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Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi

Year 2024, Volume: 5 Issue: 2, 369 - 382, 20.12.2024
https://doi.org/10.55546/jmm.1582242

Abstract

Bu çalışmada yüksek sertliğe, yüksek kırılma tokluğuna, yüksek sıcaklık oksidasyon direncine ve yüksek korozyon dayanımına sahip bir kompozit malzeme grubu üretmek için kullanılacak öncül Ni-Co-W-B metalik cam alaşımları geliştirilmiştir. Düşük bor içeriğine sahip Ni-Co-W-B metalik cam alaşımlarının geliştirilmesi için yapılan çalışmalara temel oluşturan alaşım Ni42.6Co20W20B17.4 alaşımıdır. Camlaşma kabiliyeti en yüksek alaşımları belirlemek için Ni, Co ve W miktarları sistematik olarak değiştirilmiştir. Bu çalışmalar sonucunda %13 B ve %15 B içeren metalik cam alaşımları geliştirilmiştir. % 13 B ve % 15 B içerikli alaşımların hepsinin kritik döküm kalınlıklarının 0.3 mm olduğu belirlenmiştir.

Supporting Institution

TÜBİTAK

Project Number

122M548

Thanks

Bu çalışma 122M548 No’lu TÜBİTAK projesi kapsamında desteklenmiştir.

References

  • Almound E. A., Roebuck B.W., Identification of optimum binder phase compositions for improved WC hard metals. Materials Science and Engineering 105, 237-248, 1998.
  • Borrel A., Salvador M. D., Rocha V. G., Fernandez A., Aviles A. M., Gotor J., Bulk TiCxN1-x –15%Co cermets obtained by directs park plasma sintering of Mechanochemical synthesized powders. Materials Research Bulletin 47, 4487-4490, 2012.
  • Chang S. H., Chen S. L., Characterization and properties of sintered Wc-Co and WC-Ni-Fe hard metal alloys. Journal of Alloys and Compounds 585, 407-413, 2014.
  • Han J. J., Wang C. P., Kou S. Z., Liu X. J., Thermal stability, crystallization behavior, Vickers hardness and magnetic properties of Fe-Co-Ni-Cr-Mo-C-B-Y bulk metallic glasses. Transactions of Nonferrous Metals Society of China (English Edition), 23(1), 148-155, 2013.
  • Hitit A., Yazıcı Z. O., Öztürk P., Şahin H., Aşgın A. M., Hitit B., A Ni-CoWB composite developed by devitrification of Ni-Co-W-B bulk metallic glass. Materials Science and Engineering A, 803, 140479, 2021.
  • Iqbal M., Akhter J. I., Zhang, H. F., Hu Z. Q., Synthesis and characterization of Bulk amorphous steels. Journal of Non-Crystalline Solids 354, 3284-3290, 2008.
  • Kim H. V., Son I. J., Yoon J. K., Doh J. M., Munir Z. A., Rapid sintering of ultrafine WC-Ni cermets. Int. Journal of Refractory Metals and Hard Materials 24, 427-431, 2006.
  • Liu K., Wang Z., Yin Z., Gao L., Yuan J., Effect of Co content on microstructure and mechanical properties of ultra fine grained WC-Co cemented carbide sintered by Spark plasma sintering. Ceramics International 44, 18711-18718, 2018.
  • Marques B. J., Feranandes C. M., Senos A. M. R., Sintering, microstructure and properties of WC-AISI304 powder composites. Journal of Alloys and Compounds 562, 164-170, 2013.
  • Su W., Wen Y., Zhang O., Effects of Ni and Cu additions on microstructures, Mechanical properties and wear resistances of ultra-coar segrained WC-6Co Cemented carbides. International Journal of Refractory Metals and Hard Materials 70, 176-183, 2018.
  • Venkateswaran T., Basu B., Raju G. B., Kim D. Y., Densification and properties of transition metal borides-based cermets via spark plasma sintering. Journal of the European Ceramic Society, 26, 2431-2440, 2006.
  • Yu H., Liu W., Zheng Y., Microstructure and mechanical properties of liquid phase Sintered Mo2FeB2 based cermets. Materials and Design 32(6), 3521-3525, 2011.
  • Zakhariev Z., Zlateva R., Petrov K., Microhardness and High-Temperature Oxidation Stability of CoWB. Journal of the Less-Common Metals 117, 129-133, 1986.
  • Zhang G., Xiong W., Yang O., Yao Z., Chen S., Chen X., Effect of Moaddition on Microstructure and mechanical properties of (Ti,W)C solid solution based cermets. Int. Journal of refractory Metals and Hard Materials 43, 77-82, 2014.
  • Zhang T., Yin H., Zhang C., Zhang R., Yang Z., Elder S., Jiang X., Deng Z., Yang G., Zheng Q., Qu X., Synthesis and microstructure evolution of WCoB based cermets durings spark plasma sintering. Ceramics International 45, 17536-17544, 2019.

