Research Article
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Year 2024, , 303 - 312, 04.02.2024
https://doi.org/10.18596/jotcsa.1391735

Abstract

References

  • 1. Kumar V, Kaushik NK, Tiwari SK, Singh D, Singh B. Green synthesis of iron nanoparticles: Sources and multifarious biotechnological applications. International Journal of Biological Macromolecules. 2023 Dec 31;253:127017. Available from: <URL>.
  • 2. Hussain A, Lakhan MN, Hanan A, Soomro IA, Ahmed M, Bibi F, et al. Recent progress on green synthesis of selenium nanoparticles – a review. Materials Today Sustainability. 2023 Sep 1;23:100420. Available from: <URL>.
  • 3. Nshizirungu T, Rana M, Khan MIH, Jo YT, Park JH. Innovative green approach for recovering Co2O3 nanoparticles and Li2CO3 from spent lithium-ion batteries. Journal of Hazardous Materials Advances. 2023 Feb 1;9:100242. Available from: <URL>.
  • 4. Liu S, Xu X, Ye J, Wang J, Wang Q, Liu Z, et al. Metal-coordinated nanodrugs based on natural products for cancer theranostics. Chemical Engineering Journal. 2023 Jan 15;456:140892. Available from: <URL>.
  • 5. Sharma A, Kumar N, Mudhoo A, Garg VK. Phytobiomass-based nanoadsorbents for sequestration of aquatic emerging contaminants: An Overview. Journal of Environmental Chemical Engineering. 2023 Apr 1;11(2):109506. Available from: <URL>.
  • 6. Jena A, Dube D, Mishra S, Kumar Sahoo P, Kumar Sahoo N. Removal of europium by green tea mediated zero valent iron nanoparticles. Materials Today Proceedings [Internet]. 2023 Oct 31 [cited 2023 Nov 12]; Available from: <URL>.
  • 7. Nguyen NTH, Tran GT, Nguyen NTT, Nguyen TTT, Nguyen DTC, Tran T Van. A critical review on the biosynthesis, properties, applications and future outlook of green MnO2 nanoparticles. Environmental Research. 2023 Aug 15;231:116262. Available from: <URL>.
  • 8. Balu S kumar, Andra S, Jeevanandam J, Kulabhusan PK, Khamari A, Vedarathinam V, et al. Exploring the potential of metal oxide nanoparticles as fungicides and plant nutrient boosters. Crop Protection. 2023 Dec 1;174:106398. Available from: <URL>.
  • 9. Kim JW, Aruchamy G, Kim BK. Recent advances in single-entity electrochemistry for metal nanoparticle, nanodroplet, and bio-entity analysis. TrAC Trends in Analytical Chemistry. 2023 Dec 1;169:117358. Available from: <URL>.
  • 10. Hosseinzadeh E, Foroumadi A, Firoozpour L. What is the role of phytochemical compounds as capping agents for the inhibition of aggregation in the green synthesis of metal oxide nanoparticles? A DFT molecular level response. Inorganic Chemistry Communications. 2023 Jan 1;147:110243. Available from: <URL>.
  • 11. Ally N, Gumbi B. A review on metal nanoparticles as nano-sensors for environmental detection of emerging contaminants. Materials Today: Proceedings. 2023 Aug 8; Available from: <URL>.
  • 12. Kodasi B, Kamble RR, Manjanna J, Hoolageri SR, Bheemayya L, Nadoni VB, et al. Adept green synthesis of Cu2O nanoparticles using Kiwi fruit (Actinidia deliciosa) juice and Studies on their cytotoxic activity and antimicrobial evaluation. Journal of Trace Elements and Minerals. 2023 Mar 1;3:100044. Available from: <URL>.
  • 13. Karakuş S, Özbaş F, Baytemir G, Taşaltın N. Cubic-shaped corylus colurna extract coated Cu2O nanoparticles-based smartphone biosensor for the detection of ascorbic acid in real food samples. Food Chemistry. 2023 Aug 15;417:135918. Available from: <URL>.
  • 14. Madhuri Peddada L, Phyu Cho P, Dulgaj S, Annapragada R, Raja Kanuparthy P. Facile synthesis of green engineered CuO/Cu2O-C nano heterostructures with the controlled Cu2O content for the photodegradation of crystal violet. Results in Optics. 2023 Dec 1;13:100537. Available from: <URL>.
  • 15. Qiao Y, Xie W, Yu F, Yu J, Yao P, Fan Z, et al. High-performance flexible energy storage: Decorating wrinkled MXene with in situ grown Cu2O nanoparticles. Journal of Alloys and Compounds. 2023 Dec 15;968:171921. Available from: <URL>.
  • 16. Al-Hakkani MF, Hassan SHA, Saddik MS, El-Mokhtar MA, Al-Shelkamy SA. Bioengineering, characterization, and biological activities of C@Cu2O@Cu nanocomposite based-mediated the Vicia faba seeds aqueous extract. Journal of Materials Research and Technology. 2021 Sep 1;14:1998–2016. Available from: <URL>.
  • 17. Ramesh C, HariPrasad M, Ragunathan V. Antibacterial Behaviour of Cu2O Nanoparticles Against Escherichia coli; Reactivity of Fehling’s Solution on Manihot esculenta Leaf Extract. Curr Nanosci. 2011 Oct 1;7(5):770–5. Available from: <URL>.
  • 18. Sotelo-Mazon O, Valdez S, Porcayo-Calderon J, Casales-Diaz M, Henao J, Salinas-Solano G, et al. Corrosion protection of 1018 carbon steel using an avocado oil-based inhibitor. Green Chemistry Letters and Reviews. 2019 Jul 3;12(3):255–70. Available from: <URL>.
  • 19. Putra RS, Amri RY, Ayu M. Turbidity removal of synthetic wastewater using biocoagulants based on protein and tannin. AIP Conference Proceedings. 040028. Available from: <URL>.
  • 20. Chinnaiah K, Maik V, Kannan K, Potemkin V, Grishina M, Gohulkumar M, et al. Experimental and Theoretical Studies of Green Synthesized Cu2O Nanoparticles Using Datura Metel L. Journal of Fluorescence. 2022 Mar 8;32(2):559–68. Available from: <URL>.
  • 21. Zheng H, Lu X, He K. In situ transmission electron microscopy and artificial intelligence enabled data analytics for energy materials. Journal of Energy Chemistry. 2022 May;68:454–93. Available from: <URL>.
  • 22. Du BD, Phu D Van, Quoc LA, Hien NQ. Synthesis and Investigation of Antimicrobial Activity of Cu 2 O Nanoparticles/Zeolite. Journal of Nanoparticles. 2017 Jan 9;2017:1–6. Available from: <URL>.
  • 23. Muthukumaran M, Dhinagaran G, Venkatachalam K, Sagadevan S, Gunasekaran S, Podder J, et al. Green synthesis of cuprous oxide nanoparticles for environmental remediation and enhanced visible-light photocatalytic activity. Optik. 2020 Jul;214:164849. Available from: <URL>.
  • 24. Nithiyavathi R, John Sundaram S, Theophil Anand G, Raj Kumar D, Dhayal Raj A, Al Farraj DA, et al. Gum mediated synthesis and characterization of CuO nanoparticles towards infectious disease-causing antimicrobial resistance microbial pathogens. Journal of Infection and Public Health. 2021 Dec;14(12):1893–902. Available from: <URL>.
  • 25. Hasanin MS, Youssef AM. Ecofriendly bioactive film doped CuO nanoparticles based biopolymers and reinforced by enzymatically modified nanocellulose fibers for active packaging applications. Food Packag Shelf Life. 2022 Dec;34:100979. Available from: <URL>.
  • 26. Ramalechume C, Shamili P, Krishnaveni R, Andrew Swamidoss CM. Synthesis of copper oxide nanoparticles using tree gum extract, its spectral characterization, and a study of its anti- bactericidal properties. Material Today: Proceedings. 2020;33:4151–5. Available from: <URL>.
  • 27. Ponmani S, William JKM, Samuel R, Nagarajan R, Sangwai JS. Formation and characterization of thermal and electrical properties of CuO and ZnO nanofluids in xanthan gum. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2014 Feb;443:37–43. Available from: <URL>.
  • 28. Khoshsang H, Abbasi K, Ghaffarinejad A. Biosynthesis of ZnO and CuO nanoparticles using sunflower petal extract. Inorg Chem Commun. 2023 Sep;155:111083. Available from: <URL>.

