Sterolitografi tekniği ile tek adımda gümüş nanopartikül içeren nanokompozitlerin hazırlanması
Year 2024,
, 263 - 275, 31.07.2024
Ayberk Baykal
Onur Alp Aksan
,
Ahmet Yavuz Oral
,
Kaan Bilge
,
Nuray Kızıldağ
Abstract
As a technique that uses ultraviolet light to cure photo-polymers layer by layer with high spatial resolution and surface quality, stereolithography (SLA) allows for precise process control and optimization for various UV-curable polymers and their nanocomposites with various nanoparticles. In this study, UV-curable polymer nanocomposites were prepared with the addition of different contents of silver nitrate via SLA technique for use in antibacterial applications. In-situ synthesis of AgNPs was achieved during the SLA process without any additional treatments. The effect of AgNO3 addition on the curing of the resin and the mechanical properties of the nanocomposite specimens were investigated. To understand the fracture mechanism of the nanocomposite samples, the fractured surfaces of the samples were evaluated by SEM, and the AgNO3 content of the nanocomposite was evaluated by EDX. The nanocomposites containing 0.3 wt. % AgNO3 exhibited improved mechanical properties. Further increasing the AgNO3 content to 3 wt. % led to deterioration in the physical and mechanical properties of the polymer nanocomposites.
Project Number
GTU-BAP Project 2023-A-101-15
References
- Al Rashid A, Khan A, Al-Ghamdi SG, Koc M (2021) Additive manufacturing of polymer nanocomposites: Needs and challenges in materials, processes, and applications. Journal of Materials Research and Technology, 14:910-941. https://doi.org/10.1016/j.jmrt.2021.07.016
- Wu H, Fahy WP, Kim S, Kim H, Zhao N, Pilato L, Kafi A, Bateman S, Koo JH (2020) Recent developments in polymers/polymer nanocomposites for additive manufacturing. Progress in Materials Science, 111: 100638. https://doi.org/10.1016/j.pmatsci.2020.100638
- Ahangar P, Cooke ME, Weber MH, Rosenzweig DH (2019) Current biomedical applications of 3D printing and additive manufacturing. Applied Sciences, 9:1713. https://doi.org/10.3390/APP9081713
- Nachal N, Moses JA, Karthik P, Anandharamakrishnan C (2019) Applications of 3D printing in food processing. Food Engineering Reviews 11:123–141. https://doi.org/10.1007/S12393-019-09199-8
- Campbell TA, Ivanova OS (2013) 3D Printing of multifunctional nanocomposites. Nano Today, 8:119–120, https://doi.org/10.1016/j.nantod.2012.12.002
- Taormina G, Sciancalpore C, Messori M, Bondioli F (2018) Advanced resins for stereolithography: In situ generation of silver nanoparticles. AIP Conference Proceedings, 1981:20065. https://doi.org/10.1063/1.5045927
- Fantino E, Chiappone A, Roppolo I, Manfredi D, Bongiovanni R, Pirri CF, Calignano F (2016) 3D Printing of conductive complex structures with in situ generation of silver nanoparticles. Advanced Materials, 28(19):3712–3717. https://doi.org/10.1002/ADMA.201505109
- Kartal I., Ozcan Z. (2023) Investigation of effect of chestnut sawdust on mechanical properties of epoxy matrix composites. Journal of Innovative Engineering and Natural Science, 3(2):67-74. https://doi.org/10.29228/JIENS.69363
- Khalid MY, Imran R, Arif ZU, Akram N, Arshad H, Al Rashid A, Márquez FPG (2021) Developments in chemical treatments, manufacturing techniques and potential applications of natural-fibers-basedb biodegradable composites. Coatings, 11:293. https://doi.org/10.3390/COATINGS11030293
- Billings C (2023) Additive manufacturing and synthesis of advanced antibacterial and sensing photocurable polymer nanocomposites. Dissertation, University of Oklahoma.
