Characterization of a diamond-like carbon film produced from an electrosynthesized pre-ceramic polymer

Year 2019, Volume: 8 Issue: 2, 74 - 81, 31.12.2019

Necati Başman Semra Ergen Cemil Alkan Orhan Uzun

Abstract

In this study, we aimed to prepare diamond-like carbon film from the electrosynthesized poly(hydridocarbyne) polymer and to investigate its surface, compositional and structural properties. The polymer was coated on Si substrate and then heated from room temperature to 1050 oC under argon atmosphere. More detailed characterizations than the previous studies revealed some new results. Surface morphology was examined by scanning electron microscopy. X-ray photoelectron spectroscopy analysis revealed that the film consisted of mainly carbon, with lesser percentages of oxygen, ferrum and silicium. From deconvolution of C 1s peak, sp3/sp2 ratio was found 0.55. Raman spectroscopy showed two broad bands at approximately 1347 cm-1 and 1597 cm-1, related to the D and G band of DLC, respectively. Furthermore, several peaks which were matched with the Fe3O4 and the Fe2SiO4 phase appeared in the Raman spectrum. Although these peaks were observed in the previous studies, they were not matched with any bound or structure. By means of analyses it was concluded that electrosynthesized polymer includes iron oxide due to the erosion of steel electrodes and this phase is also included in the DLC films produced from this polymer. Additionally, Fe2SiO4 is seen due to the reaction between iron oxide included in the polymer solution and Si substrate at the interface between the Si substrate and DLC film.

Keywords

Diamond-like carbon, Pre-ceramic polymers, Raman spectroscopy

Supporting Institution

Scientific Research Project Committee of Gaziosmanpaşa University and Turkish State Planning Organisation

Project Number

2010/14 and 2009/54 and 2003K120510

Thanks

We are indebted to the Scientific Research Project Committee of Gaziosmanpaşa University (Under the Grand Contract No: 2010/14 and 2009/54) and Turkish State Planning Organisation (Under the Grand Contract No: 2003K120510) for financial support.

Characterization of a diamond-like carbon film produced from an electrosynthesized pre-ceramic polymer

