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Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste

Year 2016, Volume: 11 Issue: 1, 110 - 123, 30.03.2016

Abstract

Sodium dodecyl sulfate (SDS) was chosen to obtain a sandwich type assembly
of SDS and graphene (GR) sheets. The modified (SDS/GR) and unmodified GR were
characterized by powder X-ray diffraction (XRD),
high-resolution transmission electron microscopy (HRTEM),
Fourier transform infra-red (FTIR) spectroscopy, as well as thermal (TG) 
and TMA analyses. The SDS obviously prompts the dispersion of GR into a typical
wrinkled layered structure.
The addition of SDS into GR has lowering the
coefficient of thermal expansion (CTE).  137Cs is the most currently
radioactive isotope generated in the area around the
Chernobyl disaster. Cerium is quantitatively concentrated and
separated from Egyptian monazite by leaching the monazite lanthanide oxides
cake. So, SDS/GR was applied to remove Cs(I) and Ce(III) from aqueous solutions
using a batch technique.
The factors pH, contact time, temperature, and dosage
were investigated.
The
highest adsorption capacity of SDS/GR is found to be 44 and 60 mg g-1for
137Cs(I) and  Ce(III),respectively.
The adsorption of Cs(I) and Ce(III) onto SDS/GR fitted the pseudo-second-order
model. It was found that the adsorption processes have reached their
equilibrium state in about 2h, which is faster than most of carbon-based
adsorbents can do. From the thermodynamic parameters the sorption process was
endothermic and spontaneous in nature.

