Cosmetıc investıgatıon of the adsorption of hyalunoric and glycolic acid on tutmaç clay

Year 2021, Volume: 16 Issue: 4, 133 - 139, 31.12.2021

Adnan Yıldız Nur Beyaztaş Tuğba Gür

Abstract

In this study, hyaluronic and glycolic acids were adsorbed on Tutmaç clay. Clay brought from the village of Tutmaç in Guzelsu town of Gurpinar district in Van. The clay we obtained in the form of large particles was first sieved with a pore size of 0.038 mm (400 mesh). This ground clay was heated in an oven at 100 °C for 24 hours and stored in a desiccator. The clay sample, that is, 0.2 gr clay, was weighed 10 times and adsorbed for 10 minutes at room temperature with 1,2,3,4.5 ml of concentrated hyaluronic acid and glycolic acid for each 0.2 gr clay. The same operations were carried out for heat-treated clay. When the adsorption process came to equilibrium, the samples were filtered on filter paper and then washed with ionized water. The solid part was dried and the Differential Thermal Analysis (DTA), Thermogravimetric Analysis (TGA) and Scanning Electron Microscope (SEM) analyzes of these samples were performed, and the results were obtained by interpreting the analyzes in the central laboratory. In this study, studies were carried out on pure clay and clay treated with acids. As a result of the processes and thermal changes, it was observed that the amount of hyaluronic acid adsorbing was higher in the untreated clay, and it was concluded that these clay minerals can be used as a skin mask when suitable conditions are met. At the same time, it was concluded that the pore structure of the clay was deteriorated and it moved towards an irregular shape with the heat treatment of pure clay.

