Iodine–β-Cyclodextrin: An Effective Corrosion Inhibitor for Carbon Steel in Sulfuric Acid Solution - Experimental Design and Investigating Thermodynamic Parameters

Year 2024, , 161 - 170, 04.02.2024

Tarik Attar , Abbes Benchadlı , Esma Choukchou Braham , Amal Benkhaled

https://doi.org/10.18596/jotcsa.1346065

Cited By: 2

Abstract

Widely used across industries, carbon steel is vulnerable to corrosion in aggressive environments, especially acidic ones. Thus, effective methods to mitigate metal corrosion from acids are crucial. Inhibitors are extensively used to prevent corrosion in industries, with the potential for improved protective performance. The design of experiments was employed to determine the optimal conditions for enhancing the inhibitor efficiency of Iodine–β-Cyclodextrin (Iodine/β-CD) in a sulfuric acid solution at temperatures ranging from 20°C to 50°C. The relationship between the factors and responses was established using response surface methodology (RSM), employing regression statistical analysis and probabilistic analysis. A single response was recorded: inhibitor efficiency was determined by measuring weight loss before and after immersion in the inhibitor solution. Thermodynamic parameters were also computed to determine adsorption and activation processes. The statistical analysis revealed that the quadratic models for inhibition efficiencies (IE) were highly significant with a coefficient of multiple regressions R2= 0.997. Further validation of the model indicated a good fit (R2 Adj= 0.994), and the experimentally observed values aligned well with predicted ones, demonstrating a highly significant model with Q2= 0.978. The theoretical efficiency predicted by the RSM model was 88.41%, whereas the efficiency observed during the experimental test procedure with the best-evaluated variables was 82.45%. In conclusion, this paper aims to identify the optimal conditions for employing Iodine–β-Cyclodextrin as a new corrosion inhibitor for carbon steel, utilizing experimental design methods. The results indicate that iodine/β-CD exhibits remarkable corrosion inhibitory properties for carbon steel under specific conditions.

Keywords

Corrosion inhibition, carbon steel, Iodine–β-Cyclodextrin, Thermodynamic and kinetic parameters, Response surface methodology, Optimization

Thanks

The authors wish to express their appreciation to the Ministry of Higher Education and Scientific Research of the Algerian Government for their invaluable support.

