Research Article
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Year 2023, , 129 - 138, 28.02.2023
https://doi.org/10.18596/jotcsa.1194323

Abstract

References

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  • 20. Sadlapurkar AV, Barache UB, Shaikh AB, Dhale PC, Gaikwad SH, Lokhande TN. Statistically designed extractive spectrophotometric determination scheme for bismuth(III) with 2-chlorobenzaldehyde thiocarbohydrazone: Analysis of environmental and real resources. Chemical Data Collections. 2022 Feb;37:100798. Availabe from: <URL>.
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Synthesis, Spectral Characterization, Crystal Structure, and Antioxidant Properties of novel Palladium(II) Complex from ONS Donor 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone

Year 2023, , 129 - 138, 28.02.2023
https://doi.org/10.18596/jotcsa.1194323

Abstract

A new Pd(II) complex, [Pd(PPh3)(L)] (L = 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone, PPh3 = triphenylphosphine), was synthesized and characterized by FTIR, 1H NMR and UV-Vis spectroscopies and elemental analysis. The molecular structure of [Pd(PPh3)(L)] was confirmed by the single-crystal X-ray diffraction technique. Palladium ion has distorted square planar geometry according to X-ray diffraction studies. The free thiocarbohydrazone (L), potentially a pentadentate ONSNO donor, acted as a tridentate ONS donor. The antioxidant capacity of the free thiocarbohydrazone and Pd(II) complex was determined using the CUPRAC (cupric reducing antioxidant capacity) method. Also, the DPPH method was used to test the free radical scavenging activity of the free thiocarbohydrazone and Pd(II) complex. Antioxidant activity studies showed that free thiocarbohydrazone exhibited better activity than Pd(II) complex.

Thanks

I dedicate this paper to Prof. Dr. Ayşe ERÇAĞ, the mentor of my research career.