Sustainable Synthesis of Green Cu2O Nanoparticles using Avocado Peel Extract as Biowaste Source

Year 2024, , 303 - 312, 04.02.2024
https://doi.org/10.18596/jotcsa.1391735

Abstract

In recent years, there has been a significant shift towards the production of advanced nanomaterials using sustainable methods, reflecting a heightened focus on reducing environmental impact and optimizing resource utilization. This growing interest stems from the necessity to address environmental concerns and embrace eco-friendly practices in material synthesis. The primary objective of this study is to explore the eco-friendly synthesis of novel metal oxide nanoparticles (NPs) by utilizing bio-waste as a sustainable precursor. The central theme revolves around employing ultrasound-assisted techniques for Cu2O NP synthesis, with a specific emphasis on utilizing avocado peel waste as an effective phytochemical compound for capping. Through systematic process optimization, we conducted a comprehensive assessment of the resulting NPs, delving into their chemical, thermal, and surface properties. Advanced characterization techniques, including X-ray Diffraction analysis (XRD), Transmission Electron Microscopy (TEM), Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), and Fourier-transform Infrared Spectroscopy (FT-IR), were employed to gain profound insights into the attributes of the synthesized NPs. Our experimental results conclusively demonstrate the successful synthesis of spherical Cu2O NPs, each with a diameter of 25 ± 2 nm. This was achieved by utilizing avocado peel waste (APW) and ultrasound-assisted cavitation at room temperature. The study significantly contributes to our understanding of the potential applications of green synthesis methods, paving the way for environmentally friendly and cost-effective Cu2O NPs.

