilerin sızdırmazlık özelliklerini iyileştirme yeteneği iyi bilinen bir özelliktir. Petrol endüstrisinde kolofon türevleri, amfifilik doğalarından dolayı korozyon inhibitörlerine olan ilgiyi artırmaktadır. Kolofon türevleri, doğada çözünürlüğü arttırılmış, yenilenebilir bir hammaddedir. Ayrıca petrol bazlı malzemelerle karşılaştırıldığında uygun fiyatı ve düşük toksisitesi ile öne çıkmaktadır. Bu nedenle kolofon ve türevleri, kimyasal bazlı toksik korozyon inhibitörlerine kıyasla, spesifik kimyasal yapılara sahip ileri polimer uygulamalarının hammaddesi olarak dikkat çeken yeni bir yaklaşıma sahiptir. Kolofon ve türevinin deniz taşımacılığı gibi alanlarda su kirliliğine neden olmadığı da kritik bir noktadır.

Keywords

Reçine/Kolofoni, Rosin esteri, Korozyon kimyasalları, Tall Oil Kolofanı, Sakız Kolofanı

COLOPHONY and It’s Derivatives as Corrosion Inhibitor Agent

Abstract

Colophony obtained from oleoresin, toll oil and wood stump sources from the Pine species. The dominant components of colophony are resin acids and abietic acid forms the primary resin acid. Colophony and derivatives as inhibitor agent of metallic surface corrosion and alloy dissolution in corrosive environments reviewed. The novel approach and basic chemical reactions of the colophony derivatives as a corrosion inhibitor given in detailed. Toxicity research approved that colophony and derivatives practically non-toxic component. This evidence has strengthened the reason why colophony is the escalated attention of industrial applications.
Colophony is considered green oil because it is renewable, inexpensive, and environmentally friendly material. The ability of colophony, also named naval store, to improve the sealing properties of ships is well known feature. In the oil industry, colophony derivatives have rising interest of corrosion inhibitors thanks to their amphiphilic nature. Additionally, it could be utilized as petroleum dispersants. Colophony derivatives are renewable raw material which has enhanced solubility and ambient in nature. Besides, comparing to petroleum-based materials it has affordable price and low toxicity. Therefore, colophony and derivatives have advantageous as a unique raw material of advanced polymers applications compared to chemical based toxic corrosion inhibitors. A critical note that colophony and derivative does not causing water pollution in field such as maritime transportation.

Keywords

Rosin/Colophony, Rosin ester, Corrosion chemicals, Tall Oil Rosin, Gum Rosin

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