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Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları

Year 2019, Volume: 31 - Özel Sayı I:, 75 - 83, 20.05.2019
https://doi.org/10.7240/jeps.497405

Abstract

Metal
nanoparçacıkların sahip oldukları üstün optik, elektronik özeliklerinden dolayı
son yıllarda optoelektronik, kataliz, tıp, kimyasal/biyokimyasal sensörler gibi
alanlarda kullanımları yoğun olarak araştırılmaktadır. Bu çalışmada gümüş
nanoparçacıklar (AgNPs), tarçın, keçiboynuzu, zencefil ve zerdeçal antioksidan
özütleri kullanılarak başarıyla sentezlenmiştir. Sentezlenen antioksidan gümüş
nanoparçacıklar UV-VIS spektroskopisi, SEM-EDX ve FTIR ile karakterize edilmiştir.
Sentezlenen AgNPs’ler boyaların (Metil Oranj, Metilen Mavisi ve Rodamin B)
sodyum borhidrür (
NaBH4) ile indirgenmesinde
katalizör olarak uygulanmıştır. Bozunma reaksiyonları için kinetik parametreler
(k) hesaplanmış ve yaklaşık 6-10 dakika antioksidan gümüş nanoparçacıklarına
maruz kalmalarıyla boyaların etkili bir şekilde parçalanmasını sağlamıştır. 

References

  • 1) S. Navalona, A. Dhakshinamoorthy, M. Alvaroa, H. Garcia, “Metal nanoparticles supported on two-dimensional graphenes as heterogeneous catalysts”, Coord Chem Rev 312 (2016) 99–148.2) V.S. Suvith, D. Philip, “Catalytic degradation of methylene blue using biosynthesized gold and silver nanoparticles”, Spectrochim Acta A Mol Biomol Spectrosc 118 (2014) 526–532.3) S. Anandan, P. Satish Kumar, N. Pugazhenthiran, J. Madhavan, P. Maruthamuthu, “Effect of loaded silver nanoparticles on TiO2 for photocatalytic degradation of acid red 88”, Solar Energy Mater Solar Cells 92 (2008) 929–937.4) M.A. Khalilzadeh, M. Borzoo, “Green synthesis of silver nanoparticles using onion extract and their application for the preparation of a modified electrode for determination of ascorbic acid”, J Food and Drug Anal 24(4) (2016) 796–803.5) D. Wesenberg, I. Kyriakides, S.N. Aqathos, “White-rot fungi and their enzymes for the treatment of industrial dye effuents”, Biotechnology Adv 22(1–2) (2003) 161–187.6) Arumai, S. D., Mahendiran, D., Senthil, K. R., Kalilur, R. A., (2018). “Garlic, green tea and turmeric extracts-mediated green synthesis of silver nanoparticles: Phytochemical, antioxidant and in vitro cytotoxicity studies”, Journal of Photochemistry and Photobiology, B:180, 243-252.7) Firdaus, M., Andriana, S., Elvinawati, A. W., Swistoro, E., Ruyani, A., Sundaryono, A., (2017). “Green synthesis of silver nanoparticles using Carica Papaya fruit extract under sunlight irradiation and their colorimetric detection of mercury ions”, Journal of Physics: 012029/1.8) Mani, K., Ramasamy, S., Ganesan, A., Subbaiyan, R., (2017). “Evaluation of silver nanoparticles as a comparative study and determination of its effect on Vigna radiata”, International Research Journal of Pharmacy, 8(1), 33-40.9) Mekkawy, A. I., El-Mokhtar, M. A., Nafady, N. A., Yousef, N., Hamad, M. A., El-Shanawany, S. M., Ibrahim, E. H., Elsabahy, M., (2017). “In vitro and in vivo evaluation of biologically synthesized silver nanoparticles for topical applications: effect of surface coating and loading into hydrogels”, International Journal of Nanomedicine, 12, 759-777.10) Selvapriya, V., Deepa, C., (2017). “A novel, comparative study of chemical and green synthesis of silver nanoparticles”, Journal of Environmental Nanotechnology, 6(1), 23-26.11) Srirangam, G. M., Rao, K. P., (2017). “Synthesis and charcterization of silver nanoparticles from the leaf extract of Malachra capitata (L.)” , Journal of Chemistry, 10(1), 46-53.
Year 2019, Volume: 31 - Özel Sayı I:, 75 - 83, 20.05.2019
https://doi.org/10.7240/jeps.497405

