N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

Rukiye Fırıncı

doi:10.18596/jotcsa.90024

EN

N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

Abstract

A series of N-butyl substituted imidazolium salts, (1a-c) and their pyridine enhanced precatalyst preparation stabilization and initiation (PEPPSI) themed palladium N-heterocyclic carbene complexes (2a-c) were synthesized and characterized. Pd-NHC complexes were fully determined by elemental analysis and spectroscopic. The synthesized complexes were tested in Suzuki-Miyaura cross-coupling reaction. These complexes were found to be efficient catalysts for the Suzuki-Miyaura reaction of phenylboronic acid with aryl bromides.

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Details

Primary Language

English

Subjects

-

Journal Section

-

Authors

Rukiye Fırıncı This is me

Publication Date

January 8, 2017

Submission Date

July 1, 2016

Acceptance Date

-

Published in Issue

Year 2016 Volume: 3 Number: 3

DOI

https://doi.org/10.18596/jotcsa.90024

IZ

https://izlik.org/JA83AW46YM

Cite

RIS / Bibtex

APA

Fırıncı, R. (2017). N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION. Journal of the Turkish Chemical Society Section A: Chemistry, 3(3), 93-104. https://doi.org/10.18596/jotcsa.90024

AMA

1.Fırıncı R. N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION. JOTCSA. 2017;3(3):93-104. doi:10.18596/jotcsa.90024

Chicago

Fırıncı, Rukiye. 2017. “N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION”. Journal of the Turkish Chemical Society Section A: Chemistry 3 (3): 93-104. https://doi.org/10.18596/jotcsa.90024.

EndNote

Fırıncı R (January 1, 2017) N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION. Journal of the Turkish Chemical Society Section A: Chemistry 3 3 93–104.

IEEE

[1]R. Fırıncı, “N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION”, JOTCSA, vol. 3, no. 3, pp. 93–104, Jan. 2017, doi: 10.18596/jotcsa.90024.

ISNAD

Fırıncı, Rukiye. “N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION”. Journal of the Turkish Chemical Society Section A: Chemistry 3/3 (January 1, 2017): 93-104. https://doi.org/10.18596/jotcsa.90024.

JAMA

1.Fırıncı R. N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION. JOTCSA. 2017;3:93–104.

MLA

Fırıncı, Rukiye. “N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 3, no. 3, Jan. 2017, pp. 93-104, doi:10.18596/jotcsa.90024.

Vancouver

1.Rukiye Fırıncı. N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION. JOTCSA. 2017 Jan. 1;3(3):93-104. doi:10.18596/jotcsa.90024

Cited By

Synthesis, characterization and catalytic activity in Suzuki-Miyaura coupling of palladacycle complexes with n -butyl-substituted N-heterocyclic carbene ligands

Applied Organometallic Chemistry

https://doi.org/10.1002/aoc.4109