References

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  • Andrew GH, Korkut S, Punckt Ch, Ilhan AA, (2013) Dispersion Stability of Functionalized Graphene in Aqueous Sodium Dodecyl Sulfate Solutions, Langmuir, 29, 14831−14838.
  • Ansari R, Pornahad A, (2010) Removal of cerium(IV) ion from aqueous solutions using sawdust as a very low cost bioadsorbent. J. Appl. Sci. Environ. Sanit. 5, 253-262.
  • Ashraf MA, Khan AM, Ahmad M, Akib S, Balkhair KS, Bakar NK (2014) Release, deposition and elimination of radiocesium 137Cs in the terrestrial environment, J. Environ. Geochem. Health., 36, 1165-1190.
  • Attallah MF, Hamed MM, El Afifi EM, Ali HF, (2015) Removal of Ra-226 and Ra-228 from TENORM sludge waste using surfactants solutions, J. Environ. Radio, 139, 78-84.
  • Awual M, Yaita T, Shiwaku H, (2013) Design a novel optical adsorbent for simultaneous ultra-trace cerium(III) detection, sorption and recovery, J. Chemical Engineering ,228, 327–335.
  • Çavuş S, Gürdag Gl, (2009) Noncompetitive removal of heavy metal ions from aqueous solutions by poly[2-(acrylamido)-2-methyl-1-propanesulfonic acid-coitaconic acid] hydrogel” J. Ind. Eng. Chem. Res., 48, 2652-2658.
  • Deiseroth HJ, (2004) Advanced Inorganic Chemistry (part 1) basic solid state chemistry WS 05/06. Fan HT, Fan X, Li J, Guo M, Zhang D, (2012) Selective removal of arsenic(V) from aqueous solution using a surface-ion-imprinted amine functionalized silica gel sorbent, J. Ind Eng Chem Res, 51, 5216-5223.
  • Hao Y, Wang Zh, Gou J, Wang Zh, (2015) Kinetics and thermodynamics of diquat removal from water using magnetic graphene oxide nanocomposite, The Canadian J. of Chemical Engineering, 93,1713–1720.
  • Hawelek L. , Kolano-Burian A, Szade J, Maziarz W, Woznica N, Burian A, (2013) The atomic scale structure of nanographene platelets studied by X-ray diffraction, high-resolution transmission electron microscopy and molecular dynamics , J. Diamond and Related Materials, 35, 40–46.
  • Humelnicu D, Blegescu C, Ganju D, (2014) Removal of uranium(VI) and thorium(IV) ions from aqueous solutions by functionalized silica: kinetic and thermodynamic studies, J. Radioanal Nucl Chem , 299,1183–1190. IAEA-TECDOC-1504 (2006) Innovative waste treatment and conditioning technologies at nuclear power plants, Vienna.
  • Jeffrey RP, Sun HL, Todd MA, Jinho An, Mery IDS, Richard DP, Rodney SR, (2011) Thermomechanical properties of chemically modified graphene/poly(methyl methacrylate) composites made by in situ polymerization, J. Carbon, 49, 2615-2623.
  • Kuibo Y, Haitao L, Yidong X, Hengchang B, Jun S, Zhiguo L, Litao S, (2011) Thermodynamic and Kinetic Analysis of Low temperature Thermal Reduction of Graphene Oxide, Nano-Micro Lett., 3, 51-55
  • Li Y, Chen Ch, Xu J, Zhang Zh, Yuany B, Huang X, (2011), Improved mechanical properties of carbon nanotubes-coated flax fiber reinforced composites, J. Compos.: Part B, 42, 2121- 2130.
  • Lonkar SP, Deshmukh YS, Abdala AA, (2014), Recent Advances in Chemical Modifications Graphene, J. Nano Research, 4, 1-36.
  • Maa PCh, Naveed AS, Marom G, Kim JK, (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review Composites: Part A, 41, 1345–1367.
  • Mali KS, Greenwood J, Adisoejoso J, Phillipson R, Feyter SD, (2015), Nanostructuring graphene for controlled and reproducible functionalization, J. Nanoscale, 7, 1566.
  • Marcano DC, Kosynkin DV, Berlin ,JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ( 2010), Improved Synthesis of Graphene Oxide, J. American Chemical Society, 8, 4806–4814.
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  • Mishra A, Ramaprabhu S, (2011) Functionalized graphene sheets for arsenic removal and esalination of sea water, Desalination, 282, 39-45.
  • Pham TA, Kumar NA, Jeong YT, (2010), Covalent functionalization of graphene oxide with polyglycerol and their use as templates for anchoring magnetic nanoparticles, J. Synthetic Metals ,160, 2028–2036.
  • Rahmani A, Mousavi HZ, Fazli M, (2010) Effect of nanostructure alumina on adsorption of heavy metals, J. Desalination, 253, 94-100.
  • Rama KL, Sanjoy S, Arun KN, (2012) The physical properties of sulphonated/ graphene polyvinyl alcohol composite, J. Carbon, 50, 815-827.
  • Richard DP, Rodney SR, Jiang JW, Wang JS, Li B, (2009) Thermal expansion in single-walled carbon nanotubes and graphene: Nonequilibrium green’s function approach, J. Phys. Rev. B. 80, 205429.
  • Ruparelia JP, Duttagupta SP, Chatterjee AK, Mukherji S (2008) Potential of carbon nanomaterials for removal of heavy metals from water, J. Desalination , 232, 145-156.
  • Sepehrian H, Cheraghali R, Rezaei P, Abdi H, (2013) Adsorption behavior studies of Cerium on modified Mesoporous Aluminosilicate, Int. J. Nano Dimens., 5, 169-175.
  • Si YC, Samulski ET, (2008) Synthesis of water soluble graphene, Nano Lett., 8, 1679–1682.
  • Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhamma A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide, Carbon, 45, 1558-1565.
  • Sungjin P, Jinho A, Jeffrey RP, Aruna V, Shanthi M, Rodney SR, (2011) Hydrazine-reduction of graphite- and graphene oxide, J. Carbon, 49, 3019-3023.
  • Tapas K, Saswata B, Ananta KM, Partha Kh, Nam HK, Joong HL, (2012), Effect of functionalized graphene on the physical properties of linear low density polyethylene nanocomposites, J. Polymer Testing, 31, 31-38.
  • Tapas K, Saswata B, Kumar MA, Partha K, Namhoon K, Joonghee L, (2012) Chemical functionalization of graphene and its applications, J. Prog Mater Sci, 57, 1061-1105.
  • Thayumanavan N, Pankaj T, Girish J, (2015) Effect of surfactant and sodium alginate modification of graphene on the mechanical and thermal properties of polyvinyl alcohol (PVA) nanocomposites, J. Cellulose Chem. Technol., 49, 69-80.
  • Uddin ME, Kuila, T, Nayak GC, Kim NH, Ku BC, Lee JH, (2013) Effects of various surfactants on the dispersion stability and electrical conductivity of surface modified grapheme, J. Alloys and Compounds ,562, 134-142.
  • Worsley MA, Olson TY, Lee JRI, (2011) High surface area, sp2-cross-linked three-dimensional graphene monoliths, J. Phys Chem Lett., 2, 921–925.
  • Xu LQ, Wang L, Zhang B, Lima CH, Chen Y, Neoh KG, Kang ET, Fu GD, (2011), Functionalization of reduced graphene oxide nanosheets via stacking interactions with the fluorescent and water-soluble perylene bisimide-containing polymers, Polymer , 52, 2376-2383.
  • Yan W, Hanjin L, Hou W, Can W, Jian Zh, Zilong Zh, (2013) Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethylammonium bromide, J. Colloid and Interface Science, 394, 183-191.
  • Yuxi X, Wenjing H, Hua B, Chun L, Gaoquan S, (2009) Strong and ductile poly(vinyl alcohol) graphene oxide composite films with a layerd structure, J. Carbon, 47, 3538-3543.
  • Zhenghai T, Yanda L, Baochun G, Liqun Z, Demin J, (2012) The use of rhodamine B-decora ted graphene as a reinforcement in polyvinyl alcohol composites, J. Polymer, 53, 673-680.
Year 2016, Volume: 11 Issue: 1, 110 - 123, 30.03.2016

