Analysis of Toxic Element with Icp-Oes and Libs Methods in Marine Sediments Around the Sea of Marmara in Kapidağ Peninsula

Abstract

In this work, the LIBS (Laser Induced Breakdown Spectroscopy) and ICP-OES technique has been applied to the determination of total contents of heavy metals (Fe, Zn, Al, Mn, Co, Cr, Cu, Ni, Na, Mg, K, Ca) in soil samples of Marmara Sea. In order to validate the technique, LIBS data were compared with data obtained on the same soil samples by application of conventional Inductively Coupled Plasma ICP spectroscopy. The partial agreement obtained between the two sets of data suggested the potential applicability of the LIBS technique to the measurement of heavy metals in soils. According to the results, it was seen that the elements determined by ICP-OES analysis were also determined by LIBS method. The LIBS method is an important and practical technique for determining the elements that are enriched with anthropogenic factors as well as the elements resulting from natural processes.

Keywords

• LIBS,ICP-OES,Marmara Sea

References

1. [1] Nicholson, F.A., Smith, S.R., Alloway, B.J., Carlton-Smith, C., Chambers, B.J., “An inventory of metals inputs to agricultural soils in England and Wales”, The Science of the Total Environment, 311 (2003) : 205-219.
2. [2] Wisbrun, R., Schechter, I., Niessner, R., Schroeder, H., Kompa, K.L., “Detector for trace element analysis of solid. Environmental samples by laser plasma spectroscopy”, Anal. Chem. 66 (1994) : 2964–2975.
3. [3] Ciucci, A., Palleschi, V., Rastelli, S., Barbini, R., Colao, F., Fantoni, R., Palucci, A., Ribezzo, S., van der Steen, H.J.L., “Trace pollutants in soil by a time-resolved laser induced breakdown spectroscopy technique”, Appl. Phys. B 63 (1996) : 185–190.
4. [4] Eppler, A.S., Cremers, D.A., Hickmott, D.D., Ferris, M.J., Koskelo, A.C., “Matrix effects in the detection of Pb and Ba in soils using laser-induced breakdown spectroscopy”, Appl. Spectrosc. 50 9 (1996) 1175–1181.
5. [5] Cremers D.A., Yueh F.Y., Singh J.P., Zhang H., “Laser-induced breakdown spectroscopy, elemental analysis”, Encycl. Anal. Chem. (2006).
6. [6] Capitelli F., Colao F., Provenzano M.R., Fantoni R., Brunetti G., Senesi N., “Determination of heavy metals in soils by Laser Induced Breakdown Spectroscopy”, Geoderma 106 (2002) : 45–62.
7. [7] Radziemsky, L.J., Loree, T.R., Cremers, D.A., “Laser-induced breakdown spectroscopy LIBS.: A new spectroscopical technique”, In: Killinge, D.K., Mooradian, A. Eds., Optical and Laser-Remote Sensing. Springer, New York, Chap. 7.3. (1983) : 273–298.
8. [8] Moenke-Blankenburg, L., “Laser Microanalysis”, Wiley, New York, Chap. 3. (1989) : 64–65. NIST Electronic Database, http:rrphyslab.nist.govrPhysRefDatarcontents-atomic.html.

9. [9] Radziemsky, L.J., Cremers, D.A., “Spectrochemical analysis using laser plasma excitation”, In: Radziemsk, L.J., Cremers, D.A. Eds.., Laser-Induced Plasmas and Applications. Marcel Dekker, New York, Chap. 7. (1989) : 295–325.
10. [10] Velioğlu, M.H., Sezer, B., Bilge, G., Baytur, S.E., Boyacı, İ.H., “Identification of offal adulteration in beef by laser induced breakdown spectroscopy”, Meat Science 138 (2018) : 28-33.
11. [11] Dockery, C.R., Goode, S.R., “Laser-induced Breakdown Spectrocopy for the detection of gunshot residues on the hands of a shooter”, Appl Opt. 42(30) (2003) : 6153-8.
12. [12] Almessiere, M.A., Altuwiriqi, R., Gondal, M.A., Aldakheal, R.K., Alotaibi, H.F., “Qualitative and quantitative analysis of human nails to find correlation between nutrients and vitamin D deficiency using LIBS and ICP-AES”, Talanta 185 (2018) : 61-70.
13. [13] Anzano, J.M., Villoria, M.A., Ruíz-Medina, A., Lasheras, R.J., “Laser-induced breakdown spectroscopy for quantitative spectrochemical analysis of geological materials: Effects of the matrix and simultaneous determination”, Analytical Chimica Acta 575 (2) (2006) : 230-235.
14. [14] Samek, O., Krzyžánek, V., Beddows, D.C., Telle, H.H., Kaiser, J., Liška, M., “In: material identification using laser spectroscopy and pattern recognition algorithms”, International Conference on Computer Analysis of Images and Patterns, Springer, Berlin (2001) : 443–450.
15. [15] Vadillo, J.M., Cardell, K., Cremers, D.A., Laserna, J.J., “Rapid screening method for heavy metals in contaminated soils using LIBS”, Quimica Analytica, 18 (1999) : 169-174.
16. [16] Senesi, G.S., Baldassarre, G., Senesi, N., Radina, B., “Trace element inputs into soils by anthropogenic activities and implications for human health”, Chemosphere 39, (1999) : 343–377.
17. [17] Yümün, Z.Ü., “The effect of heavy metal pollution on foraminifera in the western Marmara Sea (Turkey)”, Journal of African earth Science 129 (2017) : 346-365.
18. [18] Yümün, Z.Ü., Önce, M., “Monitoring heavy metal pollution in foraminifera from the Gulf of Edremit (northeastern Aegean Sea) between Izmir, Balıkesir and Çanakkale (Turkey)”, Journal of African Earth Sciences. 130 (2017) : 110-124.
19. [19] Kam, E., Önce, M., “Pollutıon potentıal of heavy metals in the current sea sediments between Bandırma (Balıkesir) and Lapseki (Çanakkale) in the Marmara sea”, Journal of Engineering Technology and Applied Sciences. 3 (2016) : 141-148.
20. [20] Barbini, R., Colao, F., Fantoni, R., Palucci, A., Capitelli, F., “Application of laser induced breakdown spectroscopy to the analysis of metals in soils”, Appl. Phys. A 69 (1999) : S175–S179 Supp. l.
21. [21] Yang, N., “Elemental analysis of soil using laser-induced Breakdown spectroscopy . University of Tennessee. master theses (2009).
22. [22] Pandhija, S., Rai, N.K., Rai, A.K., Thankur, S.N., “Contaminant concentration in enviromental samples using LIBS and CF-LIBS”, Applied Physics B 98 (2010) : 231-241.