Development of Ni-Co-W-B Bulk Metallic Glass Alloys with Low Boron Content for the Production of Ni-CoWB Composites

Year 2024, Volume: 5 Issue: 2, 369 - 382, 20.12.2024
https://doi.org/10.55546/jmm.1582242

Abstract

In this study, Ni-Co-W-B metallic glass alloys were developed as precursors to produce a composite material group with high hardness, high fracture toughness, high temperature oxidation resistance and high corrosion resistance. The alloy that forms the basis for the studies carried out for the development of Ni-Co-W-B metallic glass alloys with low boron content is Ni42.6Co20W20B17.4 alloy. In order to determine the alloys with the highest glass forming ability, the amounts of Ni, Co and W were systematically changed. As a result of these studies, metallic glass alloys containing 13 at.% B and 15 at. % B were developed. It was determined that the critical casting thicknesses of all alloys with 13 at.% B and 15 at.% B content were 0.3 mm.

Project Number

122M548

Thanks

This study was supported by TUBITAK project number 122M548.

References

  • Almound E. A., Roebuck B.W., Identification of optimum binder phase compositions for improved WC hard metals. Materials Science and Engineering 105, 237-248, 1998.
  • Borrel A., Salvador M. D., Rocha V. G., Fernandez A., Aviles A. M., Gotor J., Bulk TiCxN1-x –15%Co cermets obtained by directs park plasma sintering of Mechanochemical synthesized powders. Materials Research Bulletin 47, 4487-4490, 2012.
  • Chang S. H., Chen S. L., Characterization and properties of sintered Wc-Co and WC-Ni-Fe hard metal alloys. Journal of Alloys and Compounds 585, 407-413, 2014.
  • Han J. J., Wang C. P., Kou S. Z., Liu X. J., Thermal stability, crystallization behavior, Vickers hardness and magnetic properties of Fe-Co-Ni-Cr-Mo-C-B-Y bulk metallic glasses. Transactions of Nonferrous Metals Society of China (English Edition), 23(1), 148-155, 2013.
  • Hitit A., Yazıcı Z. O., Öztürk P., Şahin H., Aşgın A. M., Hitit B., A Ni-CoWB composite developed by devitrification of Ni-Co-W-B bulk metallic glass. Materials Science and Engineering A, 803, 140479, 2021.
  • Iqbal M., Akhter J. I., Zhang, H. F., Hu Z. Q., Synthesis and characterization of Bulk amorphous steels. Journal of Non-Crystalline Solids 354, 3284-3290, 2008.
  • Kim H. V., Son I. J., Yoon J. K., Doh J. M., Munir Z. A., Rapid sintering of ultrafine WC-Ni cermets. Int. Journal of Refractory Metals and Hard Materials 24, 427-431, 2006.
  • Liu K., Wang Z., Yin Z., Gao L., Yuan J., Effect of Co content on microstructure and mechanical properties of ultra fine grained WC-Co cemented carbide sintered by Spark plasma sintering. Ceramics International 44, 18711-18718, 2018.
  • Marques B. J., Feranandes C. M., Senos A. M. R., Sintering, microstructure and properties of WC-AISI304 powder composites. Journal of Alloys and Compounds 562, 164-170, 2013.
  • Su W., Wen Y., Zhang O., Effects of Ni and Cu additions on microstructures, Mechanical properties and wear resistances of ultra-coar segrained WC-6Co Cemented carbides. International Journal of Refractory Metals and Hard Materials 70, 176-183, 2018.
  • Venkateswaran T., Basu B., Raju G. B., Kim D. Y., Densification and properties of transition metal borides-based cermets via spark plasma sintering. Journal of the European Ceramic Society, 26, 2431-2440, 2006.
  • Yu H., Liu W., Zheng Y., Microstructure and mechanical properties of liquid phase Sintered Mo2FeB2 based cermets. Materials and Design 32(6), 3521-3525, 2011.
  • Zakhariev Z., Zlateva R., Petrov K., Microhardness and High-Temperature Oxidation Stability of CoWB. Journal of the Less-Common Metals 117, 129-133, 1986.
  • Zhang G., Xiong W., Yang O., Yao Z., Chen S., Chen X., Effect of Moaddition on Microstructure and mechanical properties of (Ti,W)C solid solution based cermets. Int. Journal of refractory Metals and Hard Materials 43, 77-82, 2014.
  • Zhang T., Yin H., Zhang C., Zhang R., Yang Z., Elder S., Jiang X., Deng Z., Yang G., Zheng Q., Qu X., Synthesis and microstructure evolution of WCoB based cermets durings spark plasma sintering. Ceramics International 45, 17536-17544, 2019.
There are 15 citations in total.