Abstract

References

  • Abdel Rahman RO, Ibrahium HA, Hung YT (2011) Liquid Radioactive Wastes Treatment: A Review, Water, 3, 551-565.
  • Andrew GH, Korkut S, Punckt Ch, Ilhan AA, (2013) Dispersion Stability of Functionalized Graphene in Aqueous Sodium Dodecyl Sulfate Solutions, Langmuir, 29, 14831−14838.
  • Ansari R, Pornahad A, (2010) Removal of cerium(IV) ion from aqueous solutions using sawdust as a very low cost bioadsorbent. J. Appl. Sci. Environ. Sanit. 5, 253-262.
  • Ashraf MA, Khan AM, Ahmad M, Akib S, Balkhair KS, Bakar NK (2014) Release, deposition and elimination of radiocesium 137Cs in the terrestrial environment, J. Environ. Geochem. Health., 36, 1165-1190.
  • Attallah MF, Hamed MM, El Afifi EM, Ali HF, (2015) Removal of Ra-226 and Ra-228 from TENORM sludge waste using surfactants solutions, J. Environ. Radio, 139, 78-84.
  • Awual M, Yaita T, Shiwaku H, (2013) Design a novel optical adsorbent for simultaneous ultra-trace cerium(III) detection, sorption and recovery, J. Chemical Engineering ,228, 327–335.
  • Çavuş S, Gürdag Gl, (2009) Noncompetitive removal of heavy metal ions from aqueous solutions by poly[2-(acrylamido)-2-methyl-1-propanesulfonic acid-coitaconic acid] hydrogel” J. Ind. Eng. Chem. Res., 48, 2652-2658.
  • Deiseroth HJ, (2004) Advanced Inorganic Chemistry (part 1) basic solid state chemistry WS 05/06. Fan HT, Fan X, Li J, Guo M, Zhang D, (2012) Selective removal of arsenic(V) from aqueous solution using a surface-ion-imprinted amine functionalized silica gel sorbent, J. Ind Eng Chem Res, 51, 5216-5223.
  • Hao Y, Wang Zh, Gou J, Wang Zh, (2015) Kinetics and thermodynamics of diquat removal from water using magnetic graphene oxide nanocomposite, The Canadian J. of Chemical Engineering, 93,1713–1720.
  • Hawelek L. , Kolano-Burian A, Szade J, Maziarz W, Woznica N, Burian A, (2013) The atomic scale structure of nanographene platelets studied by X-ray diffraction, high-resolution transmission electron microscopy and molecular dynamics , J. Diamond and Related Materials, 35, 40–46.
  • Humelnicu D, Blegescu C, Ganju D, (2014) Removal of uranium(VI) and thorium(IV) ions from aqueous solutions by functionalized silica: kinetic and thermodynamic studies, J. Radioanal Nucl Chem , 299,1183–1190. IAEA-TECDOC-1504 (2006) Innovative waste treatment and conditioning technologies at nuclear power plants, Vienna.
  • Jeffrey RP, Sun HL, Todd MA, Jinho An, Mery IDS, Richard DP, Rodney SR, (2011) Thermomechanical properties of chemically modified graphene/poly(methyl methacrylate) composites made by in situ polymerization, J. Carbon, 49, 2615-2623.
  • Kuibo Y, Haitao L, Yidong X, Hengchang B, Jun S, Zhiguo L, Litao S, (2011) Thermodynamic and Kinetic Analysis of Low temperature Thermal Reduction of Graphene Oxide, Nano-Micro Lett., 3, 51-55
  • Li Y, Chen Ch, Xu J, Zhang Zh, Yuany B, Huang X, (2011), Improved mechanical properties of carbon nanotubes-coated flax fiber reinforced composites, J. Compos.: Part B, 42, 2121- 2130.
  • Lonkar SP, Deshmukh YS, Abdala AA, (2014), Recent Advances in Chemical Modifications Graphene, J. Nano Research, 4, 1-36.
  • Maa PCh, Naveed AS, Marom G, Kim JK, (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review Composites: Part A, 41, 1345–1367.
  • Mali KS, Greenwood J, Adisoejoso J, Phillipson R, Feyter SD, (2015), Nanostructuring graphene for controlled and reproducible functionalization, J. Nanoscale, 7, 1566.
  • Marcano DC, Kosynkin DV, Berlin ,JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ( 2010), Improved Synthesis of Graphene Oxide, J. American Chemical Society, 8, 4806–4814.