- Sangermano M, Tagci Y, Rizza G (2007). In situ synthesis of silver-epoxy nanocomposites by photoinduced electron transfer and cationic polymerization processes. Macromolecules, 40:8827-8829. https://doi.org/10.1021/ma702051g
- Peerzada M, Abbasi S, Lau KT, Hameed N (2020). Additive manufacturing of epoxy resins: Materials, methods, and latest trends. Industrial&Engineering Chemistry Research, 59(14):6375-6390. https://doi.org/10.1021/acs.iecr.9b06870
- Bruna T, Maldonado-Bravo F, Jara P, Caro N (2021) Silver nanoparticles and their antibacterial applications. International Journal of Molecular Sciences, 22(13):7202. https://doi.org/10.3390/ijms22137202
- Valencia LM, Herrera M, de la Mata M, de León AS, Delgado FJ, Molina SI (2022) Synthesis of silver nanocomposites for stereolithography: in situ formation of nanoparticles. Polymers, 14(6):1168. https://doi.org/10.3390/polym14061168
- Yaragatti N, Patnaik A (2021) A review on additive manufacturing of polymers composites. Materials Today: Proceedings, 44:4150-4157. https://doi.org/10.1016/j.matpr.2020.10.490
- Anastasio R, Peerbooms W, Cardinaels R, Van Breemen LCA (2019) Characterization of ultraviolet-cured methacrylate networks: From photopolymerization to ultimate mechanical properties. Macromolecules, 52:9220–9231. https://doi.org/10.1021/ACS.MACROMOL.9B01439
- Singh N, Khyanna P (2007) In situ synthesis of silver nano-particles in polymethylmethacrylate. Materials Chemistry and Physics, 104 (2-3):367-372. https://doi.org/10.1016/j.matchemphys.2007.03.026
- Darman Singho N, Akmal Che Lah N, Rafie Johan M, Ahmad R (2012) FTIR Studies on silver-poly(methylmethacrylate) nanocomposites via in-situ polymerization technique. International Journal of Electrochemical Science, 7(6):5596-5603. https://doi.org/10.1016/S1452-3981(23)19646-5
- Siddiqui MN, Redhwi HH, Vakalopoulou E, Tsagkalias I, Ioannidou MD, Achilias DS (2015) Synthesis, characterization and reaction kinetics of PMMA/silver nanocomposites prepared via in situ radical polymerization. European Polymer Journal, 72:256–269. https://doi.org/10.1016/j.eurpolymj.2015.09.019
- Russ, J. C. (1984) Fundamentals of Energy Dispersive X-ray Analysis, Butterworths, London.
- https://www.edax.com/resources/posters/periodic-table-poster, accessed on 29.01.2024
- Chinni, S. V., Gopinath, S. C., Anbu, P., Fuloria, N. K., Fuloria, S., Mariappan, P., ... & Samuggam, S. (2021). Characterization and antibacterial response of silver nanoparticles biosynthesized using an ethanolic extract of Coccinia indica leaves. Crystals, 11(2), 97. https://doi.org/10.3390/cryst11020097
- Shaban, M., Ahmed, A., Abdel-Rahman, E., Hamdy, H. (2017) Tunability and Sensing Properties of Plasmonic/1D Photonic Crystal. Scientific Reports, 7, 41983. https://doi.org/10.1038/srep41983
One-step preparation of silver nanoparticle containing polymer nanocomposites via stereolithography technique
Year 2024,
, 263 - 275, 31.07.2024
Ayberk Baykal
Onur Alp Aksan
,
Ahmet Yavuz Oral
,
Kaan Bilge
,
Nuray Kızıldağ
Abstract
As a technique that uses ultraviolet light to cure photo-polymers layer by layer with high spatial resolution and surface quality, stereolithography (SLA) allows for precise process control and optimization for various UV-curable polymers and their nanocomposites with various nanoparticles. In this study, UV-curable polymer nanocomposites were prepared with the addition of different contents of silver nitrate via SLA technique for use in antibacterial applications. In-situ synthesis of AgNPs was achieved during the SLA process without any additional treatments. The effect of AgNO3 addition on the curing of the resin and the mechanical properties of the nanocomposite specimens were investigated. To understand the fracture mechanism of the nanocomposite samples, the fractured surfaces of the samples were evaluated by SEM, and the AgNO3 content of the nanocomposite was evaluated by EDX. The nanocomposites containing 0.3 wt. % AgNO3 exhibited improved mechanical properties. Further increasing the AgNO3 content to 3 wt. % led to deterioration in the physical and mechanical properties of the polymer nanocomposites.
Ethical Statement
The support of Gebze Technical University through Project 2023-A-101-15 is acknowledged.
