Removal of Methyl Orange from Aqueous Solution Using Orange Peel as a Low Cost Adsorbent

Year 2024, , 39 - 46, 04.02.2024

Ahmed Lawal , Abdulhafeez Abdulsalam

https://doi.org/10.18596/jotcsa.1313059

Cited By: 2

Abstract

The objective of this research was to evaluate the feasibility of using orange peels as a low-cost adsorbent to remove methyl orange (MO) from water solutions. The orange peel adsorbent underwent characterization through Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) Spectroscopy to determine its properties before and after adsorption. A series of batch adsorption experiments were carried out to investigate the effects of various parameters such as contact time, adsorbent dosage, particle size, and initial dye concentration on the adsorption process. In each case, varying the value of the parameter of interest while keeping all other parameters constant. Results revealed that the highest removal of the dye from the adsorbent was achieved at a contact time of 90 min, the adsorbent dosage of 0.5 g, a particle size of less than 63 µm, and an initial concentration of 300 mg/L. Furthermore, the adsorption rate increased with increasing contact time, adsorbent dosage, and initial concentration, while it decreased with increasing particle size of the adsorbent. Concentrations of methyl orange were analyzed using a UV-Vis spectrophotometer. The experimental equilibrium data was analyzed using Langmuir and Freundlich isotherm models. The Langmuir isotherm provided the best fit for the experimental data with a correlation coefficient value of 0.9964 and a maximum adsorption capacity of 17.69 mg/g.

Keywords

Adsorbent, Orange Peel, Methyl Orange

References

• 1. Rashid R, Shafiq I, Akhter P, Iqbal MJ, Hussain M. A state-of-the-art review on wastewater treatment techniques: the effectiveness of adsorption method. Environmental Science and Pollution Research 2021 Feb 1;28(8):9050–66. Available from: <URL>
• 2. Dakhil IH. Recycling of agriculture wastes for efficient removal of methyl orange dye using batch adsorption unit. IOP Conference Series: Materials Science and Engineering. 2020 Jul;881(1):012186. Available from: <URL>
• 3. Fallah S, Mamaghani HR, Yegani R, Hajinajaf N, Pourabbas B. Use of graphene substrates for wastewater treatment of textile industries. Advanced Composites and Hybrid Materials. 2020 Jun 1;3(2):187–93. Available from: <URL>
• 4. Ali AF, Atwa SM, El-Giar EM. 6 - Development of magnetic nanoparticles for fluoride and organic matter removal from drinking water. In: Grumezescu AM, editor. Water Purification [Internet]. Academic Press; 2017 [cited 2023 Apr 5]. p. 209–62. Available from: <URL>
• 5. Tang Y, Yang R, Ma D, Zhou B, Zhu L, Yang J. Removal of methyl orange from aqueous solution by adsorption onto a hydrogel composite. Polymers and Polymer Composites. 2018 Feb 1;26(2):161–8. Available from: <URL>
• 6. Lakshmana Naik R, Rupas Kumar M, Bala Narsaiah T. Removal of heavy metals (Cu & Ni) from wastewater using rice husk and orange peel as adsorbents. Materials Today: Proceedings. 2023 Jan 1;72:92–8. Available from: <URL>
• 7. Krika F, Benlahbib O el F. Removal of methyl orange from aqueous solution via adsorption on cork as a natural and low-coast adsorbent: equilibrium, kinetic and thermodynamic study of removal process. Desalination and Water Treatment. 2015 Mar 27;53(13):3711–23. Available from: <URL>
• 8. Deshmukh P, Khadse G, Shinde V, Labhasetwar P. Cadmium removal from aqueous solutions using dried banana peels as an adsorbent: kinetics and equilibrium modeling. Journal of Bioremediation and Biodegradation. 2017 Apr 24;08. Available from: <URL>
• 9. Bhattacharya AK, Naiya TK, Mandal SN, Das SK. Adsorption, kinetics and equilibrium studies on removal of Cr(VI) from aqueous solutions using different low-cost adsorbents. Chemical Engineering Journal. 2008 Apr 15;137(3):529–41. Available from: <URL>
• 10. Eljiedi AAA, Kamari A. Removal of methyl orange and methylene blue dyes from aqueous solution using lala clam (Orbicularia orbiculata) shell. AIP Conference Proceedings. 2017 May 19;1847(1):040003. Available from: <URL>
• 11. Subbaiah MV, Kim DS. Adsorption of methyl orange from aqueous solution by aminated pumpkin seed powder: Kinetics, isotherms, and thermodynamic studies. Ecotoxicology and Environmental Safety. 2016 Jun 1;128:109–17. Available from: <URL>
• 12. Mallakpour S, Hatami M. An effective, low-cost and recyclable bio-adsorbent having amino acid intercalated LDH@Fe3O4/PVA magnetic nanocomposites for removal of methyl orange from aqueous solution. Applied Clay Science. 2019 Jun 15;174:127–37. Available from: <URL>
• 13. Arami M, Limaee NY, Mahmoodi NM, Tabrizi NS. Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies. Journal of Colloid and Interface Science. 2005 Aug 15;288(2):371–6. Available from: <URL>
• 14. Mafra MR, Igarashi-Mafra L, Zuim DR, Vasques ÉC, Ferreira MA. Adsorption of remazol brilliant blue on an orange peel adsorbent. Brazilian Journal of Chemical Engineering. 2013 Sep;30:657–65. Available from: <URL>
• 15. Kratochvil D, Volesky B. Advances in the biosorption of heavy metals. Trends in Biotechnology. 1998 Jul 1;16(7):291–300. Available from: <URL>
• 16. Liu T. Treatment of model wastewater including eriochrome black t based on eggshell membrane. Advanced Materials Research. 2011;183–185:2120–3. Available from: <URL>
• 17. Omar S, Yusoff NSM, Muhamad MS, Hamidon N, Hamid NHA, Harun H, et al. The characterization of banana blossom peel and floret as an adsorbent for the removal of manganese from groundwater. Mater Sci Forum. 2020 Mar;981:362—8. <URL>.
• 18. Rattanapan S, Srikram J, Kongsune P. Adsorption of methyl orange on coffee grounds activated carbon. Energy Procedia. 2017 Oct 1;138:949–54. Available from: <URL>
• 19. Li WH, Yue QY, Gao BY, Ma ZH, Li YJ, Zhao HX. Preparation and utilization of sludge-based activated carbon for the adsorption of dyes from aqueous solutions. Chemical Engineering Journal. 2011 Jun 15;171(1):320–7. Available from: <URL>
• 20. Mozaffari Majd M, Kordzadeh-Kermani V, Ghalandari V, Askari A, Sillanpää M. Adsorption isotherm models: A comprehensive and systematic review (2010−2020). Science of The Total Environment. 2022 Mar 15;812:151334. Available from: <URL>.