  • Michael JM, Je-Luen Li, Douglas HA, Hannes CSc,Ahmed AA, Jun L, Margarita HA, David LM,Roberto C, Robert KP, Ilhan AA, (2007) Single sheet functionalized graphene by Oxidation and thermal expansion of graphite, J. Chem. Mater, 19, 4396-4404.
  • Mishra A, Ramaprabhu S, (2011) Functionalized graphene sheets for arsenic removal and esalination of sea water, Desalination, 282, 39-45.
  • Pham TA, Kumar NA, Jeong YT, (2010), Covalent functionalization of graphene oxide with polyglycerol and their use as templates for anchoring magnetic nanoparticles, J. Synthetic Metals ,160, 2028–2036.
  • Rahmani A, Mousavi HZ, Fazli M, (2010) Effect of nanostructure alumina on adsorption of heavy metals, J. Desalination, 253, 94-100.
  • Rama KL, Sanjoy S, Arun KN, (2012) The physical properties of sulphonated/ graphene polyvinyl alcohol composite, J. Carbon, 50, 815-827.
  • Richard DP, Rodney SR, Jiang JW, Wang JS, Li B, (2009) Thermal expansion in single-walled carbon nanotubes and graphene: Nonequilibrium green’s function approach, J. Phys. Rev. B. 80, 205429.
  • Ruparelia JP, Duttagupta SP, Chatterjee AK, Mukherji S (2008) Potential of carbon nanomaterials for removal of heavy metals from water, J. Desalination , 232, 145-156.
  • Sepehrian H, Cheraghali R, Rezaei P, Abdi H, (2013) Adsorption behavior studies of Cerium on modified Mesoporous Aluminosilicate, Int. J. Nano Dimens., 5, 169-175.
  • Si YC, Samulski ET, (2008) Synthesis of water soluble graphene, Nano Lett., 8, 1679–1682.
  • Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhamma A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide, Carbon, 45, 1558-1565.
  • Sungjin P, Jinho A, Jeffrey RP, Aruna V, Shanthi M, Rodney SR, (2011) Hydrazine-reduction of graphite- and graphene oxide, J. Carbon, 49, 3019-3023.
  • Tapas K, Saswata B, Ananta KM, Partha Kh, Nam HK, Joong HL, (2012), Effect of functionalized graphene on the physical properties of linear low density polyethylene nanocomposites, J. Polymer Testing, 31, 31-38.
  • Tapas K, Saswata B, Kumar MA, Partha K, Namhoon K, Joonghee L, (2012) Chemical functionalization of graphene and its applications, J. Prog Mater Sci, 57, 1061-1105.
  • Thayumanavan N, Pankaj T, Girish J, (2015) Effect of surfactant and sodium alginate modification of graphene on the mechanical and thermal properties of polyvinyl alcohol (PVA) nanocomposites, J. Cellulose Chem. Technol., 49, 69-80.
  • Uddin ME, Kuila, T, Nayak GC, Kim NH, Ku BC, Lee JH, (2013) Effects of various surfactants on the dispersion stability and electrical conductivity of surface modified grapheme, J. Alloys and Compounds ,562, 134-142.
  • Worsley MA, Olson TY, Lee JRI, (2011) High surface area, sp2-cross-linked three-dimensional graphene monoliths, J. Phys Chem Lett., 2, 921–925.
  • Xu LQ, Wang L, Zhang B, Lima CH, Chen Y, Neoh KG, Kang ET, Fu GD, (2011), Functionalization of reduced graphene oxide nanosheets via stacking interactions with the fluorescent and water-soluble perylene bisimide-containing polymers, Polymer , 52, 2376-2383.
  • Yan W, Hanjin L, Hou W, Can W, Jian Zh, Zilong Zh, (2013) Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethylammonium bromide, J. Colloid and Interface Science, 394, 183-191.
  • Yuxi X, Wenjing H, Hua B, Chun L, Gaoquan S, (2009) Strong and ductile poly(vinyl alcohol) graphene oxide composite films with a layerd structure, J. Carbon, 47, 3538-3543.
  • Zhenghai T, Yanda L, Baochun G, Liqun Z, Demin J, (2012) The use of rhodamine B-decora ted graphene as a reinforcement in polyvinyl alcohol composites, J. Polymer, 53, 673-680.
There are 38 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Magda S. Sayed This is me