Supporting Institution
Gebze Technical University
Project Number
GTU-BAP Project 2023-A-101-15
References
- Al Rashid A, Khan A, Al-Ghamdi SG, Koc M (2021) Additive manufacturing of polymer nanocomposites: Needs and challenges in materials, processes, and applications. Journal of Materials Research and Technology, 14:910-941. https://doi.org/10.1016/j.jmrt.2021.07.016
- Wu H, Fahy WP, Kim S, Kim H, Zhao N, Pilato L, Kafi A, Bateman S, Koo JH (2020) Recent developments in polymers/polymer nanocomposites for additive manufacturing. Progress in Materials Science, 111: 100638. https://doi.org/10.1016/j.pmatsci.2020.100638
- Ahangar P, Cooke ME, Weber MH, Rosenzweig DH (2019) Current biomedical applications of 3D printing and additive manufacturing. Applied Sciences, 9:1713. https://doi.org/10.3390/APP9081713
- Nachal N, Moses JA, Karthik P, Anandharamakrishnan C (2019) Applications of 3D printing in food processing. Food Engineering Reviews 11:123–141. https://doi.org/10.1007/S12393-019-09199-8
- Campbell TA, Ivanova OS (2013) 3D Printing of multifunctional nanocomposites. Nano Today, 8:119–120, https://doi.org/10.1016/j.nantod.2012.12.002
- Taormina G, Sciancalpore C, Messori M, Bondioli F (2018) Advanced resins for stereolithography: In situ generation of silver nanoparticles. AIP Conference Proceedings, 1981:20065. https://doi.org/10.1063/1.5045927
- Fantino E, Chiappone A, Roppolo I, Manfredi D, Bongiovanni R, Pirri CF, Calignano F (2016) 3D Printing of conductive complex structures with in situ generation of silver nanoparticles. Advanced Materials, 28(19):3712–3717. https://doi.org/10.1002/ADMA.201505109
- Kartal I., Ozcan Z. (2023) Investigation of effect of chestnut sawdust on mechanical properties of epoxy matrix composites. Journal of Innovative Engineering and Natural Science, 3(2):67-74. https://doi.org/10.29228/JIENS.69363
- Khalid MY, Imran R, Arif ZU, Akram N, Arshad H, Al Rashid A, Márquez FPG (2021) Developments in chemical treatments, manufacturing techniques and potential applications of natural-fibers-basedb biodegradable composites. Coatings, 11:293. https://doi.org/10.3390/COATINGS11030293
- Billings C (2023) Additive manufacturing and synthesis of advanced antibacterial and sensing photocurable polymer nanocomposites. Dissertation, University of Oklahoma.
- Sangermano M, Tagci Y, Rizza G (2007). In situ synthesis of silver-epoxy nanocomposites by photoinduced electron transfer and cationic polymerization processes. Macromolecules, 40:8827-8829. https://doi.org/10.1021/ma702051g
- Peerzada M, Abbasi S, Lau KT, Hameed N (2020). Additive manufacturing of epoxy resins: Materials, methods, and latest trends. Industrial&Engineering Chemistry Research, 59(14):6375-6390. https://doi.org/10.1021/acs.iecr.9b06870
- Bruna T, Maldonado-Bravo F, Jara P, Caro N (2021) Silver nanoparticles and their antibacterial applications. International Journal of Molecular Sciences, 22(13):7202. https://doi.org/10.3390/ijms22137202
- Valencia LM, Herrera M, de la Mata M, de León AS, Delgado FJ, Molina SI (2022) Synthesis of silver nanocomposites for stereolithography: in situ formation of nanoparticles. Polymers, 14(6):1168. https://doi.org/10.3390/polym14061168
- Yaragatti N, Patnaik A (2021) A review on additive manufacturing of polymers composites. Materials Today: Proceedings, 44:4150-4157. https://doi.org/10.1016/j.matpr.2020.10.490
- Anastasio R, Peerbooms W, Cardinaels R, Van Breemen LCA (2019) Characterization of ultraviolet-cured methacrylate networks: From photopolymerization to ultimate mechanical properties. Macromolecules, 52:9220–9231. https://doi.org/10.1021/ACS.MACROMOL.9B01439
- Singh N, Khyanna P (2007) In situ synthesis of silver nano-particles in polymethylmethacrylate. Materials Chemistry and Physics, 104 (2-3):367-372. https://doi.org/10.1016/j.matchemphys.2007.03.026
- Darman Singho N, Akmal Che Lah N, Rafie Johan M, Ahmad R (2012) FTIR Studies on silver-poly(methylmethacrylate) nanocomposites via in-situ polymerization technique. International Journal of Electrochemical Science, 7(6):5596-5603. https://doi.org/10.1016/S1452-3981(23)19646-5
- Siddiqui MN, Redhwi HH, Vakalopoulou E, Tsagkalias I, Ioannidou MD, Achilias DS (2015) Synthesis, characterization and reaction kinetics of PMMA/silver nanocomposites prepared via in situ radical polymerization. European Polymer Journal, 72:256–269. https://doi.org/10.1016/j.eurpolymj.2015.09.019
- Russ, J. C. (1984) Fundamentals of Energy Dispersive X-ray Analysis, Butterworths, London.
- https://www.edax.com/resources/posters/periodic-table-poster, accessed on 29.01.2024
- Chinni, S. V., Gopinath, S. C., Anbu, P., Fuloria, N. K., Fuloria, S., Mariappan, P., ... & Samuggam, S. (2021). Characterization and antibacterial response of silver nanoparticles biosynthesized using an ethanolic extract of Coccinia indica leaves. Crystals, 11(2), 97. https://doi.org/10.3390/cryst11020097
- Shaban, M., Ahmed, A., Abdel-Rahman, E., Hamdy, H. (2017) Tunability and Sensing Properties of Plasmonic/1D Photonic Crystal. Scientific Reports, 7, 41983. https://doi.org/10.1038/srep41983