Keywords

Hyaluronic acid, Glycolic acid, Clay, Adsorption, SEM

References

• Alper Ş, (2013) Bazı inorganik iyonların ve kolesterolün tutmaç kili üzerindeki adsorpsiyonunun incelenmesi. YYÜ, Fen Bilimleri Enstitüsü, Van.
• Bangash FK and Alam S, (2009) Adsorption of acid blue 1 on activated carbon produced from the wood of ailanthus altissima. Brazilian Journal of Chemical Engineering, 26,2, 275-285.
• Berardesca E, Maibach H, (1995) AHA mechanisms of action. Cosm. Toilet, 110,6:30-31.
• Beyhan M, (2003) Atık çamurlar v eve doğal malzemeler ile sulardan florür iyonu gideriminin araştırılması. Doktora Tezi, Yıldız Teknik Üniversitesi Fen Bilimleri Enstitüsü, İstanbul.
• Bulut E, Özacar M and Şengil İA, (2008) Adsorption of malachite green onto bentonite: equilibrium and kinetic studies and process design. Microporous and Mesoporous Material, 115, 234-246.
• Canning C, (1994) The skin care market. Happi, 31-38.
• Carretero MI, (2002) Clay minerals and their beneficial effects upon human health. A review, Applied Clay Science, 21,155-163.
• Crini G, (2006) Non-conventional low-cost adsorbans for dye removal: A review, Bioresource Technology, 97, 1061-1085.
• Dalgıç A, Kavak O,(2004) Kil Mineralleri ve Sağlık. Dicle Tıp Dergisi 31(2),73-78.
• Dong Y, Marshsall J, Haroosh HJ, Mohammadzadehmoghadam S, Liu D, Qi X, Lau KT, (2015) Polylactic acid (PLA)/halloysite nanotube (HNT) composite mats: influence of HNT content and modification. Composites A, 76,28–36.
• Dunn CA, (1996) What's new in cosmetic R&D, Happi. 56- 62.
• Ekici S, Ilgın P, Yılmaz S, Aktas N, Sahiner N, (2011) Temperature and magnetic field responsive hyaluronic acid particles with tunable physical and chemical properties. Appl. Surf. Sci. 257,2669–2676.
• Erickson IE, Kestle SR, Zellars KH, Farrell MJ, Kim M, Burdick JA, Mauckl RL, (2012) High mesenchymal stem cell seeding densities in hyaluronic acid hydrogels produce engineered cartilage with native tissue properties. Acta Biomater, 8,3027–3034.
• Ilgin P, Avci G, Silan C, Ekici S, Aktas N, Ayyala RS, John VT, Sahiner N, (2010) Colloidal drug carries from (sub)micron hyaluronic acid hydrogel particles with tunable properties for biomedical applications. Carbohydr. Polym, 82,997–1003.
• Jha AK, Hule RA, Jiao T, Teller SS, Clifton RJ, Duncan RL, Pochan DJ, Jia X, (2009) Structural analysis and mechanical characterization of hyaluronic acid-based doubly cross-linked networks. Macromolecules, 42, 537–546.
• Khaled A, El Nemr A, El-Sikaily A and Abdelwahab O, (2009) Removal of direct n blue-106 from artificial textile dye effluent using activated carbon from orange peel: Adsorption İsotherm and Kinetic Studies. Journal of Hazardous Materials, 165, 100-110.
• Kim H and Guiochon G, (2005) Adsorption on molecularly imprinted polymers of structural analogues of a template. SingleComponent Adsorption İsotherm Data. Analytical Chemistry, 77, 6415-6425.
• Malayoğlu U, Akar A, (1999) Killerin Sınıflandırılmasında ve Kullanım Alanlarının Saptanmasında Aranan Kriterlerin İrdelenmesi, pp.125-142. Endüstriyel Hammaddeler Sempozyumu 1, İzmir.
• Miranda DG, Malmonge S, Campos DM, Attik NG, Grosgogeat B, Gritsch K, (2016) A chitosan-hyaluronic acid hydrogel scaffold for periodontal tissue engineering. J. Biomed. Mater. Res. B. Appl. Biomater, 104B,1691–1702.
• Oelschlaeger C, Bossler F, Willenbacher N, (2016) Synthesis, structural and micromechanical properties of 3D hyaluronic acid-based croyogel scaffolds. Biomacromolecules, 17,580–589.
• Sahiner N, Jia X, (2008) One-step synthesis of hyaluronic acid-based (sub) micron hydrogel particles: process optimization and preliminary characterization, Turk. J. Chem, 32,397–409.
• Schimmel D, Fagnani KC, Oliveira dos Santos JB, Barros MASD, Antonio da Silva E, (2010) Adsorption of turquoise blue qg reactive by commercial activated carbon in batch reactor: kinetic and equilibrium studies. Brazilian Journal of Chemical Engineering, 27, 289-298.
• Scholz D, Brooks GJ, Parish DF, Burmeister F, (1994) Fruit acid extracts, a fresh approach to skin renewal. International journal of cosmetic science, 16(6), 265-272.
• Selçuk A, (1991) Termal işleme tabi tutulan speolitin bazı organik bazlarla etkileşmesinin spektrofotometrik incelenmesi. YYÜ, Fen Bilimleri Enstitüsü, Van.
• Singh D, Tripathi A, Zo S, Singh D, Han SS, (2014) Synthesis of composite gelatin-hyaluronic acid-alginate porous scaffold and evaluation for in vitro stem cell growth and in vivo tissue integration. Colloids Surf. B, 116, 502–509.
• Stiller MJ, Bartolone J, Stern R, Smith S, Kollias N, Gillies R, Drake L.A (1996) Topical 8% glycolic acid and 8% L-lactic acid creams for the treatment of photodamaged skin: a double-blind vehicle-controlled clinical trial. Archives of dermatology, 132(6), 631-636.
• Tavsanli B, Okay O, (2016) Preparation and fracture process of high strength hyaluronic acid hydrogels cross-linked by ethylene glycol diglycidyl ether. React. Funct. Polym, 109,42–51.
• Van Scott EJ, Yu Rj, (1974) Control of keratinization with ahydroxy acids and related compounds. Archives of Dermatology, 110,586-590.
• Veli S and Alyüz B, (2007) Adsorption of copper and zinc from aqueous solutions by using natural clay. Journal of Hazardous Materials, 149, 226-233.
• Veliev EV, Öztürk T, Veli S, Fatullayev AG, (2006) Application of diffusion model for adsorption of azo reactive dye on pumice. Polish Journal of Environmental Studies, 15, 347-353.
• Wypych F, (2004) Clay Surfaces. Fundamental and Applications (Eds.: F. Wypych, K.G. Satyanarayana) Chemical Modification of Clay Surfaces, 22,578.
• Yıldız A, (1999) Bazı toksikantların modifiye edilmiş killer üzerindeki adsorpsiyonu. YYÜ, Fen Bilimleri Enstitüsü, Van.
• Yılmaz K, (1990) Harran Ovası Topraklarının Mineralojik Karakterizasyonları. Doktora Tezi. Çukurova Üniversitesi Fen Bilimleri Enstitüsü, Adana.