SYNTHESIS OF NOVEL NAKED-EYE FE3+ CHEMOSENSING SILICA PARTICLES AND RH+3 COMPLEX BASED ON 4- 1H-IMIDAZO[4,5-F][1,10]PHENANTHROLINE-2YLPHENOL

Year 2015, Volume: 2 Issue: 1, 28 - 42, 01.06.2015

Mehmet Ali Özler Said Nadeem

Abstract

A Rh3+ complex 4 derived from 4- 1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl phenol 3 was prepared at room temperature. 3 was stirred with pentamethylcyclopentadienlyrhodium chloride dimer for 30 minutes which resulted yellow precipitates which were washed with methanol, redissolved in acetone and purified chromatographically with ethanol. Phenanthroline-derived 3 was reacted with 3-chloropropyl trimethoxysilane to obtain an alkylated compound 5. Silica particles were functionalized by reacting with 5 at 70 oC in DMF for 6 h. Functionalized silica particles can be used for removal of different metals from aqueous and organic solutions and due to their bigger size can be easily filtered

Keywords

1, 10-phenanthroline, fluorescence, functionalized silica particles, Rh-complex, metal removal

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