References

• 1. Tamalmani K, Husin H. Review on Corrosion Inhibitors for Oil and Gas Corrosion Issues. Appl Sci [Internet]. 2020 May 14;10(10):3389. Available from: <URL>.
• 2. Benchadli A, Attar T, Choukchou-Braham E. Inhibition of Carbon Steel Corrosion in Perchloric Acid Solution by Povidone Iodine. Phys Chem Res [Internet]. 2019 Dec 1;7(4):837–48. Available from: <URL>.
• 3. Ortega Ramirez AT, Barrantes L, Casallas Martin BD, Cortés Salazar N. Application of green inhibitors for corrosion control in metals. review. DYNA [Internet]. 2021 May 20;88(217):160–8. Available from: <URL>.
• 4. Barrahi M, Elhartiti H, Saadouni M. Corrosion inhibition of mild steel by Fennel seeds (Foeniculum vulgare Mill) essential oil in 1 M hydrochloric acid solution. Int J Corros Scale Inhib [Internet]. 2019 Dec 26;8(4):937–53. Available from: <URL>.
• 5. Petrunin MA, Gladkikh NA, Maleeva MA, Maksaeva LB, Yurasova TA. The use of organosilanes to inhibit metal corrosion. A review. Int J Corros Scale Inhib [Internet]. 2019 Dec 26;8(4):882–907. Available from: <URL>.
• 6. Attar T, Nouali F, Kibou Z, Benchadli A, Messaoudi B, Choukchou-Braham E, et al. Corrosion inhibition, adsorption and thermodynamic properties of 2-aminopyridine derivatives on the corrosion of carbon steel in sulfuric acid solution. J Chem Sci [Internet]. 2021 Dec 19;133(4):109. Available from: <URL>.
• 7. Yamin JAA, Sheet EAE, Al-Amiery AA. ANN and DOE Analysis of Corrosion Resistance Inhibitor for Mild Steel Structures in Iraq. Mod Appl Sci [Internet]. 2019 Mar 31;13(4):80–8. Available from: <URL>.
• 8. Salman TA, Salman TA, Al-Amiery AA, Shaker LM, Kadhum AAH, Takriff MS. A study on the inhibition of mild steel corrosion in hydrochloric acid environment by 4-methyl-2-(pyridin-3-yl)thiazole-5-carbohydrazide. Int J Corros Scale Inhib [Internet]. 2019 Dec 26;8(4):1035–59. Available from: <URL>.
• 9. Benchadli A, Attar T, Messaoudi B, Choukchou-Braham E. Polyvinylpyrrolidone as a Corrosion Inhibitor for Carbon Steel in a Perchloric Acid Solution: Effect of Structural Size. Hungarian J Ind Chem [Internet]. 2021 Sep 21;49(1):59–69. Available from: <URL>.
• 10. Bouraoui MM, Chettouh S, Chouchane T, Khellaf N. Inhibition Efficiency of Cinnamon Oil as a Green Corrosion Inhibitor. J Bio- Tribo-Corrosion [Internet]. 2019 Mar 23;5(1):28. Available from: <URL>.
• 11. Attar T, Benkhaled A, Benchadli A, Choukchou-braham E. Etude de l’inhibition de la corrosion de l’acier au carbone en milieu sulfurique par polyéthylène glycol. Rev des matériaux énergies renouvelables [Internet]. 2022 Mar 28;6(1):1–7. Available from: <URL>.
• 12. Zarrok H, Zarrouk A, Salghi R, Ramli Y, Hammouti B, Al-Deyab SS, et al. Adsorption and Inhibition Effect of 3-Methyl-1-Propargylquinoxalin-2(1H)-One on Carbon Steel Corrosion in Hydrochloric Acid. Int J Electrochem Sci [Internet]. 2012 Sep 1;7(9):8958–73. Available from: <URL>.
• 13. Harada A. Cyclodextrin-Based Molecular Machines. Acc Chem Res [Internet]. 2001 Jun 1;34(6):456–64. Available from: <URL>.
• 14. Zhang J, Ma PX. Cyclodextrin-based supramolecular systems for drug delivery: Recent progress and future perspective. Adv Drug Deliv Rev [Internet]. 2013 Aug 1;65(9):1215–33. Available from: <URL>.
• 15. Wang T, Li B, Feng Y, Guo Q. Preparation, quantitive analysis and bacteriostasis of solid state iodine inclusion complex with β-cyclodextrin. J Incl Phenom Macrocycl Chem [Internet]. 2011 Feb 5;69(1–2):255–62. Available from: <URL>.