Details

Primary Language Turkish
Subjects Materials Engineering (Other)
Journal Section Research Articles
Authors

Cumali Dincer 0000-0001-7341-5993

Aytekin Hitit 0000-0003-2312-7840

Selinnur Aksu 0009-0002-8293-8803

Project Number 122M548
Publication Date December 20, 2024
Submission Date November 12, 2024
Acceptance Date December 12, 2024
Published in Issue Year 2024 Volume: 5 Issue: 2

Cite

APA Dincer, C., Hitit, A., & Aksu, S. (2024). Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi. Journal of Materials and Mechatronics: A, 5(2), 369-382. https://doi.org/10.55546/jmm.1582242
AMA Dincer C, Hitit A, Aksu S. Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi. J. Mater. Mechat. A. December 2024;5(2):369-382. doi:10.55546/jmm.1582242
Chicago Dincer, Cumali, Aytekin Hitit, and Selinnur Aksu. “Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi”. Journal of Materials and Mechatronics: A 5, no. 2 (December 2024): 369-82. https://doi.org/10.55546/jmm.1582242.
EndNote Dincer C, Hitit A, Aksu S (December 1, 2024) Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi. Journal of Materials and Mechatronics: A 5 2 369–382.
IEEE C. Dincer, A. Hitit, and S. Aksu, “Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi”, J. Mater. Mechat. A, vol. 5, no. 2, pp. 369–382, 2024, doi: 10.55546/jmm.1582242.
ISNAD Dincer, Cumali et al. “Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi”. Journal of Materials and Mechatronics: A 5/2 (December 2024), 369-382. https://doi.org/10.55546/jmm.1582242.
JAMA Dincer C, Hitit A, Aksu S. Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi. J. Mater. Mechat. A. 2024;5:369–382.
MLA Dincer, Cumali et al. “Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi”. Journal of Materials and Mechatronics: A, vol. 5, no. 2, 2024, pp. 369-82, doi:10.55546/jmm.1582242.
Vancouver Dincer C, Hitit A, Aksu S. Ni-CoWB Kompozitlerinin Üretimi İçin Düşük Bor İçeriğine Sahip Ni-Co-W-B İri Hacimli Metalik Cam Alaşımlarının Geliştirilmesi. J. Mater. Mechat. A. 2024;5(2):369-82.