Abstract

References

  • 1) S. Navalona, A. Dhakshinamoorthy, M. Alvaroa, H. Garcia, “Metal nanoparticles supported on two-dimensional graphenes as heterogeneous catalysts”, Coord Chem Rev 312 (2016) 99–148.2) V.S. Suvith, D. Philip, “Catalytic degradation of methylene blue using biosynthesized gold and silver nanoparticles”, Spectrochim Acta A Mol Biomol Spectrosc 118 (2014) 526–532.3) S. Anandan, P. Satish Kumar, N. Pugazhenthiran, J. Madhavan, P. Maruthamuthu, “Effect of loaded silver nanoparticles on TiO2 for photocatalytic degradation of acid red 88”, Solar Energy Mater Solar Cells 92 (2008) 929–937.4) M.A. Khalilzadeh, M. Borzoo, “Green synthesis of silver nanoparticles using onion extract and their application for the preparation of a modified electrode for determination of ascorbic acid”, J Food and Drug Anal 24(4) (2016) 796–803.5) D. Wesenberg, I. Kyriakides, S.N. Aqathos, “White-rot fungi and their enzymes for the treatment of industrial dye effuents”, Biotechnology Adv 22(1–2) (2003) 161–187.6) Arumai, S. D., Mahendiran, D., Senthil, K. R., Kalilur, R. A., (2018). “Garlic, green tea and turmeric extracts-mediated green synthesis of silver nanoparticles: Phytochemical, antioxidant and in vitro cytotoxicity studies”, Journal of Photochemistry and Photobiology, B:180, 243-252.7) Firdaus, M., Andriana, S., Elvinawati, A. W., Swistoro, E., Ruyani, A., Sundaryono, A., (2017). “Green synthesis of silver nanoparticles using Carica Papaya fruit extract under sunlight irradiation and their colorimetric detection of mercury ions”, Journal of Physics: 012029/1.8) Mani, K., Ramasamy, S., Ganesan, A., Subbaiyan, R., (2017). “Evaluation of silver nanoparticles as a comparative study and determination of its effect on Vigna radiata”, International Research Journal of Pharmacy, 8(1), 33-40.9) Mekkawy, A. I., El-Mokhtar, M. A., Nafady, N. A., Yousef, N., Hamad, M. A., El-Shanawany, S. M., Ibrahim, E. H., Elsabahy, M., (2017). “In vitro and in vivo evaluation of biologically synthesized silver nanoparticles for topical applications: effect of surface coating and loading into hydrogels”, International Journal of Nanomedicine, 12, 759-777.10) Selvapriya, V., Deepa, C., (2017). “A novel, comparative study of chemical and green synthesis of silver nanoparticles”, Journal of Environmental Nanotechnology, 6(1), 23-26.11) Srirangam, G. M., Rao, K. P., (2017). “Synthesis and charcterization of silver nanoparticles from the leaf extract of Malachra capitata (L.)” , Journal of Chemistry, 10(1), 46-53.
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Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Articles
Authors

Muradiye Şahin 0000-0002-5445-6682

Publication Date May 20, 2019
Published in Issue Year 2019 Volume: 31 - Özel Sayı I:

Cite

APA Şahin, M. (2019). Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları. International Journal of Advances in Engineering and Pure Sciences, 31, 75-83. https://doi.org/10.7240/jeps.497405
AMA Şahin M. Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları. JEPS. May 2019;31:75-83. doi:10.7240/jeps.497405
Chicago Şahin, Muradiye. “Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu Ve Kataliz Uygulamaları”. International Journal of Advances in Engineering and Pure Sciences 31, May (May 2019): 75-83. https://doi.org/10.7240/jeps.497405.
EndNote Şahin M (May 1, 2019) Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları. International Journal of Advances in Engineering and Pure Sciences 31 75–83.
IEEE M. Şahin, “Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları”, JEPS, vol. 31, pp. 75–83, 2019, doi: 10.7240/jeps.497405.
ISNAD Şahin, Muradiye. “Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu Ve Kataliz Uygulamaları”. International Journal of Advances in Engineering and Pure Sciences 31 (May 2019), 75-83. https://doi.org/10.7240/jeps.497405.
JAMA Şahin M. Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları. JEPS. 2019;31:75–83.
MLA Şahin, Muradiye. “Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu Ve Kataliz Uygulamaları”. International Journal of Advances in Engineering and Pure Sciences, vol. 31, 2019, pp. 75-83, doi:10.7240/jeps.497405.
Vancouver Şahin M. Antioksidan Gümüş Nanoparçacıkların Sentezlenmesi, Karakterizasyonu ve Kataliz Uygulamaları. JEPS. 2019;31:75-83.