Ethical Statement

Not applicable

Thanks

The authors would like to thank Istanbul University-Cerrahpaşa, Istanbul, Turkiye for its support in the present work.

References

  • 1. Kumar V, Kaushik NK, Tiwari SK, Singh D, Singh B. Green synthesis of iron nanoparticles: Sources and multifarious biotechnological applications. International Journal of Biological Macromolecules. 2023 Dec 31;253:127017. Available from: <URL>.
  • 2. Hussain A, Lakhan MN, Hanan A, Soomro IA, Ahmed M, Bibi F, et al. Recent progress on green synthesis of selenium nanoparticles – a review. Materials Today Sustainability. 2023 Sep 1;23:100420. Available from: <URL>.
  • 3. Nshizirungu T, Rana M, Khan MIH, Jo YT, Park JH. Innovative green approach for recovering Co2O3 nanoparticles and Li2CO3 from spent lithium-ion batteries. Journal of Hazardous Materials Advances. 2023 Feb 1;9:100242. Available from: <URL>.
  • 4. Liu S, Xu X, Ye J, Wang J, Wang Q, Liu Z, et al. Metal-coordinated nanodrugs based on natural products for cancer theranostics. Chemical Engineering Journal. 2023 Jan 15;456:140892. Available from: <URL>.
  • 5. Sharma A, Kumar N, Mudhoo A, Garg VK. Phytobiomass-based nanoadsorbents for sequestration of aquatic emerging contaminants: An Overview. Journal of Environmental Chemical Engineering. 2023 Apr 1;11(2):109506. Available from: <URL>.
  • 6. Jena A, Dube D, Mishra S, Kumar Sahoo P, Kumar Sahoo N. Removal of europium by green tea mediated zero valent iron nanoparticles. Materials Today Proceedings [Internet]. 2023 Oct 31 [cited 2023 Nov 12]; Available from: <URL>.
  • 7. Nguyen NTH, Tran GT, Nguyen NTT, Nguyen TTT, Nguyen DTC, Tran T Van. A critical review on the biosynthesis, properties, applications and future outlook of green MnO2 nanoparticles. Environmental Research. 2023 Aug 15;231:116262. Available from: <URL>.
  • 8. Balu S kumar, Andra S, Jeevanandam J, Kulabhusan PK, Khamari A, Vedarathinam V, et al. Exploring the potential of metal oxide nanoparticles as fungicides and plant nutrient boosters. Crop Protection. 2023 Dec 1;174:106398. Available from: <URL>.
  • 9. Kim JW, Aruchamy G, Kim BK. Recent advances in single-entity electrochemistry for metal nanoparticle, nanodroplet, and bio-entity analysis. TrAC Trends in Analytical Chemistry. 2023 Dec 1;169:117358. Available from: <URL>.
  • 10. Hosseinzadeh E, Foroumadi A, Firoozpour L. What is the role of phytochemical compounds as capping agents for the inhibition of aggregation in the green synthesis of metal oxide nanoparticles? A DFT molecular level response. Inorganic Chemistry Communications. 2023 Jan 1;147:110243. Available from: <URL>.
  • 11. Ally N, Gumbi B. A review on metal nanoparticles as nano-sensors for environmental detection of emerging contaminants. Materials Today: Proceedings. 2023 Aug 8; Available from: <URL>.
  • 12. Kodasi B, Kamble RR, Manjanna J, Hoolageri SR, Bheemayya L, Nadoni VB, et al. Adept green synthesis of Cu2O nanoparticles using Kiwi fruit (Actinidia deliciosa) juice and Studies on their cytotoxic activity and antimicrobial evaluation. Journal of Trace Elements and Minerals. 2023 Mar 1;3:100044. Available from: <URL>.
  • 13. Karakuş S, Özbaş F, Baytemir G, Taşaltın N. Cubic-shaped corylus colurna extract coated Cu2O nanoparticles-based smartphone biosensor for the detection of ascorbic acid in real food samples. Food Chemistry. 2023 Aug 15;417:135918. Available from: <URL>.
  • 14. Madhuri Peddada L, Phyu Cho P, Dulgaj S, Annapragada R, Raja Kanuparthy P. Facile synthesis of green engineered CuO/Cu2O-C nano heterostructures with the controlled Cu2O content for the photodegradation of crystal violet. Results in Optics. 2023 Dec 1;13:100537. Available from: <URL>.
  • 15. Qiao Y, Xie W, Yu F, Yu J, Yao P, Fan Z, et al. High-performance flexible energy storage: Decorating wrinkled MXene with in situ grown Cu2O nanoparticles. Journal of Alloys and Compounds. 2023 Dec 15;968:171921. Available from: <URL>.