• 16. Polumbryk M, Kravchenko V, Pasichnyi V, Omelchenko C, Pachitskaya I. The effect of intake of sausages fortified with β-CD-I2 complex on iodine status and thyroid function: A preliminary study. J Trace Elem Med Biol [Internet]. 2019 Jan 1;51:159–63. Available from: <URL>.
• 17. Benchadli A, Mellal T, Attar T, Dali Youcef B, Choukchou-Braham E. Optimization of inhibition efficiencies process of polyvinylpyrrolidone using response surface methodology. Rev Mex Física [Internet]. 2022 Jun 23;68(4):041003. Available from: <URL>.
• 18. Omran MA, Fawzy M, Mahmoud AED, Abdullatef OA. Optimization of mild steel corrosion inhibition by water hyacinth and common reed extracts in acid media using factorial experimental design. Green Chem Lett Rev [Internet]. 2022 Jan 2;15(1):216–32. Available from: <URL>.
• 19. Attar T, Benchadli A, Mellal T, Youcef BD, Choukchou- Braham E. Use of Experimental Designs to Evaluate the Influence of Methyl Green Dye as a Corrosion Inhibitor for Carbon Steel in Perchloric Acid. Malaysian J Chem [Internet]. 2021;23(1):60–9. Available from: <URL>.
• 20. Kumari P, Lavanya M. Optimization of Inhibition Efficiency of a Schiff Base on Mild Steel in Acid Medium: Electrochemical and RSM Approach. J Bio- Tribo-Corrosion [Internet]. 2021 Sep 9;7(3):110. Available from: <URL>.
• 21. Haladu SA, Dalhat Mu’azu N, Ali SA, Elsharif AM, Odewunmi NA, Abd El-Lateef HM. Inhibition of mild steel corrosion in 1 M H2SO4 by a gemini surfactant 1,6-hexyldiyl-bis-(dimethyldodecylammonium bromide): ANN, RSM predictive modeling, quantum chemical and MD simulation studies. J Mol Liq [Internet]. 2022 Mar 15;350:118533. Available from: <URL>.
• 22. Attar T, Benchadli A, Messaoudi B, Choukchou-Braham E. Corrosion Inhibition Efficiency, Experimental and Quantum Chemical Studies of Neutral Red Dye for Carbon Steel in Perchloric Acidic Media. Chem Chem Technol [Internet]. 2022 Sep 30;16(3):440–7. Available from: <URL>.
• 23. Attar T, Benchadli A, Choukchou-Braham E. View of Corrosion inhibition of carbon steel in perchloric acid by potassium iodide. Int J Adv Chem [Internet]. 2019;7(1):35–41. Available from: <URL>.
• 24. Attar T, Benchadli A, Boulanouar M, Choukchou-Braham E. Corrosion Inhibition, Adsorption and Thermodynamic Properties of Poly (Sodium 4-Styrenesulfonate) on Carbon Steel in Phosphoric Acid Medium. French-Ukrainian J Chem [Internet]. 2022 Jul 14;10(1):70–83. Available from: <URL>.
• 25. Attar T, Benchadli A, Choukchou-Braham E. Inhibition of corrosion of copper by polyvinylpyrrolidone-iodine in sulfuric acid medium. Alger J Mater Chem [Internet]. 2022;5(1):1–8. Available from: <URL>.
• 26. Salam K, Agarry S, Arinkoola A, Shoremekun I. Optimization of operating conditions affecting microbiologically influenced corrosion of mild steel exposed to crude oil environments using response surface methodology. Br Biotechnol J. 2015;7(2):68–78.
• 27. Attar T, Choukchou-Braham E, Youcef BD, Benchadli A, Mellal T, Benabdelkader I. Application of polyvinylpyrrolidone-iodine complex as corrosion inhibitor for carbon steel using an experimental design method. Alger J Eng Technol [Internet]. 2022 Jun 28;6:14–8. Available from: <URL>.
• 28. Dennison TJ, Smith J, Hofmann MP, Bland CE, Badhan RK, Al-Khattawi A, et al. Design of Experiments to Study the Impact of Process Parameters on Droplet Size and Development of Non-Invasive Imaging Techniques in Tablet Coating. Sung S-Y, editor. PLoS One [Internet]. 2016 Aug 22;11(8):e0157267. Available from: <URL>.
• 29. Gao X, Dai K, Wang Z, Wang T, He J. Establishing quantitative structure tribo-ability relationship model using Bayesian regularization neural network. Friction [Internet]. 2016 Jun 28;4(2):105–15. Available from: <URL>.