Abstract

Keywords

Diamond-like carbon, pre-ceramic polymer, Raman spectroscopy

Project Number

2010/14 and 2009/54 and 2003K120510

References

• [1] Sun Z, Shi X, Tay BK, Flynn D, et al. Morphological features of diamond films grown on diamond-like carbon films synthesized from polymer by chemical vapor deposition. Journal of Crystal Growth, 1997, 173:402-407
• [2] Zhang S, Nasar A Nanocomposite thin films and coatings: processing, properties and performance. London, Imperial College Press, 2007: 112
• [3] Zhang J, Huang L, Yu L, et al. Synthesis and tribological behaviors of diamond-like carbon films by electrodeposition from solution of acetonitrile and water. Applied Surface Science, 2008, 254:3896-3901
• [4] Donnet C, Erdemir A. Tribology of Diamond-Like Carbon Films. New York: Springer Science and Business Media, 2008: 28
• [5] Meškinis Š, Gudaitis R, Kopustinskas V, et al. Piezoresistive, optical and electrical properties of diamond like carbon and carbon nitride films. Diamond and Related Materials, 2010, 19:1249-1253
• [6] Zeng A, Neto VF, Gracio JJ, et al. Diamond-like carbon (DLC) films as electrochemical electrodes. Diamond & Related Materials, 2014, 43:12-22.
• [7] Yan XB, Xu T, Chen G, et al. Effect of deposition voltage on the microstructure of electrochemically deposited hydrogenated amorphous carbon films. Carbon, 2004, 42:3103-3108
• [8] Yan XB, Xu T, Chen G, et al. Preparation and characterization of amorphous hydrogenated carbon films containing Au nanoparticles from heat-treatment of polymer precursors. Appl. Phys. A, 2005, 81:97-203.
• [9] Wan S, Wang L, Xue Q. Electrochemical deposition of sulfur doped DLC nanocomposite film at atmospheric pressure. Electrochemistry Communications, 2010, 12:61-65
• [10] Nery RPOS, Bonelli RS, Camargo SS Jr. Evaluation of corrosion resistance of diamond-like carbon films deposited onto AISI 4340 steel. J Mater Sci, 2010, 45:5472-5477
• [11] Tao Y, Yi D, Zhu B, et al. Direct hydrothermal electrochemical preparation of diamond-like carbon films on substrates. J Mater Sci, 2011, 46:1136-1138
• [12] Chaus AS, Fedosenko TN, Rogachev AV, Čaplovič L. Surface, microstructure and optical properties of copper-doped diamond-like carbon coating deposited in pulsed cathodic arc plasma. Diamond and Related Materials, 2014, 42:64-70
• [13] Rusop M, Omer AMM, Adhikari S, et al. Effects of annealing temperature on the optical, bonding, structural and electrical properties of nitrogenated amorphous carbon thin films grown by surface wave microwave plasma chemical vapor deposition. J Mater Sci, 2006, 41:537-547
• [14] Zhang J, Huang L, Yu L, Zhang P. Synthesis and tribological behaviors of diamond-like carbon films by electrodeposition from solution of acetonitrile and water. Applied Surface Science, 2008, 254:3896–3901
• [15] Honglertkongsakul K, May PW, Paosawatyanyong B, Electrical and optical properties of diamond-like carbon films deposited by pulsed laser ablation. Diamond and Related Materials, 2010, 19:999-1002
• [16] Li Y, Zhang GF, X DH, Deng DW. Growth mechanism of carbon films from organic electrolytes, J Mater Sci, 2013 48:3505-3510
• [17] Visscher GT and Bianconi PA. Synthesis and characterization of polycarbynes, a new class of carbon-based network polymers. J Am Chem Soc, 1994, 116:1805-1811
• [18] Bianconi PA, Joray SJ, Aldrich BL, et al. Diamond and diamond-like carbon from a preceramic polymer. J Am Chem Soc, 2004, 126:3191-3202
• [19] Nur Y, Duygulu S, Pitcher MW, Toppare L. The electrochemical synthesis of poly(methylcarbyne) for diamond film coatings. Journal of Applied Polymer Science, 2011, 124:3626-3632
• [20] Nur Y., Pitcher, M.W., Seyyidoğlu, S. ve Toppare, L. Facile synthesis of poly(hydridocarbyne): a precursor to diamond and diamond-like ceramics. J Macr Sci Pure Appl Chem, 2008, 45:358-363
• [21] Nur Y, Cengiz HM, Pitcher MW, Toppare L. Electrochemical polymerizatıon of hexachloroethane to form poly(hydridocarbyne): a pre-ceramic polymer for diamond production. J Mater Sci, 2009, 44:2774-2779
• [22] Başman N, Uzun O, Fiat S, Alkan C, Çankaya G. Electrical characterization of a pre-ceramic polymer modified Ag/poly(hydridocarbyne)/p-Si Schottky barrier diode. J Mater Sci: Mater Electron, 2012, 23:2282-2288
• [23] Li RS, Liu B, Zhou M, et al. Effect of deposition voltage on the field emission properties of electrodeposited diamond-like carbon films. Applied Surface Science, 2009, 255:4754- 4757
• [24] Chen G, Zhang J, Yang S, A novel method for the synthesis of Au nanoparticles incorporated amorphous hydrogenated carbon films. Electrochemistry Communications, 2007, 9:1053-1056
• [25] Ferrari AC. Determination of bonding in diamond-like carbon by Raman Spectrocopy. Diamond and Related Materials, 2002, 11:1053-1061
• [26] Xu S, Flynn D, Tay BK, et al. Mechanical properties and Raman spectra of tetrahedral amorphous carbon films with high sp3 fraction deposited. Philosophical Magazine Part B, 1997, 76:351-361
• [27] Chen ZY, Zhao JP, Yano T, et al. Observation of sp3 bonding in tetrahedral amorphous carbon using visible Raman spectroscopy. J Appl Phys, 2000, 88: 2305-2308 [28] Liang H, Deliana L, Xian C, et al. The deposition of a thick tetrahedral amorphous carbon film by argon ion bombardment. Applied Surface Science, 2012, 258:4794-4800
• [29] Chopelas A. Single crystal Raman spectra of forsterite, fayalite, and monticellite. American Mineralogist, 1991, 76:1101-1109
• [30] Shebanova ON and Lazor P. Raman spectroscopic study of magnetite (Fe3O4): a new assignment for the vibrational spectrum. Journal of Solid State Chemistry, 2003, 174:424-430
• [31] Legodi MA and de Waal D. The preparation of magnetite, goethite, hematite and maghemite of pigment quality from mill scale iron waste. Dyes and Pigments, 2007, 74:161-168
• [32] Jubb AM, and Allen HC. Vibrational spectroscopic characterization of hematite, maghemite, and magnetite thin films produced by vapor deposition. Applied Materials and Interfaces, 2010, 2:2804-2812
• [33] Katzenmeyer AM, Bayam Y, Logeeswaran VJ, et al. Poly(hydridocarbyne) as highly processable ınsulating polymer precursor to micro/nanostructures and graphite conductors. Journal of Nanomaterials Article. ID 832327, 2009, 4 pages