Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator
Abstract
This work aims to investigate synthesis of Nickel based energetic materials as a replacement for lead based compounds. Commercially employed mixtures of lead azide, and lead styphnate are toxic, and very sensitive to friction, impact and heat. Nickel hydrazine nitrate (NHN) can be utilized as a safer choice for developing energetic materials due to its low mechanical sensitivity, good stability, and insensitivity towards light. Nickel based mixture was synthesized in lab-scale and compared to conventional mixtures in terms of efficacy as energetic material, safety during synthesis as well as in storage and handling. NHN is synthesized on batch method by hydrazine (80%) and nickel nitrate in the presence of Ethanol (80-90%). A comparatively study of LA, LS & NHN have been carried out and it is observed that NHN is more powerful than first two. It is concluded from results that NHN can replace LA & LS in primaries/Detonators where flash is involved. Promising results were obtained that may require validation before commercial application.
Keywords
References
- Shafi Ullah Khan, J Ong Chem Res, 2020, 5(2), 78-79, Document ID: 2020JOCR50, DOI
Details
Primary Language
English
Subjects
Organic Chemistry
Journal Section
Conference Paper
Publication Date
December 31, 2020
Submission Date
May 12, 2020
Acceptance Date
-
Published in Issue
Year 2020 Volume: 5 Number: 2
APA
Ullah Khan, S., & Imran Ahmad, M. (2020). Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator. Journal of Ongoing Chemical Research, 5(2), 78-79. https://izlik.org/JA32NG45GZ
AMA
1.Ullah Khan S, Imran Ahmad M. Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator. jocr. 2020;5(2):78-79. https://izlik.org/JA32NG45GZ
Chicago
Ullah Khan, Shafi, and Muhammad Imran Ahmad. 2020. “Process Optimization for Synthesis of Ni-Based Compounds As Initiator, Primer Detonator”. Journal of Ongoing Chemical Research 5 (2): 78-79. https://izlik.org/JA32NG45GZ.
EndNote
Ullah Khan S, Imran Ahmad M (December 1, 2020) Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator. Journal of Ongoing Chemical Research 5 2 78–79.
IEEE
[1]S. Ullah Khan and M. Imran Ahmad, “Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator”, jocr, vol. 5, no. 2, pp. 78–79, Dec. 2020, [Online]. Available: https://izlik.org/JA32NG45GZ
ISNAD
Ullah Khan, Shafi - Imran Ahmad, Muhammad. “Process Optimization for Synthesis of Ni-Based Compounds As Initiator, Primer Detonator”. Journal of Ongoing Chemical Research 5/2 (December 1, 2020): 78-79. https://izlik.org/JA32NG45GZ.
JAMA
1.Ullah Khan S, Imran Ahmad M. Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator. jocr. 2020;5:78–79.
MLA
Ullah Khan, Shafi, and Muhammad Imran Ahmad. “Process Optimization for Synthesis of Ni-Based Compounds As Initiator, Primer Detonator”. Journal of Ongoing Chemical Research, vol. 5, no. 2, Dec. 2020, pp. 78-79, https://izlik.org/JA32NG45GZ.
Vancouver
1.Shafi Ullah Khan, Muhammad Imran Ahmad. Process Optimization for Synthesis of Ni-based Compounds as Initiator, Primer/Detonator. jocr [Internet]. 2020 Dec. 1;5(2):78-9. Available from: https://izlik.org/JA32NG45GZ