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Current approaches to the synthesis of flame retardant polymers

Year 2022, , 95 - 113, 27.07.2022
https://doi.org/10.29228/JIENS.63353

Abstract

Polymeric materials are used in every field due to their easy processing and low-weight structure. However, because they are hydrocarbon-based, they are flammable, often producing toxic gases. Therefore, in the polymer industry, the development of flame retardant polymer materials is of great importance to increase the use of polymers. This review focuses on reviewing and classifying the latest developments in the knowledge and technology of flame retardant polymer materials and showing the qualitative and quantitative analyzes performed on their flame retardant properties. In addition, inorganic flame retardants containing hydroxide are disclosed, in addition to phosphorus and nitrogen elements, which replace halogens as flame retardant additives. Finally, it touches on the topic of “anti-flammable polymers,” a new strategy.

References

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  • Vahabi H, Laoutid F, Mehrpouya M, Saeb MR, Dubois P (2021) Flame retardant polymer materials: An update and the future for 3D printing developments. Materials Science Engineering: R: Reports 144:100604. https://doi.org/10.1016/j.mser.2020.100604
  • Mincheva R, Guemiza H, Hidan C, Moins S, Coulembier O, Dubois P, Laoutid F (2019) Development of inherently flame—retardant phosphorylated PLA by combination of ring-opening polymerization and reactive extrusion. Materials 13(1):13. https://doi.org/10.3390/ma13010013
  • Eren T, Aşçı A (2015) Synthesis and characterization of phosphonate based polynorbornene polymers derived from romp (ring opening metathesis polymerization) method and investigation their flame retardant properties. Sigma: Journal of Engineering & Natural Sciences/Mühendislik ve Fen Bilimleri Dergisi 33(4):615-625. https://eds.yildiz.edu.tr/sigma/
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  • Gao C, Wang L, Lei Z, Yang L, Xu X, Guo X (2017) Property of intrinsic flame retardant epoxy resin cured by functional magnesium organic composite salt and diethylenetriamine. Fire Materials 41 (2):180-192. https://doi.org/10.1002/fam.2377
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Alev geciktirici polimerlerin sentezine yönelik güncel yaklaşımlar

Year 2022, , 95 - 113, 27.07.2022
https://doi.org/10.29228/JIENS.63353

Abstract

Günümüzde polimerik malzemeler kolay işlenebilmeleri ve düşük ağırlıklı yapıları nedeniyle her alanda kullanılmaktadır. Bununla birlikte, hidrokarbon esaslı olduklarından dolayı yanıcıdırlar, çoğu zaman zehirli gaz üretirler. Polimer sektöründe, alev geciktirici polimer malzemelerin gelişimi polimerlerin kullanımlarının arttırılması için büyük bir öneme sahiptir. Bu derleme, alev geciktirici polimer malzemelerin bilgi ve teknolojisindeki son gelişmeleri incelemeye, sınıflandırmaya ve alev geciktirici özellikleri üzerinde gerçekleştirilen kalitatif ve kantitatif analizleri göstermeye odaklanmaktadır. Ayrıca, alev geciktirici katkı maddesi olarak halojenlerin yerini tutan fosfor ve azot elementlerine ilave olarak hidroksit içerikli inorganik alev geciktiriciler açıklanmaktadır. Son olarak, alev geciktirici katkı maddelerinin zamanla ortamdan salınması nedeniyle polimer matrisi ile homojen olarak karışabilirliği sınırlı olduğundan ve mekanik özellikler üzerinde olumsuz etkisinden dolayı yeni bir strateji olan “yanmaz polimerler” konusuna değinmektedir.

References

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  • Mincheva R, Guemiza H, Hidan C, Moins S, Coulembier O, Dubois P, Laoutid F (2019) Development of inherently flame—retardant phosphorylated PLA by combination of ring-opening polymerization and reactive extrusion. Materials 13(1):13. https://doi.org/10.3390/ma13010013
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  • Çakmakçı E, Güngör A (2013) Preparation and characterization of flame retardant and proton conducting boron phosphate/polyimide composites. Polymer Degradation and Stability 98 (5):927-933. https://doi.org/10.1016/j.polymdegradstab.2013.03.003
  • Gao C, Wang L, Lei Z, Yang L, Xu X, Guo X (2017) Property of intrinsic flame retardant epoxy resin cured by functional magnesium organic composite salt and diethylenetriamine. Fire Materials 41 (2):180-192. https://doi.org/10.1002/fam.2377
  • Weil ED, Zhu W, Patel N, Mukhopadhyay SM (1996) A systems approach to flame retardancy and comments on modes of action. Polymer Degradation and Stability 54 (2-3):125-136. https://doi.org/10.1016/S0141-3910(96)00036-5
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  • Weil ED, Patel NG, Said MM, Hirschler MM, Shakir S (1992) Oxygen index: Correlations to other fire tests. Fire and Materials 16 (4):159-167. https://doi.org/10.1002/fam.810160402
  • Wan L, Deng C, Zhao Z-Y, Chen H, Wang Y-Z (2020) Flame retardation of natural rubber: strategy and recent progress. Polymers 12 (2):429. https://doi.org/10.3390/polym12020429
  • Akkurt S (2007) Plastik malzeme bilimi teknolojisi ve kalıp tasarımı. Birsen Yayınevi, İstanbul.
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Details

Primary Language Turkish
Subjects Polymers and Plastics
Journal Section Reviews
Authors

Neşe Çakır Yiğit This is me 0000-0002-4714-4488

Publication Date July 27, 2022
Submission Date June 29, 2022
Published in Issue Year 2022

Cite

APA Çakır Yiğit, N. (2022). Alev geciktirici polimerlerin sentezine yönelik güncel yaklaşımlar. Journal of Innovative Engineering and Natural Science, 2(2), 95-113. https://doi.org/10.29228/JIENS.63353


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