• 30. Hamzat AK, Adediran IA, Alhems LM, Riaz M. Investigation of Corrosion Rate of Mild Steel in Fruit Juice Environment Using Factorial Experimental Design. Int J Corros [Internet]. 2020 Feb 27;2020:5060817. Available from: <URL>.
• 31. Sulaimon AA, Murungi PI, Tackie-Otoo BN, Nwankwo PC, Bustam MA. Quantitative and qualitative analyses of grafted okra for corrosion inhibition of mild steel in acidic medium. Front Chem [Internet]. 2023 Feb 24;11:1129673. Available from: <URL>.
• 32. Khormali A, Ahmadi S. Experimental and modeling analysis on the performance of 2-mercaptobenzimidazole corrosion inhibitor in hydrochloric acid solution during acidizing in the petroleum industry. J Pet Explor Prod Technol [Internet]. 2023 Nov 15;13(11):2217–35. Available from: <URL>.
• 33. Attar T, Benchadli A, Messaoudi B, Benhadria N, Choukchou-Braham E. Experimental and Theoretical Studies of Eosin Y Dye as Corrosion Inhibitors for Carbon Steel in Perchloric Acid Solution. Bull Chem React Eng Catal [Internet]. 2020 Aug 1;15(2):454–64. Available from: <URL>.
• 34. Attar T, Messaoudi B, Benchadli A, Seghiour I, Zenasni MA, Bousalem S, et al. Experimental and theoretical studies of polyvinylpyrrolidone-iodine on carbon steel corrosion in 1M hydrochloric solution. Rev Roum Chim [Internet]. 2021;66(8–9):761–70. Available from: <URL>.
• 35. Yang X, Fu S, Wang Q, Sun Q, Zhang J, Peng Y, et al. Protective behaviour of naphthylamine derivatives for steel reinforcement in the simulated concrete pore solutions: Detailed experimental and computational explorations. J Mol Struct [Internet]. 2022 Dec 15;1270:133898. Available from: <URL>.
• 36. Ahmed AH, Sherif E-SM, Abdo HS, Gad ES. Ethanedihydrazide as a Corrosion Inhibitor for Iron in 3.5% NaCl Solutions. ACS Omega [Internet]. 2021 Jun 8;6(22):14525–32. Available from: <URL>.
• 37. Danaee I, RameshKumar S, RashvandAvei M, Vijayan M. Electrochemical and Quantum Chemical Studies on Corrosion Inhibition Performance of 2,2’-(2-Hydroxyethylimino)bis[N-(alphaalpha-dimethylphenethyl)-N-methylacetamide] on Mild Steel Corrosion in 1M HCl Solution. Mater Res [Internet]. 2020 Jun 1;23(2):e20180610. Available from: <URL>.
• 38. Belarbi N, Dergal F, Abdelhamid El-Haci I, Attar T, Lerari D, Dahmani B, et al. Gravimetric, Electrochemical, and Surface Morphological Studies of Ammodaucus Lecotrichus Essential Oil as Corrosion Inhibitor for Copper Surface in Hydrochloric Acid Medium Analytical & Bioanalytical Electrochemistry. Anal Bioanal Electrochem [Internet]. 2021;13(3):340–57. Available from: <URL>.
• 39. Betti N, Al-Amiery AA, Al-Azzawi WK, Isahak WNRW. Corrosion inhibition properties of schiff base derivative against mild steel in HCl environment complemented with DFT investigations. Sci Rep [Internet]. 2023 Jun 2;13(1):8979. Available from: <URL>.
• 40. Benchadli A, Attar T, Choukchou-Braham E. Corrosion Inhibition of Carbon Steel (XC 38) in Hydrochloric Acid by Potassium Iodide. J Adv Res Sci Technol [Internet]. 2018;5(2):834–44. Available from: <URL>.
• 41. Ogunleye OO, Arinkoola AO, Eletta OA, Agbede OO, Osho YA, Morakinyo AF, et al. Green corrosion inhibition and adsorption characteristics of Luffa cylindrica leaf extract on mild steel in hydrochloric acid environment. Heliyon [Internet]. 2020 Jan 1;6(1):e03205. Available from: <URL>.
• 42. Abdul Rahiman AFS, Sethumanickam S. Corrosion inhibition, adsorption and thermodynamic properties of poly(vinyl alcohol-cysteine) in molar HCl. Arab J Chem [Internet]. 2017 May 1;10:S3358–66. Available from: <URL>.