References

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  • 5. Bonaccorso C, Marzo T, La Mendola D. Biological Applications of Thiocarbohydrazones and Their Metal Complexes: A Perspective Review. Pharmaceuticals. 2019 Dec 25;13(1):4.
  • 6. Nalawade A, Nalawade R, Londhe B, Tarwal N, Shejwal R. Microwave assisted synthesis, structure, spectral characterization and biological studies of (e)-n’-(4-fluoro benzylidene) hydrazinecarbothiohydrazide. International Journal of Pharmaceutical Science Invention. 2015;4(5):1–4.
  • 7. Zafarian H, Sedaghat T, Motamedi H, Amiri Rudbari H. A multiprotic ditopic thiocarbohydrazone ligand in the formation of mono- and di-nuclear organotin(IV) complexes: Crystal structure, antibacterial activity and DNA cleavage. Journal of Organometallic Chemistry. 2016 Dec;825–826:25–32.
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  • 9. Melha KSA. In-vitro antibacterial, antifungal activity of some transition metal complexes of thiosemicarbazone Schiff base (HL) derived from N 4 -(7′-chloroquinolin-4′-ylamino) thiosemicarbazide. Journal of Enzyme Inhibition and Medicinal Chemistry. 2008 Jan 1;23(4):493–503.
  • 10. Parsekar SU, Paliwal K, Haldar P, Antharjanam PKS, Kumar M. Synthesis, Characterization, Crystal Structure, DNA and HSA Interactions, and Anticancer Activity of a Mononuclear Cu(II) Complex with a Schiff Base Ligand Containing a Thiadiazoline Moiety. ACS Omega. 2022 Jan 25;7(3):2881–96.
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  • 13. Kaya Y, Erçağ A, Koca A. New square-planar nickel(II)-triphenylphosphine complexes containing ONS donor ligands: Synthesis, characterization, electrochemical and antioxidant properties. Journal of Molecular Structure. 2020 Apr;1206:127653.
  • 14. Kaya Y, Erçağ A, Uğuz Ö, Koca A, Zorlu Y, Hacıoğlu M, et al. New asymmetric bisthiocarbohydrazones and their mixed ligand nickel(II) complexes: Synthesis, characterization, crystal structure, electrochemical-spectroelectrochemical property, antimicrobial and antioxidant activity. Polyhedron. 2021 Oct;207:115372.
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  • 22. Priyarega S, Kalaivani P, Prabhakaran R, Hashimoto T, Endo A, Natarajan K. Nickel(II) complexes containing thiosemicarbazone and triphenylphosphine: Synthesis, spectroscopy, crystallography and catalytic activity. Journal of Molecular Structure. 2011 Sep;1002(1–3):58–62.
  • 23. Shabbir M, Akhter Z, Ashraf AR, Ismail H, Habib A, Mirza B. Nickel(II) and palladium(II) triphenylphosphine complexes incorporating tridentate Schiff base ligands: Synthesis, characterization and biocidal activities. Journal of Molecular Structure. 2017 Dec;1149:720–6.
  • 24. Rohlík Z, Holzhauser P, Kotek J, Rudovský J, Němec I, Hermann P, et al. Synthesis and coordination properties of palladium(II) and platinum(II) complexes with phosphonated triphenylphosphine derivatives. Journal of Organometallic Chemistry. 2006 May;691(11):2409–23. Available from: 10.1016/j.jorganchem.2006.01.024.
  • 25. Tan CP, Lu YY, Ji LN, Mao ZW. Metallomics insights into the programmed cell death induced by metal-based anticancer compounds. Metallomics. 2014;6(5):978.
  • 26. Elsayed SA, Badr HE, di Biase A, El-Hendawy AM. Synthesis, characterization of ruthenium(II), nickel(II), palladium(II), and platinum(II) triphenylphosphine-based complexes bearing an ONS-donor chelating agent: Interaction with biomolecules, antioxidant, in vitro cytotoxic, apoptotic activity and cell cycle analysis. Journal of Inorganic Biochemistry. 2021 Oct;223:111549.
  • 27. Anu D, Naveen P, Devendhiran T, Shyamsivappan S, Kumarasamy K, Lin MC, et al. Synthesis, spectral characterization, X-ray crystallography and biological evaluations of Pd(II) complexes containing 4(N)-substituted thiosemicarbazone. Journal of Coordination Chemistry. 2021 Dec 17;74(21–24):3153–69.
  • 28. Nadeem S, Bolte M, Ahmad S, Fazeelat T, Tirmizi SA, Rauf MK, et al. Synthesis, crystal structures and, antibacterial and antiproliferative activities in vitro of palladium(II) complexes of triphenylphosphine and thioamides. Inorganica Chimica Acta. 2010 Oct;363(13):3261–9.
  • 29. Shanmugapriya A, Jain R, Sabarinathan D, Kalaiarasi G, Dallemer F, Prabhakaran R. Structurally different mono-, bi- and trinuclear Pd( ii ) complexes and their DNA/protein interaction, DNA cleavage, and anti-oxidant, anti-microbial and cytotoxic studies. New J Chem. 2017;41(18):10324–38.
  • 30. Ayyannan G, Mohanraj M, Gopiraman M, Uthayamalar R, Raja G, Bhuvanesh N, et al. New Palladium(II) complexes with ONO chelated hydrazone ligand: Synthesis, characterization, DNA/BSA interaction, antioxidant and cytotoxicity. Inorganica Chimica Acta. 2020 Nov;512:119868.
  • 31. Khan H, Badshah A, Said M, Murtaza G, Sirajuddin M, Ahmad J, et al. Synthesis, structural characterization and biological screening of heteroleptic palladium(II) complexes. Inorganica Chimica Acta. 2016 Jun;447:176–82.
  • 32. Kavitha P, Laxma Reddy K. Pd(II) complexes bearing chromone based Schiff bases: Synthesis, characterisation and biological activity studies. Arabian Journal of Chemistry. 2016 Sep;9(5):640–8.
  • 33. Boubakri L, Mansour L, Harrath AH, Özdemir I, Yaşar S, Hamdi N. N-Heterocyclic carbene-Pd(II)-PPh 3 complexes as a new highly efficient catalyst system for the Sonogashira cross-coupling reaction: Synthesis, characterization and biological activities. Journal of Coordination Chemistry. 2018 Jan 17;71(2):183–99.
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  • 37. Asma M, Badshah A, Ali S, Sohail M, Fettouhi M, Ahmad S, et al. Synthesis, Characterization of Mixed Ligand Palladium(II) Complexes of Triphenylphosphine and Anilines and their Enzyme Inhibition Studies against β-glucuronidase. The Crystal Structure of trans-dichloro-(m-chloroaniline)(triphenylphosphine)palladium(II). Transition Met Chem. 2006 May;31(4):556–9.
  • 38. Shabbir M, Akhter Z, Ahmad I, Ahmed S, Shafiq M, Mirza B, et al. Schiff base triphenylphosphine palladium (II) complexes: Synthesis, structural elucidation, electrochemical and biological evaluation. Journal of Molecular Structure. 2016 Aug;1118:250–8.
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There are 59 citations in total.

Details

Primary Language English
Subjects Inorganic Chemistry
Journal Section Articles
Authors

Yeliz Kaya 0000-0001-5606-8088

Publication Date February 28, 2023
Submission Date October 25, 2022
Acceptance Date December 19, 2022
Published in Issue Year 2023

Cite

Vancouver Kaya Y. Synthesis, Spectral Characterization, Crystal Structure, and Antioxidant Properties of novel Palladium(II) Complex from ONS Donor 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone. JOTCSA. 2023;10(1):129-38.