Tarek M. Salama This is me

Mostafa F. Bakr This is me

Aisha. M. El Dakrory This is me

Ragab M. Maree This is me

İ.a. Ibrahim This is me

Publication Date March 30, 2016
Acceptance Date March 29, 2016
Published in Issue Year 2016 Volume: 11 Issue: 1

Cite

APA Sayed, M. S., Salama, T. M., Bakr, M. F., El Dakrory, A. M., et al. (2016). Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste. Journal of International Environmental Application and Science, 11(1), 110-123.
AMA Sayed MS, Salama TM, Bakr MF, El Dakrory AM, Maree RM, Ibrahim İ. Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste. J. Int. Environmental Application & Science. March 2016;11(1):110-123.
Chicago Sayed, Magda S., Tarek M. Salama, Mostafa F. Bakr, Aisha. M. El Dakrory, Ragab M. Maree, and İ.a. Ibrahim. “Synthesis of Graphene Functionalized With (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste”. Journal of International Environmental Application and Science 11, no. 1 (March 2016): 110-23.
EndNote Sayed MS, Salama TM, Bakr MF, El Dakrory AM, Maree RM, Ibrahim İ (March 1, 2016) Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste. Journal of International Environmental Application and Science 11 1 110–123.
IEEE M. S. Sayed, T. M. Salama, M. F. Bakr, A. M. El Dakrory, R. M. Maree, and İ. Ibrahim, “Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste”, J. Int. Environmental Application & Science, vol. 11, no. 1, pp. 110–123, 2016.
ISNAD Sayed, Magda S. et al. “Synthesis of Graphene Functionalized With (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste”. Journal of International Environmental Application and Science 11/1 (March 2016), 110-123.
JAMA Sayed MS, Salama TM, Bakr MF, El Dakrory AM, Maree RM, Ibrahim İ. Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste. J. Int. Environmental Application & Science. 2016;11:110–123.
MLA Sayed, Magda S. et al. “Synthesis of Graphene Functionalized With (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste”. Journal of International Environmental Application and Science, vol. 11, no. 1, 2016, pp. 110-23.
Vancouver Sayed MS, Salama TM, Bakr MF, El Dakrory AM, Maree RM, Ibrahim İ. Synthesis of Graphene Functionalized with (SDS) for Removal of 137Cs(I) and Ce(III) Ions from Radioactive Waste. J. Int. Environmental Application & Science. 2016;11(1):110-23.

“Journal of International Environmental Application and Science”