Üç Boyutlu ve Katmanlı Bakır Organodifosfonat Koordinasyon Polimerinin Sentezi, Karakterizasyonu, Katalitik ve Termal Özelliklerinin İncelenmesi

Year 2023, Volume: 35 Issue: 4, 428 - 438, 31.12.2023

Burak Ay

https://doi.org/10.7240/jeps.1284405

Abstract

Bu çalışmada, (1,4-fenilenbis(metilen))bis(fosfonik asit) ligandı (H4L) ve katmanlı yapıya sahip bakır organodifosfonat polimeri, [Cu2(C8H8O6P2)(H2O)2]n (1), sentezlenmiştir. Sentezlenen bileşiklerin yapıları çeşitli spektroskopik ve analitik yöntemler kullanılarak karakterize edilmiştir. Tek kristal X-ray analizi sonucunda 1 nolu bileşiğin üç boyutlu ve sütunlu tabaka yapısında organik/inorganik katmanlardan oluştuğu gözlenmiştir. Monoklinik kristal sistemi ve P21/c uzay grubunda olan bileşik 1'in hücre parametreleri a = 10.8142(9) Å, b = 7.5839(6) Å, c = 7.3991(6) Å, V = 606.26(9) Å3 ve Z= 4'tür. Polimer zinciri içinde her bir bakır atomu toplam beş koordinasyona sahip olup kısmen bozulmuş kare piramit geometridedir. 1 polimerinin heterojen katalitik aktivitesi ve termal özellikleri incelenmiştir. TG analizi sonuncunda katalizörün 200 ᵒC sıcaklığa kadar termal kararlılığa sahip olduğu gözlenmiştir. TBHP kullanarak 60 ᵒC sıcaklıkta ve 12 saat sonunda %92.37 timol dönüşümü meydana gelmiştir.

Keywords

Bakır organodifosfonat, hidrotermal sentez, koordinasyon polimeri, timokinon

Supporting Institution

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Project Number

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Thanks

Tek kristal X-ray yapı çözümlemesinde verdiği destekten dolayı Prof. Dr. Onur ŞAHİN’e ve Bruker D8 QUEST difraktometrenin kullanımı için Sinop Üniversitesi Bilimsel ve Teknolojik Araştırma Uygulama ve Araştırma Merkezi'ne teşekkür ederim. Katalizör mekanizmasının önerilmesinde önemli katkılar sağlayan Öğr. Gör. Serkan KARACA’ya (Çukurova Üniversitesi) teşekkür ederim.

Synthesis, Characterization, Investigation of Catalytic and Thermal Properties of Three-Dimensional and Layered Copper Organodiphosphonate Coordination Polymer

Abstract

In this study, (1,4-phenylenebis(methylene))bis(phosphonic acid) ligand (H4L) and its pillared layered copper organodiphosphonate polymer, [Cu2(C8H8O6P2)(H2O)2]n (1), have been synthesized. The structures of the synthesized compounds have been characterized using various spectroscopic and analytical methods. As a result of single crystal X-ray analysis, compound 1 consists of organic/inorganic layers in a three-dimensional and columnar layer structure. This compound crystallizes in the monoclinic space group P21/c, with cell parameters, a = 10.8142(9) Å, b = 7.5839(6) Å, c = 7.3991(6) Å, V = 606.26(9) Å3 and Z= 4. Each copper atom in the polymeric chain has a total of five coordination and is in a partially distorted square pyramid geometry. The heterogeneous catalytic activity and thermal property of 1 have been investigated. TG analysis showed that the catalyst has thermal stability up to 200 ᵒC. By using TBHP, 92.37% thymol conversion occurred at 60 ᵒC and after 12 hours.

Keywords

Copper organodiphosphonate, hydrothermal synthesis, coordination polymer, thymoquinone

Project Number

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