  • 16. Al-Hakkani MF, Hassan SHA, Saddik MS, El-Mokhtar MA, Al-Shelkamy SA. Bioengineering, characterization, and biological activities of C@Cu2O@Cu nanocomposite based-mediated the Vicia faba seeds aqueous extract. Journal of Materials Research and Technology. 2021 Sep 1;14:1998–2016. Available from: <URL>.
  • 17. Ramesh C, HariPrasad M, Ragunathan V. Antibacterial Behaviour of Cu2O Nanoparticles Against Escherichia coli; Reactivity of Fehling’s Solution on Manihot esculenta Leaf Extract. Curr Nanosci. 2011 Oct 1;7(5):770–5. Available from: <URL>.
  • 18. Sotelo-Mazon O, Valdez S, Porcayo-Calderon J, Casales-Diaz M, Henao J, Salinas-Solano G, et al. Corrosion protection of 1018 carbon steel using an avocado oil-based inhibitor. Green Chemistry Letters and Reviews. 2019 Jul 3;12(3):255–70. Available from: <URL>.
  • 19. Putra RS, Amri RY, Ayu M. Turbidity removal of synthetic wastewater using biocoagulants based on protein and tannin. AIP Conference Proceedings. 040028. Available from: <URL>.
  • 20. Chinnaiah K, Maik V, Kannan K, Potemkin V, Grishina M, Gohulkumar M, et al. Experimental and Theoretical Studies of Green Synthesized Cu2O Nanoparticles Using Datura Metel L. Journal of Fluorescence. 2022 Mar 8;32(2):559–68. Available from: <URL>.
  • 21. Zheng H, Lu X, He K. In situ transmission electron microscopy and artificial intelligence enabled data analytics for energy materials. Journal of Energy Chemistry. 2022 May;68:454–93. Available from: <URL>.
  • 22. Du BD, Phu D Van, Quoc LA, Hien NQ. Synthesis and Investigation of Antimicrobial Activity of Cu 2 O Nanoparticles/Zeolite. Journal of Nanoparticles. 2017 Jan 9;2017:1–6. Available from: <URL>.
  • 23. Muthukumaran M, Dhinagaran G, Venkatachalam K, Sagadevan S, Gunasekaran S, Podder J, et al. Green synthesis of cuprous oxide nanoparticles for environmental remediation and enhanced visible-light photocatalytic activity. Optik. 2020 Jul;214:164849. Available from: <URL>.
  • 24. Nithiyavathi R, John Sundaram S, Theophil Anand G, Raj Kumar D, Dhayal Raj A, Al Farraj DA, et al. Gum mediated synthesis and characterization of CuO nanoparticles towards infectious disease-causing antimicrobial resistance microbial pathogens. Journal of Infection and Public Health. 2021 Dec;14(12):1893–902. Available from: <URL>.
  • 25. Hasanin MS, Youssef AM. Ecofriendly bioactive film doped CuO nanoparticles based biopolymers and reinforced by enzymatically modified nanocellulose fibers for active packaging applications. Food Packag Shelf Life. 2022 Dec;34:100979. Available from: <URL>.
  • 26. Ramalechume C, Shamili P, Krishnaveni R, Andrew Swamidoss CM. Synthesis of copper oxide nanoparticles using tree gum extract, its spectral characterization, and a study of its anti- bactericidal properties. Material Today: Proceedings. 2020;33:4151–5. Available from: <URL>.
  • 27. Ponmani S, William JKM, Samuel R, Nagarajan R, Sangwai JS. Formation and characterization of thermal and electrical properties of CuO and ZnO nanofluids in xanthan gum. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2014 Feb;443:37–43. Available from: <URL>.
  • 28. Khoshsang H, Abbasi K, Ghaffarinejad A. Biosynthesis of ZnO and CuO nanoparticles using sunflower petal extract. Inorg Chem Commun. 2023 Sep;155:111083. Available from: <URL>.
There are 28 citations in total.

Details

Primary Language English
Subjects Nanochemistry
Journal Section RESEARCH ARTICLES
Authors

Fatih Özbaş 0000-0002-6655-9363

Publication Date February 4, 2024
Submission Date November 16, 2023
Acceptance Date November 27, 2023
Published in Issue Year 2024

Cite

Vancouver Özbaş F. Sustainable Synthesis of Green Cu2O Nanoparticles using Avocado Peel Extract as Biowaste Source. JOTCSA. 2024;11(1):303-12.